Remote detection of past habitability at Mars-analogue hydrothermal alteration terrains using an ExoMars Panoramic Camera emulator

Abstract A major scientific goal of the European Space Agency’s ExoMars 2018 rover is to identify evidence of life within the martian rock record. Key to this objective is the remote detection of geological substrates that are indicative of past habitable environments, which will rely on visual (stereo wide-angle, and high resolution images) and multispectral (440–1000 nm) data produced by the Panoramic Camera (PanCam) instrument. We deployed a PanCam emulator at four hydrothermal sites in the Namafjall volcanic region of Iceland, a Mars-analogue hydrothermal alteration terrain. At these sites, sustained acidic–neutral aqueous interaction with basaltic substrates (crystalline and sedimentary) has produced phyllosilicate, ferric oxide, and sulfate-rich alteration soils, and secondary mineral deposits including gypsum veins and zeolite amygdales. PanCam emulator datasets from these sites were complemented with (i) NERC Airborne Research and Survey Facility aerial hyperspectral images of the study area; (ii) in situ reflectance spectroscopy (400–1000 nm) of PanCam spectral targets; (iii) laboratory X-ray Diffraction, and (iv) laboratory VNIR (350–2500 nm) spectroscopy of target samples to identify their bulk mineralogy and spectral properties. The mineral assemblages and palaeoenvironments characterised here are analogous to neutral–acidic alteration terrains on Mars, such as at Mawrth Vallis and Gusev Crater. Combined multispectral and High Resolution Camera datasets were found to be effective at capturing features of astrobiological importance, such as secondary gypsum and zeolite mineral veins, and phyllosilicate-rich substrates. Our field observations with the PanCam emulator also uncovered stray light problems which are most significant in the NIR wavelengths and investigations are being undertaken to ensure that the flight model PanCam cameras are not similarly affected.

[1]  P. Browne Hydrothermal Alteration in Active Geothermal Fields , 1978 .

[2]  M. Darby Dyar,et al.  Coordinated Analyses of Antarctic Sediments as Mars Analog Materials Using Reflectance Spectroscopy and Current Flight-Like Instruments for CheMin, SAM and MOMA , 2013 .

[4]  R. Ashley,et al.  Spectra of altered rocks in the visible and near infrared , 1979 .

[5]  S. T. Elliot,et al.  Mars Exploration Rover Athena Panoramic Camera (Pancam) investigation , 2003 .

[6]  Jean-Pierre Bibring,et al.  Hydrous minerals on Mars as seen by the CRISM and OMEGA imaging spectrometers: Updated global view , 2013 .

[7]  John F. Mustard,et al.  Clay minerals in delta deposits and organic preservation potential on Mars , 2008 .

[8]  J. Bibring,et al.  Micromega/IR: Design and status of a near-infrared spectral microscope for in situ analysis of Mars samples , 2009 .

[9]  D. Peacor,et al.  Very Low‐Grade Metapelites: Mineralogy, Microfabrics and Measuring Reaction Progress , 2009 .

[10]  A. Steele,et al.  Integrated ExoMars PanCam, Raman, and close-up imaging field tests on AMASE 2009 , 2010 .

[11]  Jeffrey R. Johnson,et al.  Spectral variability among rocks in visible and near‐infrared multispectral Pancam data collected at Gusev crater: Examinations using spectral mixture analysis and related techniques , 2006 .

[12]  Matthew West,et al.  Formation of an Hesperian-aged sedimentary basin containing phyllosilicates in Coprates Catena, Mars , 2012 .

[13]  Jeffrey R. Johnson,et al.  VNIR multispectral observations of rocks at Cape York, Endeavour crater, Mars by the Opportunity rover’s Pancam , 2013 .

[14]  Steven W. Squyres,et al.  Sedimentary rocks at Meridiani Planum: Origin, diagenesis, and implications for life on Mars , 2005 .

[15]  A. Mortensen,et al.  Exploration and Utilization of the Námafjall High Temperature Area in N-Iceland , 2009 .

[16]  R. V. Morris,et al.  Mineralogy of a Mudstone at Yellowknife Bay, Gale Crater, Mars , 2014, Science.

[17]  A. Yingst,et al.  A Habitable Fluvio-Lacustrine Environment at Yellowknife Bay, Gale Crater, Mars , 2014, Science.

[18]  Gerhard Paar,et al.  Lunar PanCam: Adapting ExoMars PanCam for the ESA Lunar Lander , 2012 .

[19]  Raymond E. Arvidson,et al.  A synthesis of Martian aqueous mineralogy after 1 Mars year of observations from the Mars Reconnaissance Orbiter , 2009 .

[20]  H. Schmincke,et al.  Palagonite – a review , 2002 .

[21]  Raymond E. Arvidson,et al.  In-Situ and Experimental Evidence for Acidic Weathering of Rocks and Soils on Mars , 2006 .

[22]  D. Ming,et al.  Iron mineralogy and aqueous alteration from Husband Hill through Home Plate at Gusev Crater, Mars: Results from the Mössbauer instrument on the Spirit Mars Exploration Rover , 2008 .

[23]  Claire R. Cousins,et al.  Selecting the geology filter wavelengths for the ExoMars Panoramic Camera instrument , 2012 .

[24]  Andrew D Griffiths,et al.  Astrobiological considerations for the selection of the geological filters on the ExoMars PanCam instrument. , 2010, Astrobiology.

[25]  D. Ming,et al.  Geochemical diversity in first rocks examined by the Curiosity Rover in Gale Crater: Evidence for and significance of an alkali and volatile‐rich igneous source , 2014 .

[26]  D. Loizeau,et al.  Habitability on Mars from a microbial point of view. , 2013, Astrobiology.

[27]  David L. Bish,et al.  Reflectance Spectra Diversity of Silica-Rich Materials: Sensitivity to Environment and Implications for Detections on Mars , 2013 .

[28]  William H. Farrand,et al.  Rock spectral classes observed by the Spirit Rover's Pancam on the Gusev Crater Plains and in the Columbia Hills , 2008 .

[29]  Wolfgang Fink,et al.  Exploration of hydrothermal targets on Mars , 2007 .

[30]  J. Johnson,et al.  Observations of rock spectral classes by the Opportunity rover's Pancam on northern Cape York and on Matijevic Hill, Endeavour Crater, Mars , 2014 .

[31]  B. Ehlmann,et al.  Mineralogy and chemistry of altered Icelandic basalts: Application to clay mineral detection and understanding aqueous environments on Mars , 2012 .

[32]  R. J. Reid,et al.  Imager for Mars Pathfinder (IMP) image calibration , 1999 .

[33]  Matthew Gunn,et al.  Glaciovolcanic hydrothermal environments in Iceland and implications for their detection on Mars , 2013 .

[34]  Jean-Pierre Bibring,et al.  Subsurface water and clay mineral formation during the early history of Mars , 2011, Nature.

[35]  J. Bell,et al.  Spectral unmixing for mineral identification in pancam images of soils in Gusev crater, Mars , 2009 .

[36]  William H. Farrand,et al.  Spectral, mineralogical, and geochemical variations across Home Plate, Gusev Crater, Mars indicate high and low temperature alteration , 2009 .

[37]  Jeffrey R. Johnson,et al.  Silica-rich deposits and hydrated minerals at Gusev Crater, Mars: Vis-NIR spectral characterization and regional mapping , 2010 .

[38]  Jean-Pierre Bibring,et al.  Phyllosilicate Diversity and Past Aqueous Activity Revealed at Mawrth Vallis, Mars , 2008, Science.

[39]  I. Crawford,et al.  Volcano-ice interaction as a microbial habitat on Earth and Mars. , 2011, Astrobiology.

[40]  F. G. Carrozzo,et al.  The Mawrth Vallis region of Mars: A potential landing site for the Mars Science Laboratory (MSL) mission. , 2010, Astrobiology.

[41]  H. Edwards,et al.  The ExoMars Raman spectrometer and the identification of biogeological spectroscopic signatures using a flight-like prototype , 2012, Analytical and Bioanalytical Chemistry.

[42]  E. A. Guinness,et al.  Ancient Aqueous Environments at Endeavour Crater, Mars , 2014, Science.

[43]  R. C. Wiens,et al.  Martian Fluvial Conglomerates at Gale Crater , 2013, Science.

[44]  M. D. Dyar,et al.  Reflectance and emission spectroscopy study of four groups of phyllosilicates: smectites, kaolinite-serpentines, chlorites and micas , 2008, Clay Minerals.

[45]  Gerhard Kminek,et al.  ExoMars - searching for life on the Red Planet , 2006 .

[46]  J. Bell,et al.  Correlating multispectral imaging and compositional data from the Mars Exploration Rovers and implications for Mars Science Laboratory , 2013 .

[47]  William H. Farrand,et al.  Visible and near-infrared multispectral analysis of rocks at Meridiani Planum, Mars, by the Mars Exploration Rover Opportunity , 2007 .

[48]  Harry Y. McSween,et al.  Implications for early hydrothermal environments on Mars through the spectral evidence for carbonation and chloritization reactions in the Nili Fossae region , 2013 .

[49]  Geochemical Consequences of Widespread Clay Mineral Formation in Mars’ Ancient Crust , 2013 .

[50]  I. Fischer Sulfolobus metallicus , sp . nov . , a Novel Strictly Chemolithoautotrophic Thermophilic Archaeal Species of Metal-Mobilizers , 2009 .

[51]  S. Squyres,et al.  Diverse aqueous environments on ancient Mars revealed in the southern highlands , 2009 .

[53]  H. Ármannsson Monitoring the Effect of Geothermal Effluent from the Krafla and Bjarnarflag Power Plants on Groundwater in the Lake Mývatn Area, Iceland, with Particular Reference to Natural Tracers , 2005 .

[54]  M. T. Capria,et al.  MA_MISS: Mars multispectral imager for subsurface studies , 1999 .

[55]  R. E. Arvidson,et al.  Ancient Impact and Aqueous Processes at Endeavour Crater, Mars , 2012, Science.

[56]  Matthew Gunn,et al.  Multi-Spectral Vision Processing for the ExoMars 2018 Mission , 2011 .

[57]  E. Cloutis,et al.  Spectral reflectance properties of zeolites and remote sensing implications , 2002 .