Numerical Modeling of Diffusion in Fractured Media for Gas-Injection and -Recycling Schemes

Diffusion in fractured reservoirs, unlike in unfractured reservoirs, can affect significantly the efficiency of gas injection in oil reservoirs and recycling in gas/condensate reservoirs. The physical diffusion, similar to gravity, results in the change of the path of the injected gas species from the fractures to the matrix, giving rise to late breakthrough. In this work, we present, for the first time, a consistent model to incorporate physical diffusion of multicomponent mixtures for gas-injection schemes in fractured reservoirs. The multicomponent diffusion flux is related to multicomponent diffusion coefficients, which are dependent on temperature, pressure, and composition. These coefficients are calculated from a model based on irreversible thermodynamics. Current simulation models of fractured reservoirs that include diffusion are based on inconsistent models of gas-to-liquid diffusion at the fracture/matrix interface. We avoid this deficiency by assuming that the gas and liquid phases are in equilibrium at the interface. The concept of crossflow equilibrium (i.e., vertical equilibrium) is invoked in our model to avoid the use of transfer functions. In this work, we use the combined discontinuous Galerkin and mixed methods on 2D structured grids to calculate fluxes accurately and to have low numerical dispersion to study physical diffusion. Four examples are presented. In one of the examples, a field-scale study is performed to investigate gas injection in a fractured reservoir away from miscibility pressure and close to miscibility pressure. Results show a significant effect of diffusion on recovery performance away from miscibility pressure. In another example, recycling in a fractured gas/condensate reservoir is presented to demonstrate that diffusion has a significant effect on condensate recovery.

[1]  A. Firoozabadi,et al.  Molecular, pressure, and thermal diffusion in nonideal multicomponent mixtures , 2000 .

[2]  A. Firoozabadi,et al.  Theoretical model of thermal diffusion factors in multicomponent mixtures , 2000 .

[3]  Abbas Firoozabadi,et al.  Thermodynamics of Hydrocarbon Reservoirs , 1999 .

[4]  Shinji Takahashi,et al.  PREPARATION OF A GENERALIZED CHART FOR THE DIFFUSION COEFFICIENTS OF GASES AT HIGH PRESSURES , 1975 .

[5]  Abbas Firoozabadi,et al.  Reinfiltration in Fractured Porous Media: Part 2 - Two Dimensional Model , 1994 .

[6]  P. Belery,et al.  Molecular Diffusion in Naturally Fractured Reservoirs: A Decisive Recovery Mechanism , 1989 .

[7]  Walter Hayduk,et al.  Correlations for prediction of molecular diffusivities in liquids , 1982 .

[8]  H. Kazemi,et al.  NUMERICAL SIMULATION OF WATER-OIL FLOW IN NATURALLY FRACTURED RESERVOIRS , 1976 .

[9]  K. H. Coats,et al.  Implicit Compositional Simulation of Single-Porosity and Dual-Porosity Reservoirs , 1989 .

[10]  Hussein Hoteit,et al.  Compositional Modeling by the Combined Discontinuous Galerkin and Mixed Methods , 2004 .

[11]  J. W. Watts,et al.  A Compositional Formulation of the Pressure and Saturation Equations , 1986 .

[12]  Bernard Bourbiaux,et al.  Fractured Reservoir Simulation: a Challenging and Rewarding Issue , 2010 .

[13]  A. Firoozabadi,et al.  An analysis of species separation in a thermogravitational column filled with a porous medium , 2007 .

[14]  D. Salin,et al.  Miscible displacement between two parallel plates: BGK lattice gas simulations , 1997, Journal of Fluid Mechanics.

[15]  Hussein Hoteit,et al.  Simple phase stability-testing algorithm in the reduction method , 2006 .

[16]  Hussein Hoteit,et al.  Multicomponent fluid flow by discontinuous Galerkin and mixed methods in unfractured and fractured media , 2005 .

[17]  Sally Brown Greater Plutonio: Angola Deepwater Project , 2008 .

[18]  R. Kobayashi,et al.  Self‐diffusion measurements in methane by pulsed nuclear magnetic resonance , 1970 .

[19]  T. A. Renner,et al.  Measurement and Correlation of Diffusion Coefficients for CO2 and Rich-Gas Applications , 1988 .

[20]  D. Peng,et al.  A New Two-Constant Equation of State , 1976 .

[21]  J. E. Warren,et al.  The Behavior of Naturally Fractured Reservoirs , 1963 .

[22]  K. H. Coats,et al.  Dead-End Pore Volume and Dispersion in Porous Media , 1964 .

[23]  K. Aziz,et al.  Analysis and correlation of nitrogen and lean gas miscibility pressure , 1985 .

[24]  Eva Farkas,et al.  General Purpose Compositional Model , 1985 .

[25]  J. Thovert,et al.  Two-phase flow through fractured porous media. , 2003, Physical review. E, Statistical, nonlinear, and soft matter physics.

[26]  Hussein Hoteit,et al.  Compositional Modeling of Discrete-Fractured Media Without Transfer Functions by the Discontinuous Galerkin and Mixed Methods , 2006 .

[27]  Abbas Firoozabadi,et al.  Modeling Multicomponent Diffusion and Convection in Porous Media , 2000 .

[28]  Larry W. Lake,et al.  Effect of Diffusion on Dispersion , 2008 .

[29]  L. K. Thomas,et al.  Ekofisk Nitrogen Injection , 1991 .

[30]  H. L. Toor,et al.  Diffusion in the Three-Component Liquid System Acetone-Benzene-Carbon Tetrachloride , 1965 .

[31]  Phillip M. Sigmund,et al.  Prediction of Molecular Diffusion At Reservoir Conditions. Part 1- Measurement And Prediction of Binary Dense Gas Diffusion Coefficients , 1976 .

[32]  A. Firoozabadi,et al.  Control‐volume method for numerical simulation of two‐phase immiscible flow in two‐ and three‐dimensional discrete‐fractured media , 2004 .

[33]  C. Whitson,et al.  Estimating Diffusion Coefficients of Dense Fluids , 1993 .

[34]  M. Karimi-Fard,et al.  Numerical Simulation of Water Injection in Fractured Media Using the Discrete-Fracture Model and the Galerkin Method , 2003 .

[35]  Richard E. Ewing,et al.  Numerical Simulation of Multiphase Flow in Fractured Porous Media , 2000 .

[36]  D. Benson,et al.  Fractional Dispersion, Lévy Motion, and the MADE Tracer Tests , 2001 .

[37]  J. K. Platten,et al.  Measurements of molecular and thermal diffusion coefficients in ternary mixtures. , 2005, The Journal of chemical physics.

[38]  Phillip M. Sigmund,et al.  Prediction of Molecular Diffusion At Reservoir Conditions. Part II - Estimating the Effects Of Molecular Diffusion And Convective Mixing In Multicomponent Systems , 1976 .

[39]  Ross Taylor,et al.  Multicomponent mass transfer , 1993 .

[40]  G. P. Mathur,et al.  The self‐diffusivity of substances in the gaseous and liquid states , 1965 .