论文信息 - [ O -Methyl N -(4-chlorophenyl)thiocarbamato-κ S ](triethylphosphine-κ P )gold(I)

[ O -Methyl N -(4-chlorophenyl)thiocarbamato-κ S ](triethylphosphine-κ P )gold(I)

The molecules of the title complex, Et3PAu[SC(OMe)=N(C6H4Cl-4)] or [Au(C8H7ClNOS)(C6H15P)], involve the Au atom with linear coordination [Au—P = 2.2584 (10) A, Au—S = 2.3156 (10)A and P—Au—S = 178.32 (4)°] and are linked into centrosymmetric dimers via secondary Au⋯S interactions [3.7616 (11) A].

Primjira P. Tadbuppa | Edward R. T. Tiekink | E. Tiekink | P. Tadbuppa

[1] E. Tiekink,et al. Triorganophosphinegold(I) Carbonimidothioates , 1993 .

[2] E. Tiekink,et al. Luminescent phosphine gold(I) thiolates: correlation between crystal structure and photoluminescent properties in [R3PAu{SC(OMe)=NC6H4NO2-4}] (R = Et, Cy, Ph) and [(Ph2P-R-PPh2){AuSC(OMe)=NC6H4NO2-4}2] (R = CH2, (CH2)2, (CH2)3, (CH2)4, Fc). , 2006, Inorganic chemistry.