Investigation of the cut location in hydrogen implantation induced silicon surface layer exfoliation

The physical mechanisms of hydrogen induced silicon surface layer exfoliation were investigated using the combination of ion beam analysis, secondary ion mass spectroscopy (SIMS), scanning electron microscopy (SEM), and cross section transmission electron microscopy (XTEM). A 〈100〉 oriented silicon wafer was implanted with 175 keV protons to a dose of 5×1016 cm−2. The implanted wafer was bonded to a silicon oxide capped 〈100〉 silicon wafer and then heated to an elevated temperature of 600 °C to produce exfoliation. The hydrogen-implanted sample was analyzed in the as-implanted state as well as after the cleavage of the silicon wafer. The depth distribution of the implantation damage was monitored by Rutherford backscattering spectrometry (RBS) in channeling condition and XTEM imaging. Elastic recoil detection analysis and SIMS was performed to examine the hydrogen depth distribution. Cross section SEM and RBS channeling was used to measure the thickness of the exfoliated layer after cleavage. A comparison...

[1]  B. Aspar,et al.  A transmission electron microscopy quantitative study of the growth kinetics of H platelets in Si , 2000 .

[2]  M. Nastasi,et al.  Hydrogen blister depth in boron and hydrogen coimplanted n-type silicon , 1999 .

[3]  M. Nastasi,et al.  Fracture toughness of diamondlike carbon coatings , 1999 .

[4]  Amit Misra,et al.  Residual stresses and ion implantation effects in Cr thin films , 1999 .

[5]  Robert Hull,et al.  Properties of Crystalline Silicon , 1999 .

[6]  Michel Bruel,et al.  The History, Physics, and Applications of the Smart-Cut® Process , 1998 .

[7]  S. Kalbitzer,et al.  Energy loss and straggling of H and He ions of keV energies in Si and C , 1998 .

[8]  Y.-L. Chao,et al.  Si and SiC layer transfer by high temperature hydrogen implantation and lower temperature layer splitting , 1998 .

[9]  M. Loboda,et al.  Understandillg hydrogen silsesquioxane-based dielectric film processing , 1998 .

[10]  C. Varma,et al.  HYDROGEN-IMPLANT INDUCED EXFOLIATION OF SILICON AND OTHER CRYSTALS , 1997 .

[11]  A. Agarwal,et al.  On the mechanism of the hydrogen-induced exfoliation of silicon , 1997 .

[12]  L. B. Freund,et al.  A lower bound on implant density to induce wafer splitting in forming compliant substrate structures , 1997 .

[13]  R. Averback,et al.  Fundamental aspects of defect production in solids , 1997 .

[14]  P. Ehrhart,et al.  BOUND VACANCY INTERSTITIAL PAIRS IN IRRADIATED SILICON , 1997 .

[15]  S. Hopfe,et al.  Layer splitting process in hydrogen-implanted Si, Ge, SiC, and diamond substrates , 1997 .

[16]  Theodore V. Vorburger,et al.  Calibration of scanning electron microscope magnification standards SRM484 , 1996, Advanced Lithography.

[17]  Michel Bruel,et al.  Application of hydrogen ion beams to Silicon On Insulator material technology , 1996 .

[18]  D. Fink,et al.  Hydrogen implantation and diffusion in silicon and silicon dioxide , 1995 .

[19]  Van de Walle Cg,et al.  ENERGETICS OF BOND-CENTERED HYDROGEN IN STRAINED SI-SI BONDS , 1995 .

[20]  G. Cerofolini,et al.  A fast technique for the quantitative analysis of channeling RBS spectra , 1992 .

[21]  Ottaviani,et al.  Hydrogen-related complexes as the stressing species in high-fluence, hydrogen-implanted, single-crystal silicon. , 1992, Physical review. B, Condensed matter.

[22]  Cynthia A. Volkert,et al.  Stress and plastic flow in silicon during amorphization by ion bombardment , 1991 .

[23]  J. Pankove,et al.  Hydrogen in semiconductors , 1991 .

[24]  J. Poate,et al.  Point defect populations in amorphous and crystalline silicon , 1990 .

[25]  S. Dannefaer Defects in semiconductors , 1989 .

[26]  Nichols,et al.  Properties of hydrogen in crystalline silicon under compression and tension. , 1989, Physical review letters.

[27]  Pantelides,et al.  Theory of hydrogen diffusion and reactions in crystalline silicon. , 1989, Physical review letters.

[28]  Snyder,et al.  State and motion of hydrogen in crystalline silicon. , 1988, Physical review. B, Condensed matter.

[29]  Chang,et al.  Theory of hydrogen passivation of shallow-level dopants in crystalline silicon. , 1988, Physical review letters.

[30]  W. Gibson,et al.  The angular dependence of energy loss of channeled 2 MeV helium ions along Si 〈100〉 axis , 1986 .

[31]  J. Ziegler,et al.  stopping and range of ions in solids , 1985 .

[32]  Lawrence R. Doolittle,et al.  Algorithms for the rapid simulation of Rutherford backscattering spectra , 1985 .

[33]  A. Anttila,et al.  Ranges of the 0.3–2 MeV H+ and 0.7–2 MeV H+ 2 ions in Si and Ge , 1982 .

[34]  A. Anttila,et al.  Modal ranges of 400 - 1800 keV 4He+ ions in si measured via blistering , 1981 .

[35]  James W. Mayer,et al.  Ion implantation in semiconductors , 1973 .

[36]  M. Ashby,et al.  Diffraction contrast from spherically symmetrical coherency strains , 1963 .