A process for the synthesis of formic acid by CO2 hydrogenation: thermodynamic aspects and the role of CO.

[1]  Hiroyuki Yasuda,et al.  Transformation of carbon dioxide. , 2007, Chemical reviews.

[2]  W. Leitner.  Kohlendioxid als Rohstoff am Beispiel der Synthese von Ameisensäure und ihren Derivaten , 1995 .

[3]  P. Jessop,et al.  Hydrogenation of carbon dioxide catalyzed by ruthenium trimethylphosphine complexes: the accelerating effect of certain alcohols and amines. , 2002, Journal of the American Chemical Society.

[4]  Walter Leitner,et al.  Carbon Dioxide as a Raw Material: The Synthesis of Formic Acid and Its Derivatives from CO2 , 1995 .

[5]  P. Jessop,et al.  In situ formation of ruthenium catalysts for the homogeneous hydrogenation of carbon dioxide. , 2002, Inorganic chemistry.

[6]  M. Beller,et al.  Moderne Katalysatoren zur Hydrierung von Kohlendioxid , 2010 .

[7]  Atsushi Urakawa,et al.  Carbon dioxide hydrogenation catalyzed by a ruthenium dihydride: a DFT and high-pressure spectroscopic investigation. , 2007, Chemistry.

[8]  P. Jessop,et al.  Hydrogenation of carbon dioxide catalyzed by ruthenium trimethylphosphine complexes — Effect of gas pressure and additives on rate in the liquid phase , 2001 .

[9]  A. Urakawa,et al.  Towards a rational design of ruthenium CO2 hydrogenation catalysts by Ab initio metadynamics. , 2007, Chemistry.

[10]  P. Jessop,et al.  Homogeneous catalytic hydrogenation of supercritical carbon dioxide , 1994, Nature.

[11]  B. Han,et al.  Hydrogenation of CO2 to formic acid promoted by a diamine-functionalized ionic liquid. , 2009, ChemSusChem.

[12]  Ryoji Noyori,et al.  Homogeneous Hydrogenation of Carbon Dioxide , 1995 .

[13]  P. Jessop,et al.  HOMOGENEOUS CATALYSIS IN SUPERCRITICAL FLUIDS : HYDROGENATION OF SUPERCRITICAL CARBON DIOXIDE TO FORMIC ACID, ALKYL FORMATES, AND FORMAMIDES , 1996 .

[14]  A. Bazzanella,et al.  CO2 – und was nun? Technische Optionen für den Umgang mit CO2 , 2009 .

[15]  R. Grubbs,et al.  Convenient synthesis of ruthenium(II) dihydride phosphine complexes Ru(H)2(PP)2 and Ru(H)2(PR3)x (x = 3 and 4) , 1997 .

[16]  Steve Ritter.  HYDROGEN STORAGE GETS A BOOST , 2007 .

[17]  K. Nicholas,et al.  Rhodium-catalyzed hydrogenation of carbon dioxide to formic acid , 1992 .

[18]  Xiaoming Zheng,et al.  Silica immobilized ruthenium catalyst used for carbon dioxide hydrogenation to formic acid (I): the effect of functionalizing group and additive on the catalyst performance , 2004 .

[19]  Z. Yiping,et al.  Silica Immobilized Ruthenium Catalyst for Formic Acid Synthesis from Supercritical Carbon Dioxide Hydrogenation II: Effect of Reaction Conditions on the Catalyst Performance , 2005 .

[20]  M. Beller,et al.  Ruthenium-catalyzed hydrogenation of bicarbonate in water. , 2010, ChemSusChem.

[21]  P. Jessop,et al.  Hydrogenation of Carbon Dioxide Catalyzed by Ruthenium Trimethylphosphine Complexes: A Mechanistic Investigation Using High-Pressure NMR Spectroscopy , 2009 .

[22]  S. Sakaki,et al.  Ruthenium(II)-Catalyzed Hydrogenation of Carbon Dioxide to Formic Acid. Theoretical Study of Significant Acceleration by Water Molecules , 2006 .

[23]  S. Sakaki,et al.  Ruthenium(II)-catalyzed hydrogenation of carbon dioxide to formic acid. Theoretical study of real catalyst, ligand effects, and solvation effects. , 2005, Journal of the American Chemical Society.

[24]  Jun Zhang,et al.  Homogeneous catalytic synthesis of formic acid (salts) by hydrogenation of CO2 with H2 in the presence of ruthenium species , 1996 .

[25]  Y. Inoue,et al.  CATALYTIC FIXATION OF CARBON DIOXIDE TO FORMIC ACID BY TRANSITION-METAL COMPLEXES UNDER MILD CONDITIONS , 1976 .

[26]  Philip G. Jessop,et al.  Recent advances in the homogeneous hydrogenation of carbon dioxide , 2004 .