Laboratory test of a prototype heat storage module based on stable supercooling of sodium acetate trihydrate

Abstract Laboratory test of a long term heat storage module utilizing the principle of stable supercooling of 199.5 kg of sodium acetate water mixture has been carried out. Avoiding phase separation of the incongruently melting salt hydrate by using the extra water principleincreased the heat storage capacity. An external expansion vessel minimized the pressure built up in the module while heating and reduced the risk of instable supercooling. The module was stable supercooled at indoor ambient temperature for up to two months after which it was discharged. The energy discharged after activating the supercooled sodium acetate water mixture was 194 kJ/kg of sodium acetate water mixture in the first test cycles dropping to 179 kJ/kg in the later test cycles. Instability of the supercooling occurred when the charging periods were short and in the last test cycles where the tube connecting the module to the expansion vessel had been blocked by the salt hydrate.

[1]  N. Shamsundar,et al.  Solar Heat Storage: Latent Heat Materials, Vol. I: Background and Scientific Principles , 1983 .

[2]  Silvana S. S. Cardoso,et al.  Solidification in heat packs: I. Nucleation rate , 2003 .

[3]  J. Guion,et al.  Nucleation of sodium acetate trihydrate in thermal heat storage cycles , 1991 .

[4]  Simon Furbo,et al.  Towards seasonal heat storage based on stable super cooling of sodium acetate trihydrate , 2010 .

[5]  Hiroshi Kimura,et al.  Phase change stability of sodium acetate trihydrate and its mixtures , 1985 .

[6]  Luisa F. Cabeza,et al.  Review on thermal energy storage with phase change: materials, heat transfer analysis and applications , 2003 .

[7]  S. Furbo Investigation of heat storages with salt hydrate as storage medium based on the extra water principle , 1980 .

[8]  A. Sharma,et al.  Review on thermal energy storage with phase change materials and applications , 2009 .

[9]  Kenichi Ohsasa,et al.  Supercooling and Solidification Behavior of Phase Change Material , 2010 .

[10]  Silvana S. S. Cardoso,et al.  Solidification in heat packs: III. Metallic trigger , 2003 .

[11]  Luisa F. Cabeza,et al.  Immersion corrosion tests on metal‐salt hydrate pairs used for latent heat storage in the 32 to 36°C temperature range , 2001 .

[12]  Takuya Kinoshita,et al.  Effect of Ultrasonic Irradiation on the Crystallization of Sodium Acetate Trihydrate Utilized as Heat Storage Material , 2012 .

[13]  Atsushi Makino,et al.  Measurements of thermophysical properties of sodium acetate hydrate , 1995 .