Batch processing of overlapping molecular spectra as a tool for spatio-temporal diagnostics of power modulated microwave plasma jet

Power modulated microwave plasma jet operating in argon at atmospheric pressure was studied by spatio-temporally resolved optical emission spectroscopy (OES) in order to clarify the influence of modulation on plasma parameters. OES was carried out in OH, NH, N2 and N2+ spectral regions using a spectrometer with intensified CCD detector synchronised with 10^1 – 10^3 Hz sine modulating signal. A special software, able to fit even the overlapping spectra, was developed to batch process the massive datasets produced by this spatio-temporal study. Results show that studied species with the exception of N2+ have balanced rotational and vibrational temperatures across the modulation frequencies. Significant influence of modulation can be clearly observed on temperature spatial gradients. Whereas for low modulation frequencies where the temperatures reach sharp maxima upon discharge tip, the high frequency modulation produces thermally homogeneous plasma.

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