Green composites: sustainability and mechanical performance

Abstract This study considers the mechanical properties of a range of thermosetting resin systems, including systems with bioderived content, and associated natural fibre composites. The bioderived resin systems (22 and 40% biocontent) demonstrated similar tensile strength to standard resin systems, indicating their potential to be a substitute for such systems. To optimise the performance of the natural fibre composites, the reinforcement needed to be dried before composite processing. The stiffness and strength of the natural fibre systems improved with degree of alignment, as expected, and with the use of a semiprocessed fibre; in this way, the properties approached those of chopped strand mat E-glass composites. Even the natural fibre composite with the lowest tensile performance still demonstrated a fracture toughness that was halfway in between the E-glass composite and the resin system.

[1]  W. Marsden I and J , 2012 .

[2]  L. Gorbatikh,et al.  Assessment of the tensile properties of coir, bamboo and jute fibre , 2010 .

[3]  Patricia Krawczak,et al.  Thermosetting (bio)materials derived from renewable resources: A critical review , 2010 .

[4]  M. Singh,et al.  Life Cycle Impact Assessment of Flax Fibre for the Reinforcement of Composites , 2009 .

[5]  James Thomason,et al.  Why are natural fibres failing to deliver on composite performance , 2009 .

[6]  P. Davies,et al.  Effect of recycling on mechanical behaviour of biocompostable flax/poly(L-lactide) composites , 2008 .

[7]  K. Pickering,et al.  Engineering and evaluation of hemp fibre reinforced polypropylene composites: Fibre treatment and matrix modification , 2008 .

[8]  J. Bonnet,et al.  Influence of various chemical treatments on the composition and structure of hemp fibres , 2008 .

[9]  N. Zafeiropoulos Engineering the fibre – matrix interface in natural-fibre composites , 2008 .

[10]  R. M. Rowell,et al.  Natural fibres: types and properties , 2008 .

[11]  Mahmoud M. Farag,et al.  Quantitative methods of materials substitution: Application to automotive components , 2008 .

[12]  H. V. D. Werf,et al.  The environmental impacts of the production of hemp and flax textile yarn , 2008 .

[13]  P. Škundrić,et al.  Quality of chemically modified hemp fibers. , 2008, Bioresource technology.

[14]  C. Baley,et al.  Investigations on the recycling of hemp and sisal fibre reinforced polypropylene composites , 2007 .

[15]  K. Pickering,et al.  Optimising industrial hemp fibre for composites , 2007 .

[16]  Jim Holbery,et al.  Natural-fiber-reinforced polymer composites in automotive applications , 2006 .

[17]  Y. Grohens,et al.  Influence of chemical treatments on surface properties and adhesion of flax fibre-polyester resin , 2006 .

[18]  I. Verpoest,et al.  Improving the properties of UD flax fibre reinforced composites by applying an alkaline fibre treatment , 2006 .

[19]  Michael Søgaard Jørgensen,et al.  Effects of chemical–physical pre-treatment processes on hemp fibres for reinforcement of composites and for textiles , 2006 .

[20]  R. Drew,et al.  Wettability and spreading kinetics of molten aluminum on copper-coated ceramics , 2006 .

[21]  F. Simon,et al.  A study of the effect of acetylation and propionylation surface treatments on natural fibres , 2005 .

[22]  M. Misra,et al.  Fracture toughness and impact strength of anhydride‐cured biobased epoxy , 2005 .

[23]  Michael F. Ashby,et al.  An introduction to properties, applications, and design , 2005 .

[24]  L. Avérous,et al.  Biocomposites based on plasticized starch: thermal and mechanical behaviours , 2004 .

[25]  M. Misra,et al.  Biobased resin as a toughening agent for biocomposites , 2004 .

[26]  M. Hautala,et al.  Use of hemp and flax in composite manufacture: a search for new production methods , 2004 .

[27]  R. Joffe,et al.  Strength and adhesion characteristics of elementary flax fibres with different surface treatments , 2003 .

[28]  Kevin Barraclough,et al.  I and i , 2001, BMJ : British Medical Journal.

[29]  P. Zugenmaier Conformation and packing of various crystalline cellulose fibers , 2001 .

[30]  E. de Jong,et al.  Analysis of retted and non retted flax fibres by chemical and enzymatic means. , 2001, Journal of biotechnology.

[31]  E. Wintermantel,et al.  Influence of the growth stage of industrial hemp on chemical and physical properties of the fibres , 2001 .

[32]  J. Gassan,et al.  Effects of corona discharge and UV treatment on the properties of jute-fibre epoxy composites , 2000 .

[33]  H. Sharma,et al.  Chemical and physical characterization of water- and dew-retted flax fibers , 2000 .

[34]  Hannele S Sankari,et al.  Comparison of bast fibre yield and mechanical fibre properties of hemp (Cannabis sativa L.) cultivars , 2000 .

[35]  G. Hinrichsen,et al.  Flax and cotton fiber reinforced biodegradable polyester amide composites, 2. Characterization of biodegradation , 1999 .

[36]  M. Vignon,et al.  Fibres from semi-retted hemp bundles by steam explosion treatment , 1998 .

[37]  R. K. Basak,et al.  Studies of acetylation of jute using simplified procedure and its characterization , 1997 .

[38]  M. Vignon,et al.  Morphological characterization of steam-exploded hemp fibers and their utilization in polypropylene-based composites , 1996 .

[39]  K. Nakamae,et al.  Elastic modulus of the crystalline regions of cellulose polymorphs , 1995 .

[40]  G. Hinrichsen,et al.  Influence of water uptake on the mechanical properties of jute fiber‐reinforced polypropylene , 1994 .

[41]  M. Belgacem,et al.  Effect of corona modification on the mechanical properties of polypropylene/cellulose composites , 1994 .

[42]  P. Gatenholm,et al.  Adhesion characteristics of oxygen plasma-treated rayon fibers , 1994 .

[43]  M. Wolcott,et al.  Characterization of the interface between cellulosic fibers and a thermoplastic matrix , 1994 .

[44]  J. Barnby,et al.  Crack propagation and compliance calibration in fibre-reinforced polymers , 1976 .