Regioselective Hydrogen-atom Transfer from Triglycine†

The products of the photochemically induced reaction of triglycine with di-tert-butyl peroxide show preferential modification of the C-terminal amino acid residue.

[1]  C. Easton Free-Radical Reactions in the Synthesis of alpha-Amino Acids and Derivatives. , 1997, Chemical reviews.

[2]  Xian‐Man Zhang,et al.  Effects of adjacent acceptors and donors on the stabilities of carbon-centered radicals , 1992 .

[3]  M. Davies,et al.  Radical-induced damage to proteins: e.s.r. spin-trapping studies. , 1991, Free radical research communications.

[4]  Xian‐Man Zhang,et al.  Effects on anions and radicals of .alpha.-quaternary ammonium substituents , 1990 .

[5]  J. Stubbe Protein radical involvement in biological catalysis? , 1989, Annual review of biochemistry.

[6]  P. Steel,et al.  Dimerization of Glycine Derivatives , 1988 .

[7]  H. Hatano,et al.  Studies on γ-irradiated aqueous solutions of tripeptides composed of glycine and L-alanine by the spin-trap high-performance liquid chromatography – electron spin resonance method , 1984 .

[8]  W. Garrison REACTION MECHANISMS IN THE RADIOLYSIS OF PEPTIDES, POLYPEPTIDES AND PROTEINS II REACTIONS AT SIDE-CHAIN LOCI IN MODEL SYSTEMS , 1982 .

[9]  J. Beynon,et al.  The modern mass spectrometer—a complete chemical laboratory , 1981 .

[10]  F. Glorieux,et al.  Separation of collagen cyanogen bromide-derived peptides by reversed-phase high-performance liquid chromatography. , 1980, The Biochemical journal.

[11]  J. Beynon,et al.  Design and Performance of a Mass-analyzed Ion Kinetic Energy (MIKE) Spectrometer , 1973 .

[12]  P. Neta,et al.  Selectivity in the reactions of eaq-and OH radicals with simple peptides in aqueous solution. Optical absorption spectra of intermediates. , 1970, Journal of the American Chemical Society.