Use of lower grade coals in IGCC plants with carbon capture for the co-production of hydrogen and electricity

Abstract This paper investigates the potential use of lower grade coals in an IGCC-CCS plant that generates electricity and produces hydrogen simultaneously with carbon dioxide capture and storage. The paper underlines one of the main advantages of gasification technology, namely the possibility to process lower grade coals, which are more widely available than the high-grade coals normally used in European power plants. Based on a proposed plant concept that generates about 400 MW net electricity with a flexible output of 0–50 MWth hydrogen and a carbon capture rate of at least 90%, the paper develops fuel selection criteria for coal fluxing and blending of various types of coal for optimizing plant performance e.g. oxygen consumption, hydrogen production potential, specific syngas energy production per tonne of oxygen consumed, etc. These performance indicators were calculated for a number of case studies through process flow simulations. The main conclusion is that blending of coal types of higher and lower grade is more beneficial in terms of operation and cost performance than fluxing high-grade coals.

[1]  A. Perna Combined power and hydrogen production from coal. Part A—Analysis of IGHP plants , 2008 .

[2]  Anne-Gaëlle Collot,et al.  Matching gasification technologies to coal properties , 2006 .

[3]  Aliki Georgakaki,et al.  Enhanced Oil Recovery Using Carbon Dioxide in the European Energy System , 2005 .

[4]  Fred Starr,et al.  The design of carbon capture IGCC-based plants with hydrogen co-production , 2009 .

[5]  F. Mueller-Langer,et al.  Techno-economic assessment of hydrogen production processes for the hydrogen economy for the short and medium term , 2007 .

[6]  E. Tzimas,et al.  Critical factors in the design, operation and economics of coal gasification plants : The case of the flexible co-production of hydrogen and electricity , 2007 .

[7]  C. Cormos,et al.  Innovative Concepts for Hydrogen Production Processes Based on Coal Gasification with CO2 Capture , 2008 .

[8]  Kenneth C. Mills,et al.  The measurement and estimation of the physical properties of slags formed during coal gasification: 1. Properties relevant to fluid flow , 1989 .

[9]  Maarten van der Burgt,et al.  Gasification. 2nd. ed. , 2008 .

[10]  C. Cormos Assessment of hydrogen and electricity co-production schemes based on gasification process with carbon capture and storage , 2009 .

[11]  Giovanni Lozza,et al.  Using Hydrogen as Gas Turbine Fuel , 2003 .

[12]  T. Wall,et al.  An Empirical Method for the Prediction of Coal Ash Slag Viscosity , 2003 .

[13]  T. Nejat Veziroglu,et al.  “Green” path from fossil-based to hydrogen economy: An overview of carbon-neutral technologies , 2008 .

[14]  H. J. Hurst,et al.  Ash and slag qualities of Australian bituminous coals for use in slagging gasifiers , 2000 .

[15]  Georges Urbain,et al.  Viscosity estimation of slags , 1987 .

[16]  Tzimas Evangelos,et al.  Advanced IGCC-Hypogen Concepts for a Developing Hydrogen Market , 2007 .

[17]  Tzimas Evangelos,et al.  IGCC: Coal-Based Processing Technology for the Future , 2007 .

[18]  Evgueni Jak,et al.  Predicting coal ash slag flow characteristics (viscosity model for the Al2O3-CaO-'FeO'-SiO2 system) , 2001 .

[19]  N. Nugent,et al.  European Commission , 1993, European Energy and Environmental Law Review.

[20]  Robert H. Williams,et al.  Co-production of hydrogen, electricity and CO2 from coal with commercially ready technology. Part A: Performance and emissions , 2005 .

[21]  Tzimas Evangelos,et al.  A Large Scale Test Facility for the Production of Hydrogen and Electricity - The Hypogen Project: a JRC-Setris Perspective , 2005 .

[22]  Marc A. Rosen,et al.  Hydrogen production from coal gasification for effective downstream CO2 capture , 2010 .

[23]  Tzimas Evangelos,et al.  Gasifier Concepts for Hydrogen and Electricity Co-production with CO2 Capture , 2007 .

[24]  Judith Gurney BP Statistical Review of World Energy , 1985 .

[25]  G. H. Babcock,et al.  Steam / its generation and use , 1972 .

[26]  M. Seggiani Empirical correlations of the ash fusion temperatures and temperature of critical viscosity for coal and biomass ashes , 1999 .