Approach to a general classification of solvents using a multivariate statistical treatment of quantitative solvent parameters

Anhand von 83 organischen Losungsmitteln wird eine allgemein gultige Klassifikation abgeleitet, bei der 8 physikochemische Parameter wie Kirkwood-Funktion, Molrefraktion, Dipolmo- I′) a. ment, Brechungsindex, Kp.

[1]  N. Trinajstic,et al.  Ground states of conjugated molecules. XXII. Polarographic reduction potentials of hydrocarbons , 1970 .

[2]  M. M. Davis.  1 – Brønsted Acid—Base Behavior in “Inert” Organic Solvents , 1970 .

[3]  J. Kirkwood,et al.  Theory of Solutions of Molecules Containing Widely Separated Charges with Special Application to Zwitterions , 1934 .

[4]  G. L. Manna,et al.  Correlations based on the polarization model of the solvent influence examined by ab-initio calculations , 1980 .

[5]  R. Hoffmann.  An Extended Hückel Theory. I. Hydrocarbons , 1963 .

[6]  T. R. Griffiths,et al.  Correlations among solvent polarity scales, dielectric constant and dipole moment, and a means to reliable predictions of polarity scale values from cu , 1979 .

[7]  K. Schanze,et al.  Solvent effects on the thermal cis-trans isomerization and charge-transfer absorption of 4-(diethylamino)-4'-nitroazobenzene , 1983 .

[8]  R. J. Abraham,et al.  Medium effects on rotational equilibria. Part III. The theory for any number of dipoles and its application to 1,1,2-trichloroethane , 1967 .

[9]  L. R. Snyder,et al.  Classification of the solvent properties of common liquids , 1974 .

[10]  L. Onsager.  Electric Moments of Molecules in Liquids , 1936 .

[11]  R. Drago.  Quantitative evaluation and prediction of donor-acceptor interactions , 1973 .

[12]  M. Chastrette,et al.  Statistical study of solvent effects—II: Analysis of some empirical parameters of solvent polarity , 1982 .

[13]  V. Gutmann,et al.  Coordination reactions in non aqueous solutions - The role of the donor strength , 1966 .

[14]  R. T. McIver,et al.  Relative electron affinities of substituted nitrobenzenes in the gas phase , 1983 .

[15]  A. Katritzky,et al.  The correlation of solvent effects on physical and chemical properties , 1971 .

[16]  R. Taft,et al.  The solvatochromic comparison method. I. The .beta.-scale of solvent hydrogen-bond acceptor (HBA) basicities , 1976 .

[17]  D. Newman,et al.  The influence of the solvent on organic reactivity. Part I. Kinetics and mechanism of the reactions of carboxylic acids with diazodiphenylmethane in donor aprotic solvents , 1974 .

[18]  A. Modelli,et al.  The nature of the stabilizing effect of thio groups on the Π anion states of benzene studied by means of electron transmission spectroscopy , 1983 .

[19]  V. Gutmann,et al.  The acceptor number — A quantitative empirical parameter for the electrophilic properties of solvents , 1975 .

[20]  L. Brooker,et al.  Color and Constitution. XI.1 Anhydronium Bases of p-Hydroxystyryl Dyes as Solvent Polarity Indicators , 1951 .

[21]  M. Symons.  Structure in solvents and solutions—NMR and vibrational spectroscopic studies , 1983 .

[22]  C. Hansen,et al.  The Universality of the Solubility Parameter , 1969 .

[23]  J. Dubois,et al.  Influence des solvants sur la transition n → π * des cétones saturées , 1964 .

[24]  M. Chastrette.  Etude statistique des effets de solvant—I : Principes et applications a l'evaluation des parametres de solvant et a la classification , 1979 .

[25]  I. Kolthoff.  Acid-base equilibriums in dipolar aprotic solvents , 1974 .

[26]  L. Brooker,et al.  Color and Constitution. XIII.1 Merocyanines as Solvent Property Indicators2 , 1965 .

[27]  K. Laidler,et al.  The influence of the solvent on reaction rates , 1956 .

[28]  Kenichi Fukui,et al.  The Role of Frontier Orbitals in Chemical Reactions (Nobel Lecture) , 1982 .

[29]  K. Dimroth,et al.  Über Pyridinium‐N‐phenol‐betaine und ihre Verwendung zur Charakterisierung der Polarität von Lösungsmitteln , 1963 .

[30]  Frederick Albert Matsen IV,et al.  Electron Affinities, Methyl Affinities, and Ionization Energies of Condensed Ring Aromatic Hydrocarbons , 1956 .

[31]  H. Jaffe,et al.  Use of the CNDO Method in Spectroscopy. I. Benzene, Pyridine, and the Diazines , 1968 .

[32]  Viktor Gutmann,et al.  Solvent effects on the reactivities of organometallic compounds , 1976 .

[33]  H. Block,et al.  A modification of the onsager theory for a dielectric , 1973 .

[34]  Alan J. Parker,et al.  Protic-dipolar aprotic solvent effects on rates of bimolecular reactions , 1969 .

[35]  R. Taft,et al.  The solvatochromic comparison method. 2. The .alpha.-scale of solvent hydrogen-bond donor (HBD) acidities , 1976 .

[36]  T. R. Stengle,et al.  Contact ion pairing of the perchlorate ion. Chlorine-35 nuclear magnetic resonance study. I. Solutions in pure solvents , 1975 .

[37]  R. Taft,et al.  Regarding a generalized scale of solvent polarities , 1977 .

[38]  J. N. Brönsted.  Zur Theorie der Säure‐Basen‐Funktion , 1928 .

[39]  W. P. Weijland,et al.  Reduction potentials of various aromatic hydrocarbons and their univalent anions , 1956 .