High electron mobility in bathophenanthroline

We have measured electron mobility in vacuum-deposited films of 4,7-diphenyl-1,10phenanthroline (bathophenanthroline, or BPhen) using a time-of-flight technique. Electron transport was highly dispersive for BPhen with a dispersion parameter of a value 0.30. The electron mobility in excess of 10−4 cm2/V s has been observed at electric fields of the order of 105 V/cm with weakly dependent on the electric field. The characteristic energy of the distribution is obtained a value 0.09 eV. It is directly confirmed that the BPhen has superior electron-transport capability.

[1]  H. Tokuhisa,et al.  Electron drift mobility of oxadiazole derivatives doped in polycarbonate , 1995 .

[2]  W. Brütting,et al.  Electron transport in a starburst oxadiazole , 1997 .

[3]  E. Montroll,et al.  Anomalous transit-time dispersion in amorphous solids , 1975 .

[4]  S. Jenekhe,et al.  High electron mobility in bipolar composites of organic molecules , 1996 .

[5]  Toshio Matsumoto,et al.  Bright organic electroluminescent devices having a metal-doped electron-injecting layer , 1998 .

[6]  Stephen R. Forrest,et al.  Improved energy transfer in electrophosphorescent devices , 1999 .

[7]  Electron transport in starburst phenylquinoxalines , 1999 .

[8]  Katsutoshi Nagai,et al.  White-Light-Emitting Organic Electroluminescent Device Using Lanthanide Complexes , 1996 .

[9]  C. Tang,et al.  Organic Electroluminescent Diodes , 1987 .

[10]  Damodar M. Pai,et al.  Hole transport in solid solutions of a diamine in polycarbonate , 1984 .

[11]  V. Arkhipov,et al.  An Analysis of the Dispersive Charge Transport in Vitreous 0.55 As2S3: 0.45 Sb2S3 , 1979 .

[12]  Tetsuo Tsutsui,et al.  Charge carrier mobilities in molecular materials for electroluminescent diodes , 1998, Photonics West.

[13]  Katsutoshi Nagai,et al.  Bright red light‐emitting organic electroluminescent devices having a europium complex as an emitter , 1994 .

[14]  Hiroshi Tokailin,et al.  Transient behavior of organic thin film electroluminescence , 1992 .

[15]  G. Pfister,et al.  Electronic properties of polymers , 1982 .

[16]  W. D. Gill Drift mobilities in amorphous charge‐transfer complexes of trinitrofluorenone and poly‐n‐vinylcarbazole , 1972 .

[17]  M. Sinclair,et al.  Electron and hole mobility in tris(8‐hydroxyquinolinolato‐N1,O8) aluminum , 1995 .

[18]  Tetsuo Tsutsui,et al.  Sharply directed emission in organic electroluminescent diodes with an optical-microcavity structure , 1994 .

[19]  H. Antoniadis,et al.  Carrier deep-trapping mobility-lifetime products in poly(p-phenylene vinylene) , 1994 .