ALKALI-SILICA REACTIVITY: AN OVERVIEW OF RESEARCH

Part I of this report is a synthesis of knowledge of mechanisms of damage to concrete by alkali-silica reactivity. The details of the alkali silica reaction are discussed, and it is noted that the process is complicated by the effects of drying and growth of shrinkage cracks in exposed surfaces. The presence of chloride salts accelerates alkali-silica reactions. Formation of Friedel's salt and other complex chloride containing salts complicates test results. Part II of the report identifies 10 specific gaps in knowledege of alkali-silica reactions in concrete that limit the ability to control these reactions or to predict performance of concrete with reactive aggregates. These involve rapid and reliable test methods; moisture conditions in highway structures; effects of salts, role of sulfate reactions accompanying expansions caused by reactivity; measurement of aggregate reactivities; effect of restraint on kinetics; mechanisms by which pozzolans prevent expansion; test methods and specifications for pozzolans; and inhibition of reactivity by chemical agents.

[1]  Rasheeduzzafar,et al.  Deterioration of Concrete Structures in the Environment of the Middle East , 1984 .

[2]  David Stark,et al.  The Moisture Condition of Field Concrete Exhibiting Alkali-Silica Reactivity , 1991, "SP-126: Durability of Concrete: Second International Conference, Montreal, Canada 1991".

[3]  Zdenek P. Bazant,et al.  Creep and Shrinkage Law for Concrete at Variable Humidity , 1974 .

[4]  J. Gillott,et al.  Mechanism of alkali-silica reaction and the significance of calcium hydroxide , 1991 .

[5]  G. Verbeck,et al.  OSMOTIC STUDIES AND HYPOTHESIS CONCERNING ALKALI-AGGREGATE REACTION , 1955 .

[6]  Dent Classer,et al.  The Chemistry of Alkali-Aggregate Reactions , 1981 .

[7]  G. Davies,et al.  Alkali-silica reaction products and their development , 1988 .

[8]  S. Diamond,et al.  The occurrence of duplex films on flyash surfaces , 1980 .

[9]  W. W. Barkas,et al.  Swelling of Wood under Stress , 1950, Nature.

[10]  Lesile Glasser The chemistry of silica: By Ralph K. Iller. Pp. vii+ 866. Wiley, Chichester. 1979, £39.50 , 1980 .

[11]  B. Durand,et al.  Use of gel composition as a criterion for diagnosis of alkali-aggregate reactivity in concrete containing siliceous limestone aggregate , 1987 .

[12]  John Aurie Dean,et al.  Lange's Handbook of Chemistry , 1978 .

[13]  Alan H. Mattock,et al.  Influence of Size and Shape of Member on the Shrinkage and Creep of Concrete , 1966 .

[14]  C. L. Page,et al.  Aspects of the pore solution chemistry of blended cements related to the control of alkali silica reaction , 1987 .

[15]  S. Diamond,et al.  CHLORIDE CONCENTRATIONS IN CONCRETE PORE SOLUTIONS RESULTING FROM CALCIUM AND SODIUM CHLORIDE ADMIXTURES , 1986 .

[16]  Ellis Gartner,et al.  Saturation factors for calcium hydroxide and calcium sulfates in fresh portland cement pastes , 1985 .

[17]  R. Helmuth,et al.  Fly Ash in Cement and Concrete , 1987 .

[18]  Leslie J. Struble,et al.  Swelling Properties of Synthetic Alkali Silica Gels , 1981 .

[19]  D. W. Hobbs,et al.  Influence of pulverized–fuel ash and granulated blastfurnace slag upon expansion caused by the alkali–silica reaction , 1982 .

[20]  N. Thaulow,et al.  Quantitative microanalyses of alkali-silica gel in concrete , 1975 .

[21]  K. Lange,et al.  PROPERTIES OF SOLUBLE SILICATES , 1969 .

[22]  L. Glasser,et al.  On the role of calcium in the alkali-aggregate reaction , 1982 .

[23]  C. L. Page,et al.  Pore Solution Chemistry and Alkali Aggregate Reaction , 1987, SP-100: Concrete Durability: Proceedings of Katharine and Bryant Mather International Symposium.

[24]  David Stark,et al.  Alkali-Silica Reactivity: Some Reconsiderations , 1980 .

[25]  J. A. Larbi,et al.  Interaction of polymers with portland cement during hydration: A study of the chemistry of the pore solution of polymer-modified cement systems , 1990 .

[26]  S. Urhan,et al.  Alkali silica and pozzolanic reactions in concrete. Part 1: Interpretation of published results and an hypothesis concerning the mechanism , 1987 .

[27]  Egon Matijević,et al.  Chemistry of silica , 1980 .

[28]  S. Chatterji,et al.  The role of Ca(OH)2 in the breakdown of Portland cement concrete due to alkali-silica reaction , 1979 .

[29]  C. Page,et al.  Influence of sodium chloride on alkali-silica reaction , 1988 .

[30]  P. Grattan-Bellew,et al.  Concrete alkali-aggregate reactions , 1987 .

[31]  C. A. Randall,et al.  Potential Applications of Alkali-Activated Alumino-Silicate Binders in Military Operations , 1985 .

[32]  R. C. Mielenz,et al.  EVALUATION OF THE QUICK CHEMICAL TEST FOR ALKALI REACTIVITY OF CONCRETE AGGREGATE , 1958 .

[33]  Zdenek P. Balant,et al.  Creep and Shrinkage Characterisation for Analyzing Prestressed Concrete Structures , 1980 .

[34]  P. Nixon,et al.  Alkali metal sulphate — a factor common to both alkali aggregate reaction and sulphate attack on concrete , 1980 .

[35]  L. Struble The influence of cement pore solution on alkali-silica reaction , 1987 .

[36]  R. C. Weast CRC Handbook of Chemistry and Physics , 1973 .

[37]  Thomas E. Stanton,et al.  California Experience With the Expansion of Concrete Through Reaction Between Cement and Aggregate , 1942 .

[38]  L. Glasser,et al.  Osmotic pressure and the swelling of gels , 1979 .

[39]  M. Bhatty Mechanism of Pozzolanic Reactions and Control of Alkali-Aggregate Expansion , 1985 .

[40]  W. A. Gutteridge,et al.  Some chemical and physical properties of beltane opal rock and its gelatinous alkali silica reaction product , 1980 .

[41]  Werner Stumm,et al.  Formulation of polysilicates as determined by coagulation effects , 1967 .

[42]  S. Chatterji Mechanism of the CaCl2 attack on portland cement concrete , 1978 .

[43]  M. Muir Physical Chemistry , 1888, Nature.

[44]  S. Chatterji,et al.  An accelerated method for the detection of alkali-aggregate reactivities of aggregates , 1978 .

[45]  L. Glasser,et al.  The chemistry of ‘alkali-aggregate’ reaction , 1981 .

[46]  M. Kawamura,et al.  CHARACTERISTICS OF ALKALI-SILICA REACTION IN THE PRESENCE OF SODIUM AND CALCIUM CHLORIDE , 1990 .

[47]  Norbert Adolph Lange,et al.  Handbook of chemistry , 1944 .

[48]  W. Davies The chemistry of milk , 1936 .