Zinc–air fuel cell, a potential candidate for alternative energy

Abstract A zinc–air fuel cell (ZAFC), which generates electricity by the reaction between oxygen and zinc pallets in a liquid alkaline electrolyte, is a potential candidate for an alternative energy generator. It is efficient, completely renewable, and cheap in fabrication because precious metal catalysts are not necessary. In addition, it is environmentally benign because of producing solely recyclable zinc oxide without gas emission. It is applicable to portable, mobile, stationary, and military purposes. In spite of its high potential as an alternative power source, it is yet in a preliminary stage of commercialization because of a few uncertainties remained. This paper reviews the present status of the ZAFC technology and the problems to be overcome for further advancement toward the potential next-generation alternative energy.

[1]  Ian Brown,et al.  New developments in the Electric Fuel Ltd. zinc/air system , 1999 .

[2]  Wei Li,et al.  Preparation and characteristics of pretreated Pt/alumina catalysts for the preferential oxidation of carbon monoxide , 2009 .

[3]  Xiaogang Zhang,et al.  MnO2/MCMB electrocatalyst for all solid-state alkaline zinc-air cells , 2004 .

[4]  Eg G Technical Services Fuel Cell Handbook , 2006 .

[5]  S. Smedley A regenerative zinc air fuel cell for industrial and specialty vehicles , 2000, Fifteenth Annual Battery Conference on Applications and Advances (Cat. No.00TH8490).

[6]  Rongzhong Jiang Combinatorial electrochemical cell array for high throughput screening of micro-fuel-cells and metal/air batteries. , 2007, The Review of scientific instruments.

[7]  A. A. Mohamad Zn/gelled 6 M KOH/O2 zinc-air battery , 2006 .

[8]  Yang-Kook Sun,et al.  The roles and electrochemical characterizations of activated carbon in zinc air battery cathodes , 2006 .

[9]  Raihan Othman,et al.  Hydroponics gel as a new electrolyte gelling agent for alkaline zinc–air cells , 2001 .

[10]  K. Oyaizu,et al.  Cationic polysulfonium membrane as separator in zinc–air cell , 2003 .

[11]  Stuart I. Smedley,et al.  A regenerative zinc–air fuel cell , 2007 .

[12]  James Larminie,et al.  Fuel Cell Systems Explained , 2000 .

[13]  M. J. Riezenman Metal fuel cells [Zn-air fuel cells] , 2001 .

[14]  Donald R. Cahela,et al.  New structures of thin air cathodes for zinc–air batteries , 2003 .

[15]  Sung Taik Chung,et al.  Effect of anode diffusion media on direct formic acid fuel cells , 2008 .

[16]  B. Koretz,et al.  Regeneration of zinc anodes for the Electric Fuel(R) zinc-air refuelable EV battery system , 1997, IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203).

[17]  F. Shieu,et al.  Clay as a dispersant in the catalyst layer for zinc–air fuel cells , 2008 .

[18]  K. Kordesch,et al.  Can refillable alkaline methanol–air systems replace metal–air cells? , 2004 .

[19]  O. Haas,et al.  Optimized zinc electrode for the rechargeable zinc–air battery , 1998 .

[20]  Chang Woo Lee,et al.  Preliminary comparative studies of zinc and zinc oxide electrodes on corrosion reaction and reversible reaction for zinc/air fuel cells , 2006 .

[21]  P. J. Sebastian,et al.  Studies on the oxygen reduction catalyst for zinc–air battery electrode , 2003 .

[22]  C. Lee,et al.  Novel alloys to improve the electrochemical behavior of zinc anodes for zinc/air battery , 2006 .