Advances in reforming and partial oxidation of hydrocarbons for hydrogen production and fuel cell applications

Abstract One of the most attractive routes for the production of hydrogen or syngas for use in fuel cell applications is the reforming and partial oxidation of hydrocarbons. The use of hydrocarbons in high temperature fuel cells is achieved through either external or internal reforming. Reforming and partial oxidation catalysis to convert hydrocarbons to hydrogen rich syngas plays an important role in fuel processing technology. The current research in the area of reforming and partial oxidation of methane, methanol and ethanol includes catalysts for reforming and oxidation, methods of catalyst synthesis, and the effective utilization of fuel for both external and internal reforming processes. In this paper the recent progress in these areas of research is reviewed along with the reforming of liquid hydrocarbons, from this an overview of the current best performing catalysts for the reforming and partial oxidizing of hydrocarbons for hydrogen production is summarized.

[1]  Wang Shaoliang,et al.  Preparation and performance of a Cu–CeO2–ScSZ composite anode for SOFCs running on ethanol fuel , 2007 .

[2]  Lidong Li,et al.  Effect of NiAl2O4 Formation on Ni/Al2O3 Stability during Dry Reforming of Methane , 2015 .

[3]  G. Xu,et al.  Tuning the metal-support interaction in catalysts for highly efficient methane dry reforming reaction , 2016 .

[4]  E. Foletto,et al.  Preparation of Ni/Pt catalysts supported on spinel (MgAl2O4) for methane reforming , 2006 .

[5]  C. Papp,et al.  Effects of Support and Rh Additive on Co-Based Catalysts in the Ethanol Steam Reforming Reaction , 2014 .

[6]  J. P. Holgado,et al.  Synthesis and characterization of a LaNiO3 perovskite as precursor for methane reforming reactions catalysts , 2010 .

[7]  T. Choudhary,et al.  Partial oxidation of methane to syngas with or without simultaneous steam or CO2 reforming over a high-temperature stable-NiCoMgCeOx supported on zirconia–hafnia catalyst , 2006 .

[8]  X. Tan,et al.  The catalytic effects of La0.3Sr0.7Fe0.7Cu0.2Mo0.1O3 perovskite and its hollow fibre membrane for air separation and methane conversion reactions , 2015 .

[9]  R. Bal,et al.  Defect-Induced Efficient Partial Oxidation of Methane over Nonstoichiometric Ni/CeO2 Nanocrystals , 2015 .

[10]  Xionggang Lu,et al.  Perovskite LaNiO3 Nanocrystals inside SBA‐15 Silica: High Stability and Anti‐Coking Performance in the Pre‐Reforming of Liquefied Petroleum Gas at a Low Steam‐to‐Carbon Molar Ratio , 2016 .

[11]  Ping Liu,et al.  Direct octane fuel cells: A promising power for transportation , 2012 .

[12]  H. Chen,et al.  Kinetics Analysis and Process Simulation for Sorption-Enhanced Steam Methane Reforming , 2012 .

[13]  J. Fierro,et al.  Structural features and performance of LaNi1 xRhxO3 system for the dry reforming of methane , 2008 .

[14]  M. Segarra,et al.  Performance and stability of La0.5Sr0.5CoO3−δ perovskite as catalyst precursor for syngas production by partial oxidation of methane , 2014 .

[15]  A. Weidenkaff,et al.  Methanol steam reforming on LaCo1−x−yPdxZnyO3±δ , 2015 .

[16]  Danyan Feng,et al.  Anodic TiO2 nanotube array supported nickel – noble metal bimetallic catalysts for activation of CH4 and CO2 to syngas , 2014 .

[17]  Jianjun Liu,et al.  Nickel‐Supported on La2Sn2O7 and La2Zr2O7 Pyrochlores for Methane Steam Reforming: Insight into the Difference between Tin and Zirconium in the B Site of the Compound , 2014 .

[18]  W. Bujalski,et al.  Characterization and activity test of commercial Ni/Al2O3, Cu/ZnO/Al2O3 and prepared Ni–Cu/Al2O3 catalysts for hydrogen production from methane and methanol fuels , 2013 .

[19]  M. C. Rangel,et al.  Ni‐Catalysts Supported on Gd‐Doped Ceria for Solid Oxide Fuel Cells in Methane Steam Reforming , 2014 .

[20]  Michela Signoretto,et al.  TiO2–supported catalysts for the steam reforming of ethanol , 2014 .

[21]  Zongping Shao,et al.  Lithium and lanthanum promoted Ni-Al2O3 as an active and highly coking resistant catalyst layer for solid-oxide fuel cells operating on methane , 2011 .

[22]  José Mansur Assaf,et al.  Autothermal reforming of methane over Ni/γ-Al2O3 catalysts: the enhancement effect of small quantities of noble metals , 2004 .

[23]  I. Song,et al.  Hydrogen production by steam reforming of methanol in a micro-channel reactor coated with Cu/ZnO/ZrO2/Al2O3 catalyst , 2006 .

[24]  Adélio Mendes,et al.  Catalysts for methanol steam reforming—A review , 2010 .

[25]  Wei Wang,et al.  Enhanced electrochemical performance, water storage capability and coking resistance of a Ni+BaZr0.1Ce0.7Y0.1Yb0.1O3−δ anode for solid oxide fuel cells operating on ethanol , 2015 .

[26]  M. Walluk,et al.  Bio-fuel reformation for solid oxide fuel cell applications. Part 3: Biodiesel–diesel blends , 2014 .

[27]  John B. Goodenough,et al.  Alternative anode materials for solid oxide fuel cells , 2007 .

[28]  Á. Imre-Lucaci,et al.  Hydrogen production by ethanol steam reforming on nickel catalysts: Effect of support modification by CeO2 and La2O3 , 2015 .

[29]  Chenghao Yang,et al.  Direct-methane solid oxide fuel cells with Cu1.3Mn1.7O4 spinel internal reforming layer , 2010 .

[30]  B. Steele,et al.  Materials for fuel-cell technologies , 2001, Nature.

[31]  K. Zhao,et al.  Perovskite-type oxides LaFe1−xCoxO3 for chemical looping steam methane reforming to syngas and hydrogen co-production , 2016 .

[32]  U. Stimming,et al.  Recent anode advances in solid oxide fuel cells , 2007 .

[33]  Yao Yao,et al.  Highly Active and Stable Lanthanum‐doped Core–Shell‐structured Ni@SiO2 Catalysts for the Partial Oxidation of Methane to Syngas , 2013 .

[34]  R. Lødeng,et al.  Effects of Noble Metal Promoters on In Situ Reduced Low Loading Ni Catalysts for Methane Activation , 2010 .

[35]  V. Parmon,et al.  Syngas production by partial oxidation of methane in a microchannel reactor over a Ni–Pt/La0.2Zr0.4Ce0.4Ox catalyst , 2015 .

[36]  N. Nichio,et al.  Role of chromium in the stability of Ni/Al2O3 catalysts for natural gas reforming , 2000 .

[37]  Ping Liu,et al.  One step synthesis of mesoporous NiO–Al2O3 catalyst for partial oxidation of methane to syngas: The role of calcination temperature , 2015 .

[38]  F. Basile,et al.  Rh-Ni synergy in the catalytic partial oxidation of methane: surface phenomena and catalyst stability , 2002 .

[39]  Haibin Li,et al.  Synthesis Gas Generation by Chemical-Looping Reforming Using Ce-Based Oxygen Carriers Modified with Fe, Cu, and Mn Oxides , 2009 .

[40]  Andrew Dicks,et al.  Catalytic aspects of the steam reforming of hydrocarbons in internal reforming fuel cells , 1997 .

[41]  H. Hosono,et al.  Partial oxidation of methane to syngas over promoted C12A7 , 2004 .

[42]  Rufino M. Navarro,et al.  Production of hydrogen from methanol over Cu/ZnO catalysts promoted by ZrO2 and Al2O3 , 2003 .

[43]  X. Verykios,et al.  The study of the performance of PtNi/CeO2–nanocube catalysts for low temperature steam reforming of ethanol , 2015 .

[44]  L. Pino,et al.  Syngas production by methane oxy-steam reforming on Me/CeO2 (Me = Rh, Pt, Ni) catalyst lined on cordierite monoliths , 2015 .

[45]  M. Larrubia,et al.  Nanostructured Pt- and Ni-based catalysts for CO2-reforming of methane , 2010 .

[46]  Shuben Li,et al.  Partial oxidation of methane to carbon monoxide and hydrogen over NiO/La2O3/γ-Al2O3 catalyst , 1996 .

[47]  V. Choudhary,et al.  Beneficial Effects of Noble Metal Addition to Ni/Al2O3 Catalyst for Oxidative Methane-to-Syngas Conversion , 1995 .

[48]  H. Arandiyan,et al.  Methane reforming to syngas over LaNixFe1−xO3 (0 ≤ x ≤ 1) mixed-oxide perovskites in the presence of CO2 and O2 , 2012 .

[49]  A. Adesina,et al.  Catalyst design for methane steam reforming , 2014 .

[50]  D. Zanchet,et al.  Alumina-supported Ni catalysts modified with silver for the steam reforming of methane: Effect of Ag on the control of coke formation , 2007 .

[51]  Raymond J. Gorte,et al.  High‐Performance SOFC Cathodes Prepared by Infiltration , 2009 .

[52]  Allan J. Jacobson,et al.  Materials for Solid Oxide Fuel Cells , 2010 .

[53]  Jianli Hu,et al.  An overview of hydrogen production technologies , 2009 .

[54]  Maohong Fan,et al.  Progress in oxygen carrier development of methane-based chemical-looping reforming: A review , 2015 .

[55]  Changling Yu,et al.  Novel Ni/CeO2-Al2O3 composite catalysts synthesized by one-step citric acid complex and their performance in catalytic partial oxidation of methane , 2014 .

[56]  C. Gennequin,et al.  A highly reactive and stable Ru/Co6−xMgxAl2 catalyst for hydrogen production via methane steam reforming , 2014 .

[57]  Shaobin Wang,et al.  Influences of doping Cr/Fe/Ta on the performance of Ni/CeO2 catalyst under microwave irradiation in dry reforming of CH4 , 2016 .

[58]  J. Bokhoven,et al.  Understanding the effect of Sm2O3 and CeO2 promoters on the structure and activity of Rh/Al2O3 catalysts in methane steam reforming , 2012 .

[59]  H. Arandiyan,et al.  Production of Syngas by CO2 Reforming on MxLa1−xNi0.3Al0.7O3−d (M = Li, Na, K) Catalysts , 2008 .

[60]  Yann Bultel,et al.  A Solid Oxide Fuel Cell Operating in Gradual Internal Reforming Conditions under Pure Dry Methane , 2008 .

[61]  F. B. Noronha,et al.  Nickel/gadolinium-doped ceria anode for direct ethanol solid oxide fuel cell , 2014 .

[62]  Liquan Chen,et al.  Investigations of mesoporous CeO2–Ru as a reforming catalyst layer for solid oxide fuel cells , 2006 .

[63]  A. Ohmura,et al.  An Octane-Fueled Solid Oxide Fuel Cell , 2011 .

[64]  Chang Won Yoon,et al.  Enhanced oxygen storage capacity of Ce0.65Hf0.25M0.1O2-δ (M=rare earth elements): Applications to methane steam reforming with high coking resistance , 2014 .

[65]  Guoxing Xiong,et al.  The effect of Li and La on NiO/Al2O3 catalyst for CH4/O2 to syngas reaction , 1999 .

[66]  Sufang Wu,et al.  The microstructure and stability of a Ni-nano-CaO/Al2O3 reforming catalyst under carbonation–calcination cycling conditions , 2015 .

[67]  Misook Kang,et al.  Hydrogen rich production by ethanol steam reforming reaction over Mn/Co10Si90MCM-48 catalysts , 2014 .

[68]  M. G. Zimicz,et al.  Ni–Cu/Ce0.9Zr0.1O2 bimetallic cermets for electrochemical and catalytic applications , 2014 .

[69]  A. Yaroslavtsev,et al.  Influence of the support structure and composition of Ni–Cu-based catalysts on hydrogen production by methanol steam reforming , 2015 .

[70]  Z. Yaakob,et al.  Direct decomposition of methane over SBA-15 supported Ni, Co and Fe based bimetallic catalysts , 2015 .

[71]  Chenghao Yang,et al.  Intermediate temperature solid oxide fuel cells with Cu1.3Mn1.7O4 internal reforming layer , 2012 .

[72]  Tak-Hyoung Lim,et al.  The kinetics of steam methane reforming over a Ni/γ-Al2O3 catalyst for the development of small stationary reformers , 2015 .

[73]  W. Bujalski,et al.  Nickel–silica core@shell catalyst for methane reforming , 2013 .

[74]  R. K. Toghiani,et al.  Activation of methane to syngas over a Ni/TiO2 catalyst , 2003 .

[75]  X. Bai,et al.  Regenerable and durable catalyst for hydrogen production from ethanol steam reforming , 2011 .

[76]  D. Zanchet,et al.  The effects of Pt promotion on the oxi-reduction properties of alumina supported nickel catalysts for oxidative steam-reforming of methane: Temperature-resolved XAFS analysis , 2009 .

[77]  Dennis Y.C. Leung,et al.  A review of biomass-derived fuel processors for fuel cell systems , 2009 .

[78]  S. Specchia,et al.  MgO and Nb2O5 oxides used as supports for Ru-based catalysts for the methane steam reforming reaction , 2015 .

[79]  Antonio Medina Neto,et al.  Influence of the CeO2 and Nb2O5 supports and the inert gas in ethanol steam reforming for H2 production , 2015 .

[80]  Malcolm L. H. Green,et al.  Partial oxidation of methane to synthesis gas, and carbon dioxide as an oxidising agent for methane conversion , 1992 .

[81]  Shigetaka Wada,et al.  Effect of CaO–ZrO2 addition to Ni supported on γ-Al2O3 by sequential impregnation in steam methane reforming , 2010 .

[82]  E. Ruckenstein,et al.  Partial Oxidation of Methane to Synthesis Gas over Alkaline Earth Metal Oxide Supported Cobalt Catalysts , 2001 .

[83]  Helena Hagelin‐Weaver,et al.  Steam reforming of methanol over CeO2- and ZrO2-promoted Cu-ZnO catalysts supported on nanoparticle Al2O3 , 2009 .

[84]  A. Basile,et al.  Methanol steam reforming for hydrogen generation via conventional and membrane reactors: A review , 2014 .

[85]  M. Khan,et al.  Catalytic performance of ceria-supported cobalt catalyst for CO-rich hydrogen production from dry reforming of methane , 2016 .

[86]  Wei Chen,et al.  High carbon-resistance Ni/CeAlO3-Al2O3 catalyst for CH4/CO2 reforming , 2013 .

[87]  Qiang Sun,et al.  Solid Oxide Fuel Cell Anode Materials for Direct Hydrocarbon Utilization , 2012 .

[88]  Satoshi Hamakawa,et al.  Steam Reforming of Methanol Over Cu/CeO2 Catalysts Studied in Comparison with Cu/ZnO and Cu/Zn(Al)O Catalysts , 2003 .

[89]  Agus Haryanto,et al.  Current status of hydrogen production techniques by steam reforming of ethanol : A review , 2005 .

[90]  A. M. Efstathiou,et al.  Effect of support composition on the origin and reactivity of carbon formed during dry reforming of methane over 5wt% Ni/Ce1−xMxO2−δ (M=Zr4+, Pr3+) catalysts , 2016 .

[91]  P. S. Pizani,et al.  Catalytic partial oxidation and steam reforming of methane on La2O3–Al2O3 supported Pt catalysts as observed by X-ray absorption spectroscopy , 2012 .

[92]  C. H. Bartholomew,et al.  Heterogeneous Catalyst Deactivation and Regeneration: A Review , 2015 .

[93]  Zhen Zhao,et al.  Effect of the transition metal oxide supports on hydrogen production from bio-ethanol reforming , 2012 .

[94]  yaaaa V. 4Arams,et al.  Production of Synthesis Gas , 2020, Synthesis Gas.

[95]  Haihui Wang,et al.  Oxygen permeability and structure stability of a novel cobalt-free perovskite Gd0.33Ba0.67FeO3−δ , 2014 .

[96]  G. Han,et al.  Dynamic hydrogen production from ethanol steam‐reforming reaction on NixMoy/SBA‐15 catalytic system , 2015 .

[97]  A. J. Murrell,et al.  Selective oxidation of methane to synthesis gas using transition metal catalysts , 1990, Nature.

[98]  Zhixian Gao,et al.  Cu-Al spinel oxide as an efficient catalyst for methanol steam reforming. , 2014, Angewandte Chemie.

[99]  Raymond J. Gorte,et al.  Ceria-Based Anodes for the Direct Oxidation of Methane in Solid Oxide Fuel Cells , 1995 .

[100]  Malcolm L. H. Green,et al.  Partial oxidation of methane to synthesis gas using carbon dioxide , 1991, Nature.

[101]  Huaiyu Zhu,et al.  A NiFeCu alloy anode catalyst for direct-methane solid oxide fuel cells , 2014 .

[102]  S. Adhikari,et al.  Hydrogen production from glycerol: An update , 2009 .

[103]  Ping Liu,et al.  Promotion of water-mediated carbon removal by nanostructured barium oxide/nickel interfaces in solid oxide fuel cells , 2011, Nature communications.

[104]  Hua Wang,et al.  Ce–Fe oxygen carriers for chemical-looping steam methane reforming , 2013 .

[105]  T. Sano,et al.  Promoting effect of Rh, Pd and Pt noble metals to the Ni/Mg(Al)O catalysts for the DSS-like operation in CH4 steam reforming , 2006 .

[106]  Tao Sh.W.,et al.  Catalytic Properties of the Perovskite Oxide La0.75Sr0.25Cr0.5Fe0.5O3-δ in Relation to Its Potential as a Solid Oxide Fuel Cell Anode Material , 2004 .

[107]  John B Goodenough,et al.  Double Perovskites as Anode Materials for Solid-Oxide Fuel Cells , 2006, Science.

[108]  Yuan Liu,et al.  La1−xKxFe0.7Ni0.3O3 catalyst for ethanol steam reforming—The effect of K-doping , 2016 .

[109]  Guntae Kim,et al.  Assessment of perovskite-type La0.8Sr0.2ScxMn1−xO3–δ oxides as anodes for intermediate-temperature solid oxide fuel cells using hydrocarbon fuels , 2011 .

[110]  Andrew Murray,et al.  Cell cycle: A snip separates sisters , 1999, Nature.

[111]  Alejandro J. Santis-Alvarez,et al.  Comparison of flame-made rhodium on Al2O3 or Ce0.5Zr0.5O2 supports for the partial oxidation of methane , 2014 .

[112]  B. Liaw,et al.  Steam reforming of methanol over CuO/ZnO/CeO2/ZrO2/Al2O3 catalysts , 2009 .

[113]  John M. Vohs,et al.  Nanostructured anodes for solid oxide fuel cells , 2009 .

[114]  J. Múnera,et al.  Supported Rh nanoparticles on CaO–SiO2 binary systems for the reforming of methane by carbon dioxide in membrane reactors , 2014 .

[115]  A. Ghenciu,et al.  Review of fuel processing catalysts for hydrogen production in PEM fuel cell systems , 2002 .

[116]  Jens K. Nørskov,et al.  First-principles investigations of the Ni3Sn alloy at steam reforming conditions , 2009 .

[117]  Mireya R. Goldwasser,et al.  CO2 reforming of CH4 over Co–La-based perovskite-type catalyst precursors , 2013 .

[118]  Yong Lu,et al.  The promoting role of Ag in Ni-CeO2 catalyzed CH4-CO2 dry reforming reaction , 2015 .

[119]  M. Ocsachoque,et al.  Experimental and theoretical study about sulfur deactivation of Ni/ CeO2 and Rh/CeO2 catalysts , 2016 .

[120]  D. Zanchet,et al.  Study of the properties of supported Pd catalysts for steam and autothermal reforming of methane , 2014 .

[121]  J. Irvine,et al.  Structure, conductivity and redox reversibility of Ca-doped cerium metavanadate , 2011 .

[122]  Lidong Li,et al.  Controlled Surface Segregation Leads to Efficient Coke‐Resistant Nickel/Platinum Bimetallic Catalysts for the Dry Reforming of Methane , 2015 .

[123]  J. Assaf,et al.  Structural features of La1-xCexNiO3 mixed oxides and performance for the dry reforming of methane , 2006 .

[124]  A. Lemonidou,et al.  State-of-the-art catalysts for CH4 steam reforming at low temperature , 2014 .

[125]  H. Hwang,et al.  Catalytic activity of perovskite-type doped La0.08Sr0.92Ti1−xMxO3−δ (M = Mn, Fe, and Co) oxides for methane oxidation , 2014 .

[126]  E. Ruckenstein,et al.  Conversions of Methane to Synthesis Gas over Co/γ-Al2O3 by CO2 and/or O2 , 2001 .

[127]  F. Chen,et al.  Direct-Methane Solid Oxide Fuel Cells with Hierarchically Porous Ni-Based Anode Deposited with Nanocatalyst Layer , 2014 .

[128]  Kuan-Fu Ho,et al.  Catalytic performance of Pt-promoted cobalt-based catalysts for the steam reforming of ethanol , 2014 .

[129]  M. E. Bretado,et al.  Enhanced ethanol steam reforming by CO2 absorption using CaO, CaO*MgO or Na2ZrO3 , 2014 .

[130]  Xianglan Xu,et al.  Methane Dry Reforming over Coke‐Resistant Mesoporous Ni‐Al2O3 Catalysts Prepared by Evaporation‐Induced Self‐Assembly Method , 2015 .

[131]  Zongping Shao,et al.  Physically mixed LiLaNi–Al2O3 and copper as conductive anode catalysts in a solid oxide fuel cell for methane internal reforming and partial oxidation , 2011 .

[132]  S. A. Barnett,et al.  A direct-methane fuel cell with a ceria-based anode , 1999, Nature.

[133]  Nguyen Q. Minh,et al.  Solid oxide fuel cell technology—features and applications , 2004 .

[134]  R. Gorte,et al.  Direct hydrocarbon solid oxide fuel cells. , 2004, Chemical reviews.

[135]  S. Linic,et al.  Comparative study of the kinetics of methane steam reforming on supported Ni and Sn/Ni alloy catalysts: The impact of the formation of Ni alloy on chemistry , 2009 .

[136]  John T. S. Irvine,et al.  A redox-stable efficient anode for solid-oxide fuel cells , 2003, Nature materials.

[137]  C. Yeh,et al.  Pathways of ethanol steam reforming over ceria-supported catalysts , 2012 .

[138]  G. Madras,et al.  Production of syngas from steam reforming and CO removal with water gas shift reaction over nanosized Zr0.95Ru0.05O2−δ solid solution , 2013 .

[139]  V. Almăşan,et al.  Supported nickel catalysts for low temperature methane steam reforming: comparison between metal additives and support modification , 2012, Reaction Kinetics, Mechanisms and Catalysis.

[140]  Dazhi Wang,et al.  Hydrogen production from ethanol steam reforming over Rh/CeO2 catalyst , 2015 .

[141]  S. Moon,et al.  Performance of La1−xCexFe0.7Ni0.3O3 perovskite catalysts for methane steam reforming , 2009 .

[142]  A. G. Gribovskiy,et al.  Influence of a reaction mixture streamline on partial oxidation of methane in an asymmetric microchannel reactor , 2014 .

[143]  Qinghua Liu,et al.  Synergy effect of MgO and ZnO in a Ni/Mg–Zn–Al catalyst during ethanol steam reforming for H2-rich gas production , 2011 .

[144]  O. Deutschmann,et al.  Methane reforming kinetics within a Ni–YSZ SOFC anode support , 2005 .

[145]  J. Assaf,et al.  Catalytic evaluation of perovskite-type oxide LaNi1−xRuxO3 in methane dry reforming , 2008 .

[146]  L. Barelli,et al.  Hydrogen production through sorption-enhanced steam methane reforming and membrane technology : A review , 2008 .

[147]  G. Słowik,et al.  Comparative study on steam and oxidative steam reforming of ethanol over 2KCo/ZrO2 catalyst , 2015 .

[148]  S. Kawi,et al.  Yolk–Satellite–Shell Structured Ni–Yolk@Ni@SiO2 Nanocomposite: Superb Catalyst toward Methane CO2 Reforming Reaction , 2014 .

[149]  Zongping Shao,et al.  A high-performance cathode for the next generation of solid-oxide fuel cells , 2004, Nature.

[150]  Shaohua Zhang,et al.  An active and coke-resistant dry reforming catalyst comprising nickel–tungsten alloy nanoparticles , 2015 .

[151]  U. Graham,et al.  Ethanol decomposition and steam reforming of ethanol over CeZrO2 and Pt/CeZrO2 catalyst: Reaction mechanism and deactivation , 2009 .

[152]  Y. Matsumura,et al.  Suppression of CO by-production in steam reforming of methanol by addition of zinc oxide to silica-supported copper catalyst , 2009 .

[153]  M. G. Norton,et al.  Retraction: High‐Performance Molybdenum Dioxide‐Based Anode for Dodecane‐Fueled Solid‐Oxide Fuel Cells (SOFCs) , 2014 .

[154]  Y. Sekine,et al.  Catalytic activities and coking resistance of Ni/perovskites in steam reforming of methane , 2005 .

[155]  Bengt Sundén,et al.  Review of catalyst materials and catalytic steam reforming reactions in SOFC anodes , 2011 .

[156]  James Spivey,et al.  A review of dry (CO2) reforming of methane over noble metal catalysts. , 2014, Chemical Society reviews.

[157]  John T. S. Irvine,et al.  Recent Progress in the Development of Anode Materials for Solid Oxide Fuel Cells , 2011 .

[158]  T. Choudhary,et al.  Oxy-methane reforming over high temperature stable NiCoMgCeO and NiCoMgO supported on zirconia–haffnia catalysts: Accelerated sulfur deactivation and regeneration , 2007 .

[159]  J. Fierro,et al.  Rh/Al2O3–La2O3 catalysts promoted with CeO2 for ethanol steam reforming reaction , 2015 .

[160]  J. Bueno,et al.  Surface and structural features of Pt/PrO2–Al2O3 catalysts for dry methane reforming , 2014 .

[161]  Sung Su Kim,et al.  Effect of Ce/Ti ratio on the catalytic activity and stability of Ni/CeO2–TiO2 catalyst for dry reforming of methane , 2015 .

[162]  M. Larrubia,et al.  NiBa catalysts for CO2-reforming of methane , 2010 .

[163]  Eric Liese,et al.  Performance Comparison of Internal Reforming Against External Reforming in a Solid Oxide Fuel Cell, Gas Turbine Hybrid System , 2005 .

[164]  Rashmi Chaubey,et al.  A review on development of industrial processes and emerging techniques for production of hydrogen from renewable and sustainable sources , 2013 .

[165]  D. Brett,et al.  Intermediate temperature solid oxide fuel cells. , 2008, Chemical Society reviews.

[166]  Shaohua Zhang,et al.  Catalytic role of β-Mo2C in DRM catalysts that contain Ni and Mo , 2015 .

[167]  Misook Kang,et al.  Effect of MnOx in the catalytic stabilization of Co2MnO4 spinel during the ethanol steam reforming reaction , 2015 .

[168]  H. Morioka,et al.  Active Cu/ZnO and Cu/ZnO/Al2O3 catalysts prepared by homogeneous precipitation method in steam reforming of methanol , 2004 .

[169]  Hua Wang,et al.  Chemical-Looping Steam Methane Reforming over a CeO2–Fe2O3 Oxygen Carrier: Evolution of Its Structure and Reducibility , 2014 .

[170]  Hua Wang,et al.  Enhanced Activity of CeO2–ZrO2 Solid Solutions for Chemical-Looping Reforming of Methane via Tuning the Macroporous Structure , 2016 .

[171]  S. McIntosh,et al.  Properties and Performance of Anode-Supported Proton-Conducting BaCe0.48Zr0.4Yb0.1Co0.02O3-δ Solid Oxide Fuel Cells , 2010 .

[172]  M. Marelli,et al.  Coprecipitation versus chemical vapour deposition to prepare Rh/Ni bimetallic catalysts , 2015 .

[173]  G. Pantaleo,et al.  Bi- and trimetallic Ni catalysts over Al2O3 and Al2O3-MOx (M = Ce or Mg) oxides for methane dry reforming: Au and Pt additive effects , 2014 .

[174]  F. Basile,et al.  Partial oxidation of methane. Effect of reaction parameters and catalyst composition on the thermal profile and heat distribution , 2001 .

[175]  Caine M. Finnerty,et al.  REFORMING CATALYSTS FOR HYDROGEN GENERATION IN FUEL CELL APPLICATIONS , 2006 .

[176]  M. Segarra,et al.  Steam reforming and oxidative steam reforming of ethanol over La0.6Sr0.4CoO3−δ perovskite as catalyst precursor for hydrogen production , 2015 .

[177]  A. Kiennemann,et al.  Partial oxidation of methane to produce syngas over a neodymium-calcium cobaltate-based catalyst , 2015 .

[178]  Chusheng Chen,et al.  La2NiO4 tubular membrane reactor for conversion of methane to syngas , 2003 .

[179]  J. Papavasiliou,et al.  Steam reforming of methanol over copper-manganese spinel oxide catalysts , 2005 .

[180]  W. Fang,et al.  Highly loaded well dispersed stable Ni species in NiXMg2AlOY nanocomposites: Application to hydrogen production from bioethanol , 2015 .

[181]  G. Bonura,et al.  H2 production for MC fuel cell by steam reforming of ethanol over MgO supported Pd, Rh, Ni and Co catalysts , 2004 .

[182]  Zongping Shao,et al.  A new Gd-promoted nickel catalyst for methane conversion to syngas and as an anode functional layer , 2011 .

[183]  Shibin Liu,et al.  Coking resistant Ni/ZrO2@SiO2 catalyst for the partial oxidation of methane to synthesis gas , 2015 .

[184]  Hary Devianto,et al.  The catalytic performance of Ni/MgSiO3 catalyst for methane steam reforming in operation of direct internal reforming MCFC , 2010 .

[185]  Yu Guo,et al.  An anodic alumina supported Ni–Pt bimetallic plate-type catalysts for multi-reforming of methane, kerosene and ethanol , 2014 .

[186]  Zongping Shao,et al.  A High‐Performance Cathode for the Next Generation of Solid‐Oxide Fuel Cells. , 2004 .

[187]  R. Hayes,et al.  Methane oxidation over Pt, Pt:Pd, and Pd based catalysts: Effects of pre‐treatment , 2015 .

[188]  M. Labaki,et al.  Hydrogen production by methane steam reforming over Ru supported on Ni–Mg–Al mixed oxides prepared via hydrotalcite route , 2015 .

[189]  Yuefang Wang,et al.  Numerical Investigation of the Sorption Enhanced Steam Methane Reforming in a Fluidized Bed Reactor , 2012 .

[190]  Fanxing Li,et al.  Coke-resistant Ni@SiO2 catalyst for dry reforming of methane , 2015 .

[191]  Zongping Shao,et al.  Development of a Ni-Ce0.8Zr0.2O2 catalyst for solid oxide fuel cells operating on ethanol through internal reforming , 2011 .

[192]  J. Bilbao,et al.  Effect of calcination/reduction conditions of Ni/La2O3–αAl2O3 catalyst on its activity and stability for hydrogen production by steam reforming of raw bio-oil/ethanol , 2014 .

[193]  Wuzong Zhou,et al.  Disruption of extended defects in solid oxide fuel cell anodes for methane oxidation , 2006, Nature.

[194]  John T. S. Irvine,et al.  Layered oxygen-deficient double perovskite as an efficient and stable anode for direct hydrocarbon solid oxide fuel cells. , 2015, Nature materials.

[195]  R. Mark Ormerod,et al.  A novel perovskite based catalyst with high selectivity and activity for partial oxidation of methane for fuel cell applications. , 2014, Dalton transactions.

[196]  Shawn D. Lin,et al.  Sustainable hydrogen production by ethanol steam reforming using a partially reduced copper-nickel oxide catalyst. , 2015, ChemSusChem.

[197]  G. Moradi,et al.  The influence of partial substitution of alkaline earth with La in the LaNiO3 perovskite catalyst , 2012 .

[198]  D. Harrison Sorption-Enhanced Hydrogen Production: A Review , 2008 .

[199]  E. Wachsman,et al.  Lowering the Temperature of Solid Oxide Fuel Cells , 2011, Science.

[200]  W. Cui,et al.  Partial oxidation of methane to syngas over nickel-based catalysts modified by alkali metal oxide and rare earth metal oxide , 1997 .

[201]  D. Zanchet,et al.  Toward Understanding Metal-Catalyzed Ethanol Reforming , 2015 .

[202]  Pascale Massiani,et al.  Highly active and stable Ni/SBA-15 catalysts prepared by a “two solvents” method for dry reforming of methane , 2016 .

[203]  M. Schmal,et al.  LaCoO3 perovskite on ceramic monoliths – Pre and post reaction analyzes of the partial oxidation of methane , 2014 .

[204]  M. Engelhard,et al.  New insights into reaction mechanisms of ethanol steam reforming on Co–ZrO2 , 2015 .

[205]  Wang Shaoliang,et al.  Preparation and performance characterization of the Fe–Ni/ScSZ cermet anode for oxidation of ethanol fuel in SOFCs , 2007 .

[206]  D. Kunzru,et al.  Steam reforming of ethanol on Ni–CeO2–ZrO2 catalysts: Effect of doping with copper, cobalt and calcium , 2007 .

[207]  Anders Holmen,et al.  A review of catalytic partial oxidation of methane to synthesis gas with emphasis on reaction mechanisms over transition metal catalysts , 2008 .

[208]  Suljo Linic,et al.  Promotion of the long-term stability of reforming Ni catalysts by surface alloying , 2007 .

[209]  I. Córdova,et al.  Catalysts for H2 production using the ethanol steam reforming (a review) , 2014 .

[210]  J. Wu,et al.  Bimetallic Rh–Ni/BN catalyst for methane reforming with CO2 , 2009 .

[211]  E. Assaf,et al.  Ni catalysts with Mo promoter for methane steam reforming , 2009 .

[212]  Xiao-guang Xie,et al.  Microwave effect on partial oxidation of methane to syngas , 1999 .

[213]  M. G. Norton,et al.  Molybdenum dioxide-based anode for solid oxide fuel cell applications , 2013 .

[214]  Frank A. Coutelieris,et al.  Electricity from ethanol fed SOFCs: the expectations for sustainable development and technological benefits , 2004 .

[215]  Jixiang Chen,et al.  Synthesis gas production from dry reforming of methane over Ce0.75Zr0.25O2-supported Ru catalysts , 2010 .

[216]  Ki Bong Lee,et al.  Production of fuel-cell grade hydrogen by thermal swing sorption enhanced reaction concept , 2008 .

[217]  M. Flytzani-Stephanopoulos,et al.  A study of Ni/Al2O3 and Ni–La/Al2O3 catalysts for the steam reforming of ethanol and phenol , 2015 .

[218]  S. Casale,et al.  Partial oxidation of methane on NixAlBEA and NixSiBEA zeolite catalysts: Remarkable effect of preparation procedure and Ni content , 2014 .

[219]  M. Larrubia,et al.  Improved Pt-Ni nanocatalysts for dry reforming of methane , 2010 .

[220]  Chun-Zhu Li,et al.  Hierarchically structured NiO/CeO2 nanocatalysts templated by eggshell membranes for methane steam reforming , 2014 .

[221]  Jurka Batista,et al.  Efficient catalytic abatement of greenhouse gases: Methane reforming with CO2 using a novel and thermally stable Rh–CeO2 catalyst , 2012 .

[222]  Weiqi Wang,et al.  Steam reforming of methane over Ni/SiO2 catalyst with enhanced coke resistance at low steam to methane ratio , 2015 .

[223]  S. Singhal,et al.  Advanced anodes for high-temperature fuel cells , 2004, Nature materials.

[224]  Helen Y. Luo,et al.  Ultra-low loading Ru/γ-Al2O3: A highly active and stable catalyst for low temperature solar thermal reforming of methane , 2015 .

[225]  Zongping Shao,et al.  Nickel-based anode with water storage capability to mitigate carbon deposition for direct ethanol solid oxide fuel cells. , 2014, ChemSusChem.

[226]  S. Baek,et al.  A diesel-driven, metal-based solid oxide fuel cell , 2014 .

[227]  Shawn D. Lin,et al.  Effects of the pretreatment of CuNi/SiO2 on ethanol steam reforming: Influence of bimetal morphology , 2014 .

[228]  Meilin Liu,et al.  Enhancing Sulfur Tolerance of a Ni-YSZ Anode through BaZr0.1Ce0.7Y0.1Yb0.1O3−δ Infiltration , 2014 .

[229]  E. Assaf,et al.  Combination of dry reforming and partial oxidation of methane on NiO–MgO–ZrO2 catalyst: Effect of nickel content , 2013 .

[230]  C. Ooi,et al.  Review of methanol reforming-Cu-based catalysts, surface reaction mechanisms, and reaction schemes , 2013 .

[231]  Zongping Shao,et al.  Combustion-synthesized Ru-Al2O3 composites as anode catalyst layer of a solid oxide fuel cell operating on methane , 2011 .

[232]  Brian F. G. Johnson,et al.  Hydrogen or synthesis gas production via the partial oxidation of methane over supported nickel–cobalt catalysts , 2007 .

[233]  P. Mondal,et al.  Support interaction of Ni nanocluster based catalysts applied in CO2 reforming , 2015 .

[234]  Yongchen Song,et al.  Solid sorbents for in-situ CO2 removal during sorption-enhanced steam reforming process: A review , 2016 .

[235]  G. Pantaleo,et al.  Synthesis and support composition effects on CH4 partial oxidation over Ni–CeLa oxides , 2015 .

[236]  Kangnian Fan,et al.  Production of hydrogen by steam reforming of methanol over Cu/ZnO catalysts prepared via a practical soft reactive grinding route based on dry oxalate-precursor synthesis , 2007 .

[237]  Ali Almansoori,et al.  Readily processed protonic ceramic fuel cells with high performance at low temperatures , 2015, Science.

[238]  Shaohua Zhang,et al.  Effect of Mg/Al ratio of NiMgAl mixed oxide catalyst derived from hydrotalcite for carbon dioxide reforming of methane , 2016 .

[239]  Yuan Liu,et al.  Co–Ni bimetal catalyst supported on perovskite-type oxide for steam reforming of ethanol to produce hydrogen , 2014 .

[240]  V. Choudhary,et al.  Oxidative conversion of methane to CO and H2 over Pt or Pd containing alkaline and rare earth oxide catalysts , 1998 .

[241]  Raymond J. Gorte,et al.  An Examination of Carbonaceous Deposits in Direct-Utilization SOFC Anodes , 2004 .

[242]  A. E. Aksoylu,et al.  CO2 reforming of methane over Pt–Ni/Al2O3 catalysts: Effects of catalyst composition, and water and oxygen addition to the feed , 2011 .

[243]  B. S. Çağlayan,et al.  A study on characterization and methane dry reforming performance of Co–Ce/ZrO2 catalyst , 2015 .

[244]  A novel LaGa0.65Mg0.15Ni0.20O3–δ perovskite catalyst with high performance for the partial oxidation of methane to syngas , 2016 .

[245]  Wei Sun,et al.  Partial oxidation of methane to syngas over Ni/SiC catalysts , 2005 .

[246]  K. Sotowa,et al.  Methane steam reforming over Ce–ZrO2-supported noble metal catalysts at low temperature , 2004 .

[247]  M. Laborde,et al.  Production of hydrogen by catalytic steam reforming of oxygenated model compounds on Ni-modified supported catalysts. Simulation and experimental study , 2015 .

[248]  P. Roy,et al.  Metal foam-supported Pd–Rh catalyst for steam methane reforming and its application to SOFC fuel processing , 2014 .

[249]  Kangnian Fan,et al.  Waste-free Soft Reactive Grinding Synthesis of High-Surface-Area Copper–Manganese Spinel Oxide Catalysts Highly Effective for Methanol Steam Reforming , 2008 .

[250]  F. Mondragón,et al.  Dry reforming of methane over LaNi1-yByO3±δ (B = Mg, Co) perovskites used as catalyst precursor , 2008 .

[251]  Y. Schuurman,et al.  Hydrogen production from ethanol steam reforming over Ir/CeO2 catalysts: Enhanced stability by PrOx promotion , 2011 .

[252]  Y. Qu,et al.  Nano bimetallic alloy of Ni–Co obtained from LaCoxNi1−xO3 and its catalytic performance for steam reforming of ethanol , 2015 .

[253]  Yongfa Zhang,et al.  CO2 reforming of CH4 over efficient bimetallic Co–Zr/AC catalyst for H2 production , 2015 .

[254]  K. Pant,et al.  Activity and stability enhancement of copper–alumina catalysts using cerium and zinc promoters for the selective production of hydrogen via steam reforming of methanol , 2006 .

[255]  Shenghu Zhou,et al.  Sol–gel auto-combustion synthesis of Ni–CexZr1−xO2 catalysts for carbon dioxide reforming of methane , 2013 .

[256]  Yixiang Shi,et al.  Fundamentals of electro- and thermochemistry in the anode of solid-oxide fuel cells with hydrocarbon and syngas fuels , 2014 .

[257]  E. Luna,et al.  Methane steam reforming over rhodium promoted Ni/Al2O3 catalysts , 1999 .

[258]  Haekyoung Kim,et al.  Dual layered anode support for the internal reforming of methane for solid oxide fuel cells , 2014 .

[259]  Robert J. Kee,et al.  Solid Oxide Fuel Cells: Operating Principles, Current Challenges, and the Role of Syngas , 2008 .

[260]  L. Guczi,et al.  Methane dry reforming with CO2 on CeZr-oxide supported Ni, NiRh and NiCo catalysts prepared by sol–gel technique: Relationship between activity and coke formation , 2011 .

[261]  Raymond J. Gorte,et al.  Direct oxidation of hydrocarbons in a solid-oxide fuel cell , 2000, Nature.

[262]  John T. S. Irvine,et al.  Methane Oxidation at Redox Stable Fuel Cell Electrode La0.75Sr0.25Cr0.5Mn0.5O3-δ , 2006 .

[263]  J. Park,et al.  High coke-resistance MgAl2O4 islands decorated catalyst with minimizing sintering in carbon dioxide reforming of methane , 2016 .

[264]  F. Tao,et al.  In Situ Surface Chemistries and Catalytic Performances of Ceria Doped with Palladium, Platinum, and Rhodium in Methane Partial Oxidation for the Production of Syngas , 2013 .

[265]  T. Yashima,et al.  Small Amounts of Rh-Promoted Ni Catalysts for Methane Reforming with CO2 , 2003 .

[266]  K. Tan,et al.  Partial oxidation of methane to synthesis gas over α-Al2O3-supported bimetallic Pt–Co catalysts , 1999 .

[267]  Li Cui,et al.  Hydrogen production from ethanol over Ir/CeO2 catalyst: Effect of the calcination temperature , 2015 .

[268]  Y. Bultel,et al.  Direct methane solid oxide fuel cell working by gradual internal steam reforming: Analysis of operation , 2009 .

[269]  Aldo Steinfeld,et al.  High-temperature solar thermochemistry: Production of iron and synthesis gas by Fe3O4-reduction with methane , 1993 .

[270]  A. Tsutsumi,et al.  Catalytic Activity and Stability of Nickel-Modified Molybdenum Carbide Catalysts for Steam Reforming of Methanol , 2014 .