Mask fabrication towards sub-10 nm imprint lithography

We report for the first time the use of orientation dependent etching (ODE) of (110) c-Si in sidewall thin film technology for imprint mask fabrication with low line edge roughness (LER) over a large area. Oxidation is used for sidewall thin film formation with a good critical dimension control. 2-dimensional oxidation effects are discussed. Features down to 12 nm have been fabricated successfully. Simulation shows that the fabricated oxide line is strong enough to imprint both thermoplastic and photo-curable imprint resists.

[1]  C. Willson,et al.  Step and flash imprint lithography: Template surface treatment and defect analysis , 2000 .

[2]  C.H. Diaz,et al.  An experimentally validated analytical model for gate line-edge roughness (LER) effects on technology scaling , 2001, IEEE Electron Device Letters.

[3]  S. Turner,et al.  Zero-Mode Waveguides for Single-Molecule Analysis at High Concentrations , 2003, Science.

[4]  K. Yamabe,et al.  Nonplanar oxidation and reduction of oxide leakage currents at silicon corners by rounding-off oxidation , 1987, IEEE Transactions on Electron Devices.

[5]  B. Bhushan,et al.  Mechanical property measurements of nanoscale structures using an atomic force microscope. , 2002, Ultramicroscopy.

[6]  Martin Fuchs,et al.  DNA mapping using microfluidic stretching and single-molecule detection of fluorescent site-specific tags. , 2004, Genome research.

[7]  E. Irene The Effects of Trace Amounts of Water on the Thermal Oxidation of Silicon in Oxygen , 1974 .

[8]  J.C.S. Woo,et al.  TCAD-based statistical analysis and modeling of gate line-edge roughness effect on nanoscale MOS transistor performance and scaling , 2004, IEEE Transactions on Semiconductor Manufacturing.

[9]  Zhaoning Yu,et al.  Fabrication of large area 100 nm pitch grating by spatial frequency doubling and nanoimprint lithography for subwavelength optical applications , 2001 .

[10]  Stephen Y. Chou,et al.  Imprint lithography with sub-10 nm feature size and high throughput , 1997 .

[11]  Masaru Sasago,et al.  Study of the resist deformation in nanoimprint lithography , 2001 .

[12]  H. Kurz,et al.  Fabrication of nanostructures using a UV-based imprint technique , 2000 .

[13]  S. Chou,et al.  Ultrafast and direct imprint of nanostructures in silicon , 2002, Nature.

[14]  Mi-Chang Chang,et al.  Process and circuit design interlock for application-dependent scaling tradeoffs and optimization in the SoC era , 2003 .

[15]  Stephen Y. Chou,et al.  Imprint of sub-25 nm vias and trenches in polymers , 1995 .

[16]  Pascal Silberzan,et al.  From the Cover: The dynamics of genomic-length DNA molecules in 100-nm channels. , 2004, Proceedings of the National Academy of Sciences of the United States of America.

[17]  P. Veltink,et al.  The mechanical properties of the rubber elastic polymer polydimethylsiloxane for sensor applications , 1997 .

[18]  Wei Wu,et al.  Fabrication of 5 nm linewidth and 14 nm pitch features by nanoimprint lithography , 2004 .

[19]  Robert H. Austin,et al.  Fabrication of 10 nm enclosed nanofluidic channels , 2002 .

[20]  K. Bean,et al.  Anisotropic etching of silicon , 1978, IEEE Transactions on Electron Devices.

[21]  D. L. Kendall On etching very narrow grooves in silicon , 1975 .

[22]  Hiroshi Hiroshima,et al.  Evaluation of Line Edge Roughness in Nanoimprint Lithography Using Photocurable Polymer , 2003 .

[23]  Chia-Fu Chou,et al.  Electrodeless dielectrophoresis of single- and double-stranded DNA. , 2002, Biophysical journal.

[24]  Influence of roughness and interdiffusion in zone plate structures on the diffraction efficiency described by coupled wave theory , 1998 .