Extraordinary synergy in the mechanical properties of polymer matrix composites reinforced with 2 nanocarbons

One of the applications of nanomaterials is as reinforcements in composites, wherein small additions of nanomaterials lead to large enhancements in mechanical properties. There have been extensive studies in the literature on composites where a polymer matrix is reinforced by a single nanomaterial such as carbon nanotubes. In this article, we examine the significant synergistic effects observed when 2 different types of nanocarbons are incorporated in a polymer matrix. Thus, binary combinations of nanodiamond, few-layer graphene, and single-walled nanotubes have been used to reinforce polyvinyl alcohol. The mechanical properties of the resulting composites, evaluated by the nanoindentation technique, show extraordinary synergy, improving the stiffness and hardness by as much as 400% compared to those obtained with single nanocarbon reinforcements. These results suggest a way of designing advanced materials with extraordinary mechanical properties by incorporating small amounts of 2 nanomaterials such as graphene plus nanodiamond or nanodiamond plus carbon nanotube.

[1]  Yury Gogotsi,et al.  Nanodiamond-polymer composite fibers and coatings. , 2009, ACS nano.

[2]  U. Ramamurty,et al.  Mechanical properties of inorganic nanowire reinforced polymer–matrix composites , 2006 .

[3]  G. Pharr,et al.  An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments , 1992 .

[4]  L. Brinson,et al.  Functionalized graphene sheets for polymer nanocomposites. , 2008, Nature nanotechnology.

[5]  Elizabeth C. Dickey,et al.  Load transfer and deformation mechanisms in carbon nanotube-polystyrene composites , 2000 .

[6]  H. Wagner,et al.  Mechanical Properties of Functionalized Single‐Walled Carbon‐Nanotube/Poly(vinyl alcohol) Nanocomposites , 2005 .

[7]  C. N. R. Rao,et al.  Covalent and Noncovalent Functionalization and Solubilization of Graphene , 2009 .

[8]  C N R Rao,et al.  The problem of purifying single-walled carbon nanotubes. , 2005, Small.

[9]  C. Shearwood,et al.  Mechanical properties and interfacial characteristics of carbon-nanotube-reinforced epoxy thin films , 2002 .

[10]  Robert H. Hauge,et al.  Poly(vinyl alcohol)/SWNT Composite Film , 2003 .

[11]  J. Coleman,et al.  Morphological and mechanical properties of carbon-nanotube-reinforced semicrystalline and amorphous polymer composites , 2002 .

[12]  C. N. R. Rao,et al.  Graphene, the new nanocarbon , 2009 .

[13]  C. Rao,et al.  Nanotubes and nanowires , 2001 .

[14]  U. Ramamurty,et al.  Nano-indentation studies on polymer matrix composites reinforced by few-layer graphene , 2009, Nanotechnology.

[15]  Michael A. Sutton,et al.  Nanomechanical characterization of single-walled carbon nanotube reinforced epoxy composites , 2004 .

[16]  C. Rao,et al.  Covalent and noncovalent functionalisation and solubilisation of nanodiamond , 2008 .