论文信息 - Effects of Ru Co-Sputtering on the Properties of Porous Ni Thin Films

Effects of Ru Co-Sputtering on the Properties of Porous Ni Thin Films

NiO films and Ru co-sputtered NiO films were deposited by reactive magnetron sputtering for micro-solid oxide fuel cell anode applications. The deposited films were reduced to form porous films. The reduction kinetics of the Ru doped NiO film was more sluggish than that of the NiO film, and the resulting microstructure of the former exhibited finer pore networks. The possibility of using the films for the anodes of single chamber micro-SOFCs was investigated using an air/fuel mixed environment. It was found that the abrupt increase in the resistance is suppressed in the Ru co-sputtered film, as compared to undoped film.

Woo-Sik Kim | H. Lee | Joosung Kim | S. Choi

[1] Zongping Shao,et al. A thermally self-sustained micro solid-oxide fuel-cell stack with high power density , 2005, Nature.

[2] Joshua L. Hertz,et al. Electrochemical Characterization of Thin Films for a Micro-Solid Oxide Fuel Cell , 2004 .

[3] S. Corbin,et al. Influence of porous composite microstructure on the processing and properties of solid oxide fuel cell anodes , 2004 .

[4] L. A. Chick,et al. Diffusion Limitations in the Porous Anodes of SOFCs , 2003 .

[5] S. Bebelis,et al. AC impedance study of Ni–YSZ cermet anodes in methane-fuelled internal reforming YSZ fuel cells , 2002 .

[6] I. Katardjiev,et al. Resputtering effects during ion beam assisted deposition and the sputter yield amplification effect , 1996 .

[7] T. Hibino,et al. A novel cell design for simplifying SOFC system , 1995 .

[8] H. Tuller,et al. Doped Ceria as a Solid Oxide Electrolyte , 1975 .

[9] E. Yamaka,et al. Electrical Conductivity of NiO near the Curie Temperature , 1958 .