Preroughening transitions in crystal surfaces and valence-bond phases in quantum spin chains.

We show that disordered flat phases in crystal surfaces are equivalent to valence-bond-type phases in integer and half-integer spin quantum chains. In the quantum spin representation the disordered flat phase represents a fluid-type phase with long-range antiferromagnetic spin order. This order is stabilized dynamically by the hopping of the particles and short-range spin-exchange interactions. The mass of N\'eel solitons is finite. Numerical finite-size-scaling results confirm this. We identify the order parameter of the valence-bond phase. The Haldane conjecture suggests a fundamental difference between half-integer and integer antiferromagnetic Heisenberg spin chains. We find that disordered flat phases are realized in both cases, have exactly the same type of long-range antiferromagnetic spin order, and are stabilized by exactly the same mechanism. They differ only in the mathematical formulation of broken symmetry in the spin representation. We suggest experimental methods of observing disordered flat phases in crystal surfaces.