NHC-Pd(II)-azole complexes catalyzed Suzuki–Miyaura cross-coupling of sterically hindered aryl chlorides with arylboronic acids

[1]  Yongfei Zeng,et al.  A Highly Active Catalyst System for Suzuki–Miyaura Coupling of Aryl Chlorides , 2019, Organometallics.

[2]  S. Konishi,et al.  Synthesis, Properties, and Catalytic Application of a Triptycene-Type Borate-Phosphine Ligand , 2018, Organometallics.

[3]  C. Chen,et al.  Highly active NHC–Pd(II) complexes for cross coupling of aryl chlorides and arylboronic acids: an investigation of the effect of remote bulky groups , 2018 .

[4]  A. Biffis,et al.  Pd Metal Catalysts for Cross-Couplings and Related Reactions in the 21st Century: A Critical Review. , 2018, Chemical reviews.

[5]  Fei Huang,et al.  The Highly Efficient Suzuki–Miyaura Cross‐Coupling of (Hetero)aryl Chlorides and (Hetero)arylboronic Acids Catalyzed by “Bulky‐yet‐Flexible” Palladium–PEPPSI Complexes in Air , 2018 .

[6]  Ming‐Tsz Chen,et al.  Effect on orthometallation of NHC palladium complexes toward the catalytic activity studies in Suzuki coupling reaction. , 2017, Dalton transactions.

[7]  Feng-Shou Liu,et al.  Bulky Yet Flexible Pd-PEPPSI-IPentAn for the Synthesis of Sterically Hindered Biaryls in Air. , 2017, The Journal of organic chemistry.

[8]  F. Jordan,et al.  Recent Developments in Ruthenium-Catalyzed C–H Arylation: Array of Mechanistic Manifolds , 2017 .

[9]  N. Hazari,et al.  Well-defined nickel and palladium precatalysts for cross-coupling. , 2017, Nature reviews. Chemistry.

[10]  Jianhui Wang,et al.  Highly active palladium catalysts containing a 1,10-phenanthroline analogue N-heterocyclic carbene for room temperature Suzuki-Miyaura coupling reactions of aryl chlorides with arylboronic acids in aqueous media , 2017 .

[11]  Beibei Ma,et al.  Pd-PEPPSI Complexes Bearing Bulky [(1,2-Di-(tert-butyl)acenaphthyl] (DtBu-An) on N-Heterocarbene Backbones: Highly Efficient for Suzuki–Miyaura Cross-Coupling under Aerobic Conditions , 2016 .

[12]  Guiyan Liu,et al.  A Highly Active Pd(II) Complex with 1‐Tritylimidazole Ligand for Suzuki‐Miyaura and Heck Coupling Reactions , 2016 .

[13]  Jianhui Wang,et al.  A highly active and recyclable homogeneous NHC–palladium catalyst with pH- and light-sensitive tags for the Suzuki–Miyaura coupling reactions of aryl halides with arylboronic acids , 2016 .

[14]  F. Colobert,et al.  Recent advances and new concepts for the synthesis of axially stereoenriched biaryls. , 2015, Chemical Society reviews.

[15]  Mickaël Henrion,et al.  Nickel N-Heterocyclic Carbene-Catalyzed C–C Bond Formation: Reactions and Mechanistic Aspects , 2015 .

[16]  T. Singh,et al.  Synthesis of Biaryls through Aromatic CH Bond Activation: A Review of Recent Developments , 2014 .

[17]  W. Thiel,et al.  An Efficient Palladium N‐Heterocyclic Carbene Catalyst Allowing the Suzuki–Miyaura Cross‐Coupling of Aryl Chlorides and Arylboronic Acids at Room Temperature in Aqueous Solution , 2014 .

[18]  Jennifer L. Farmer,et al.  Room-temperature amination of deactivated aniline and aryl halide partners with carbonate base using a Pd-PEPPSI-IPentCl-o-picoline catalyst. , 2014, Angewandte Chemie.

[19]  C. Besnard,et al.  Chiral PEPPSI Complexes: Synthesis, Characterization, and Application in Asymmetric Suzuki–Miyaura Coupling Reactions , 2014 .

[20]  Yunfei Zhou,et al.  Robust acenaphthoimidazolylidene palladium complexes: highly efficient catalysts for Suzuki-Miyaura couplings with sterically hindered substrates. , 2012, Organic letters.

[21]  A. Slawin,et al.  [Pd(IPr*)(cinnamyl)Cl]: an efficient pre-catalyst for the preparation of tetra-ortho-substituted biaryls by Suzuki-Miyaura cross-coupling. , 2012, Chemistry.

[22]  Ka Hou Hoi,et al.  The development of bulky palladium NHC complexes for the most-challenging cross-coupling reactions. , 2012, Angewandte Chemie.

[23]  M. Turner,et al.  Inhibited Catalyst Activation in (N-Heterocyclic carbene)PdCl2(diethylamine) Complexes by Intramolecular Hydrogen Bonding , 2011 .

[24]  A. Maguire,et al.  A Practical Synthesis of Biaryls via a Thermal Decarboxylative Pd-Catalyzed Cross-Coupling Reaction Operating at Moderate Temperature , 2011 .

[25]  A. Suzuki Cross-coupling reactions of organoboranes: an easy way to construct C-C bonds (Nobel Lecture). , 2011, Angewandte Chemie.

[26]  G. Bringmann,et al.  Atroposelective total synthesis of axially chiral biaryl natural products. , 2011, Chemical reviews.

[27]  A. Lough,et al.  Structure-activity relationship analysis of Pd-PEPPSI complexes in cross-couplings: a close inspection of the catalytic cycle and the precatalyst activation model. , 2010, Chemistry.

[28]  S. Buchwald,et al.  A new palladium precatalyst allows for the fast Suzuki-Miyaura coupling reactions of unstable polyfluorophenyl and 2-heteroaryl boronic acids. , 2010, Journal of the American Chemical Society.

[29]  M. Organ,et al.  Pd-PEPPSI-IPent: low-temperature negishi cross-coupling for the preparation of highly functionalized, tetra-ortho-substituted biaryls. , 2010, Angewandte Chemie.

[30]  Ka Hou Hoi,et al.  Pd-PEPPSI-IPent: an active, sterically demanding cross-coupling catalyst and its application in the synthesis of tetra-ortho-substituted biaryls. , 2009, Angewandte Chemie.

[31]  S. Buchwald,et al.  Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands. , 2008, Accounts of chemical research.

[32]  F. Glorius,et al.  Surveying sterically demanding N-heterocyclic carbene ligands with restricted flexibility for palladium-catalyzed cross-coupling reactions. , 2008, Accounts of chemical research.

[33]  M. Organ,et al.  Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions--a synthetic chemist's perspective. , 2007, Angewandte Chemie.

[34]  Lunxiang Yin,et al.  Carbon-carbon coupling reactions catalyzed by heterogeneous palladium catalysts. , 2007, Chemical reviews.

[35]  A. Lough,et al.  Easily prepared air- and moisture-stable Pd-NHC (NHC=N-heterocyclic carbene) complexes: a reliable, user-friendly, highly active palladium precatalyst for the Suzuki-Miyaura reaction. , 2006, Chemistry.

[36]  Jianguo Mei,et al.  Modified (NHC)Pd(allyl)Cl (NHC = N-heterocyclic carbene) complexes for room-temperature Suzuki-Miyaura and Buchwald-Hartwig reactions. , 2006, Journal of the American Chemical Society.

[37]  M. Organ,et al.  Electronic nature of N-heterocyclic carbene ligands: effect on the Suzuki reaction. , 2005, Organic letters.

[38]  S. Buchwald,et al.  A rationally designed universal catalyst for Suzuki-Miyaura coupling processes. , 2004, Angewandte Chemie.

[39]  S. Nolan,et al.  A general method for the Suzuki-Miyaura cross-coupling of sterically hindered aryl chlorides: synthesis of di- and tri-ortho-substituted biaryls in 2-propanol at room temperature. , 2003, Journal of the American Chemical Society.

[40]  A. Yudin,et al.  Modified BINOL ligands in asymmetric catalysis. , 2003, Chemical reviews.

[41]  S. Vyskocil,et al.  Non-symmetrically substituted 1,1'-binaphthyls in enantioselective catalysis. , 2003, Chemical reviews.

[42]  E. Daugs,et al.  The Synthesis of OSU 6162: Efficient, Large-Scale Implementation of a Suzuki Coupling , 2003 .

[43]  C. Frost Palladium‐Catalyzed Coupling Reactions. , 2003 .

[44]  G. C. Fu,et al.  Palladium-catalyzed coupling reactions of aryl chlorides. , 2002, Angewandte Chemie.

[45]  W. Herrmann N-heterocyclic carbenes: a new concept in organometallic catalysis. , 2002, Angewandte Chemie.

[46]  M. Lemaire,et al.  Aryl-aryl bond formation one century after the discovery of the Ullmann reaction. , 2002, Chemical reviews.

[47]  E. Giralt,et al.  Atropisomerism, biphenyls and the Suzuki coupling: peptide antibiotics , 2001 .

[48]  G. Bringmann,et al.  Stereoselective total synthesis of axially chiral natural products via biaryl lactones. , 2001, Accounts of chemical research.

[49]  Tamio Hayashi,et al.  Chiral monodentate phosphine ligand MOP for transition-metal-catalyzed asymmetric reactions. , 2000, Accounts of chemical research.

[50]  G. C. Fu,et al.  A Convenient and General Method for Pd-Catalyzed Suzuki Cross-Couplings of Aryl Chlorides and Arylboronic Acids. , 1998, Angewandte Chemie.

[51]  Lin Pu,et al.  1,1'-Binaphthyl Dimers, Oligomers, and Polymers: Molecular Recognition, Asymmetric Catalysis, and New Materials. , 1998, Chemical reviews.

[52]  John P. Wolfe,et al.  A Highly Active Catalyst for Palladium-Catalyzed Cross-Coupling Reactions: Room-Temperature Suzuki Couplings and Amination of Unactivated Aryl Chlorides , 1998 .

[53]  Norio Miyaura,et al.  Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds , 1995 .

[54]  I. Moritani,et al.  The reaction of σ-vinylpalladium complexes with alkyllithiums. Stereospecific syntheses of olefins from vinyl halides and alkyllithiums , 1975 .

[55]  P. H. Gore The Friedel-Crafts Acylation Reaction and its Application to Polycyclic Aromatic Hydrocarbons , 1955 .