Polyphenylene sulfide (PPS) composites reinforced with recycled carbon fiber

Recycled carbon fibers were reclaimed by commercial scale pyrolysis from carbon fiber reinforced thermoset composite waste generated by the aerospace industry. The mechanical and physical properties of the reclaimed carbon fibers were shown to be comparable to those of aerospace grade virgin carbon fibers. The recycled carbon fibers were integrated into a polyphenylene sulfide (PPS) thermoplastic resin by twin screw compounding followed by injection molding. Composites containing 20 wt.% and 40 wt.% recycled carbon fibers were produced. Overall, the fibers were found to be uniformly dispersed in the polymeric matrix. The tensile, flexural and impact properties of the composites were evaluated. The recycled carbon fiber reinforced PPS composites exhibited comparable mechanical properties to equivalent compounds produced using industrial grades of short virgin carbon fiber. In addition, thermogravimetric analysis showed that the introduction of recycled carbon fibers was not detrimental to the inherent thermal stability of PPS.

[1]  P. Cebe,et al.  Effects of thermal history on the rigid amorphous phase in poly(phenylene sulfide) , 1992 .

[2]  Brian Edward Allen Characterization of Reclaimed Carbon Fibers and their Integration into New Thermoset Polymer Matrices via Existing Composite Fabrication Techniques , 2008 .

[3]  Oana Ghita,et al.  Successful closed-loop recycling of thermoset composites , 2009 .

[4]  R. Allred,et al.  Tertiary Recycling of Automotive Plastics and Composites , 2000 .

[5]  Chris D. Rudd,et al.  A fluidised-bed process for the recovery of glass fibres from scrap thermoset composites , 2000 .

[6]  K. Ushikoshi,et al.  Recycling of CFRP by Pyrolysis Method , 1995 .

[7]  S. Tsai,et al.  Introduction to composite materials , 1980 .

[8]  Jan MichaelGosau Integrated Composite Recycling Process , 2006 .

[9]  Chris D. Rudd,et al.  The characterisation and reuse of glass fibres recycled from scrap composites by the action of a fluidised bed process , 1998 .

[10]  H. L. Cox The elasticity and strength of paper and other fibrous materials , 1952 .

[11]  Chuck Zhang,et al.  Recycling of woven carbon-fibre-reinforced polymer composites using supercritical water , 2012, Environmental technology.

[12]  M. Akonda,et al.  Recycled carbon fibre-reinforced polypropylene thermoplastic composites , 2012 .

[13]  T. McNally,et al.  Recycled carbon fiber filled polyethylene composites , 2008 .

[14]  Stephen Pickering,et al.  Recycling technologies for thermoset composite materials—current status , 2006 .

[15]  R. Brooks,et al.  Effect of coupling agents on reinforcing potential of recycled carbon fibre for polypropylene composite , 2012 .

[16]  Yongping Bai,et al.  Chemical recycling of carbon fibers reinforced epoxy resin composites in oxygen in supercritical water , 2010 .

[17]  Stephen Pickering,et al.  Chemical recycling of carbon fibre composites using alcohols under subcritical and supercritical conditions , 2008 .

[18]  Soraia Pimenta,et al.  Recycling carbon fibre reinforced polymers for structural applications: technology review and market outlook. , 2011, Waste management.

[19]  J. Varna,et al.  Mechanical Performance of a Recycled Carbon Fibre/PP Composite , 2011 .

[20]  Keiji Ogi,et al.  Mechanical properties of ABS resin reinforced with recycled CFRP , 2007 .