Studies on Equivalent Viscosity of Particle-Reinforced Flexible Mold Materials Used in Soft Tooling Process

To reduce the cooling time in soft tooling process, one of the possible solutions is the use of composite mold materials, but that may affect melt mold flow properties. Therefore, a study on equivalent viscosity of melt mold material, which primarily influences the flow ability is essential. In this work, we have carried out an experimental study on equivalent viscosity of flexible mold materials (such as polyurethane and silicone rubber, which are of particular type) reinforced with highly thermal conductive filler particles, namely, aluminum and graphite powder. It has been observed that in addition to an increase of equivalent viscosity, different curing behaviors were noticed in mold materials reinforced with different fillers. By analyzing the performances of various equivalent viscosity models reported in literature, it has been observed that for higher particle size, the existing models deviate much from the experimental results. We have proposed an extension of the generalized model of Arefinia and Shojaei by including a factor that depends on particle size. It is found that the extension model provides better explanations compared to other models to the experimental results, especially for suspensions of flexible mold materials with higher particle sizes. Finally, a predictive approach is suggested for the equivalent viscosity of reinforced flexible mold materials, which may be useful to decide the amount of typical filler particles to be considered for mixing with a flexible mold material.

[1]  M. Mooney,et al.  The viscosity of a concentrated suspension of spherical particles , 1951 .

[2]  A. B. Metzner Rheology of Suspensions in Polymeric Liquids , 1985 .

[3]  K. Nandakumar,et al.  A theoretical correction of the Ouchiyama and Tanaka formula for predicting average porosity of packed beds consisting of nonuniform spheres , 1998 .

[4]  N. Standish,et al.  Porosity calculations of multi-component mixtures of spherical particles , 1987 .

[5]  P. E. Pierce,et al.  Application of ree-eyring generalized flow theory to suspensions of spherical particles , 1956 .

[6]  T. Kitano,et al.  An empirical equation of the relative viscosity of polymer melts filled with various inorganic fillers , 1981 .

[7]  Randall M. German,et al.  Particle packing characteristics , 1989 .

[8]  Howard A. Barnes,et al.  Measuring the viscosity of large-particle (and flocculated) suspensions — a note on the necessary gap size of rotational viscometers , 2000 .

[9]  N. Standish,et al.  Characterisation of non-spherical particles from their packing behaviour , 1993 .

[10]  Tatsuo Tanaka,et al.  Porosity estimation for random packings of spherical particles , 1984 .

[11]  F. de Larrard,et al.  Linear packing density model of grain mixtures , 1986 .

[12]  T. Allen Particle Size Measurement , 1965, Nature.

[13]  Andrzej Rosochowski,et al.  Rapid tooling: the state of the art , 2000 .

[14]  J. S. Chong,et al.  Rheology of concentrated suspensions , 1971 .

[15]  Thomas J. Dougherty,et al.  A Mechanism for Non‐Newtonian Flow in Suspensions of Rigid Spheres , 1959 .

[16]  A. Shojaei,et al.  On the viscosity of composite suspensions of aluminum and ammonium perchlorate particles dispersed in hydroxyl terminated polybutadiene--New empirical model. , 2006, Journal of colloid and interface science.

[17]  A. Einstein Eine neue Bestimmung der Moleküldimensionen , 1905 .

[18]  A. E. R. Westman,et al.  THE PACKING OF PARTICLES1 , 1930 .

[19]  Aibing Yu,et al.  Modifying the linear packing model for predicting the porosity of nonspherical particle mixtures , 1996 .

[20]  Aibing Yu,et al.  Evaluation of the packing characteristics of mono-sized non-spherical particles , 1996 .

[21]  David G. Thomas Transport characteristics of suspension: VIII. A note on the viscosity of Newtonian suspensions of uniform spherical particles , 1965 .

[22]  R. Crawford,et al.  The packing of particles , 1987 .

[23]  L. C. Graton,et al.  Systematic Packing of Spheres: With Particular Relation to Porosity and Permeability , 1935, The Journal of Geology.