On the effect of resonant microwave fields on temperature distribution in time and space

Abstract Microwave assisted chemistry has become a popular research topic within the framework of process intensification. The physics of microwave heating are fundamentally different from those found in conventional processing systems. Heating occurs fast, but non-uniformly in hard-to-predict patterns. In this study it is shown that these complexities are caused by the resonant nature of the microwave fields present in heating devices. This is demonstrated by means of experiments and modeling concerning heating of water-filled vials in single mode resonant microwave equipment. The results evince highly non-uniform, transient and irregularly behaving heating processes.

[1]  A. Stankiewicz,et al.  Influence of microwave irradiation on a polyesterification reaction , 2009 .

[2]  Tine Koloini,et al.  Hydrolysis of sucrose by conventional and microwave heating in stirred tank reactor , 1995 .

[3]  A. Loupy,et al.  A tentative rationalization of microwave effects in organic synthesis according to the reaction medium, and mechanistic considerations , 2001 .

[4]  Nicholas E. Leadbeater,et al.  Batch and Continuous-Flow Preparation of Biodiesel Derived from Butanol and Facilitated by Microwave Heating , 2008 .

[5]  Roger Meredith,et al.  Engineers' Handbook of Industrial Microwave Heating , 1998 .

[6]  Howard C. Reader,et al.  Understanding Microwave Heating Cavities , 2000 .

[7]  Nicholas E. Leadbeater,et al.  Microwave-promoted Suzuki coupling reactions with organotrifluoroborates in water using ultra-low catalyst loadings , 2006 .

[8]  Tom Van Gerven,et al.  On the accuracy and reproducibility of fiber optic (FO) and infrared (IR) temperature measurements of solid materials in microwave applications , 2010 .

[9]  K. P. Sandeep,et al.  Mathematical modeling of continuous flow microwave heating of liquids (effects of dielectric properties and design parameters) , 2007 .

[10]  Angel Díaz-Ortiz,et al.  Microwaves in organic synthesis. Thermal and non-thermal microwave effects. , 2005, Chemical Society reviews.

[11]  Tom Van Gerven,et al.  Microwave-activated methanol steam reforming for hydrogen production , 2011 .

[12]  Dariusz Bogdal,et al.  Microwave-assisted Organic Synthesis - One Hundred Reaction Procedures , 2006 .

[13]  Jelle E. Stumpel,et al.  The mechanism of the oxidation of benzyl alcohol by iron(III)nitrate: conventional versus microwave heating , 2009 .

[14]  P. Licence,et al.  Understanding microwave heating effects in single mode type cavities-theory and experiment. , 2010, Physical chemistry chemical physics : PCCP.

[15]  C. Oliver Kappe,et al.  Controlled microwave heating in modern organic synthesis: highlights from the 2004–2008 literature , 2009, Molecular Diversity.

[16]  D. Pozar Microwave Engineering , 1990 .

[17]  M. Herrero,et al.  Nonthermal microwave effects revisited: on the importance of internal temperature monitoring and agitation in microwave chemistry. , 2008, The Journal of organic chemistry.