Flexible and fluorophore-doped luminescent solar concentrators based on polydimethylsiloxane.

We demonstrate a simple and inexpensive method to fabricate flexible and fluorophore-doped luminescent solar concentrators (LSCs). Polydimethylsiloxane (PDMS) serves as a host material which additionally offers the potential to cast LSCs in arbitrary shapes. The laser dye Pyrromethene 567 is used as a prototype fluorophore, and it is shown that it has a high quantum yield of 93% over the concentration range investigated. The optical efficiency and loss channels of the flexible LSCs are investigated; it is also demonstrated that the efficiency remains high while bending the LSC which is essential for flexible LSCs to make an impact on solar energy.

[1]  Hiroshi Sakai,et al.  Production technology for amorphous silicon-based flexible solar cells , 2001 .

[2]  Sandra F. H. Correia,et al.  High-efficiency luminescent solar concentrators for flexible waveguiding photovoltaics , 2015 .

[3]  Aram Amassian,et al.  Efficient Spray‐Coated Colloidal Quantum Dot Solar Cells , 2015, Advanced materials.

[4]  Paul P. C. Verbunt,et al.  Thirty Years of Luminescent Solar Concentrator Research: Solar Energy for the Built Environment , 2012 .

[5]  Chun-Hsien Chou,et al.  High-Performance Flexible Waveguiding Photovoltaics , 2013, Scientific Reports.

[6]  Timothy D Heidel,et al.  High-Efficiency Organic Solar Concentrators for Photovoltaics , 2008, Science.

[7]  E. Yablonovitch Statistical ray optics , 1982 .

[8]  I. Papakonstantinou,et al.  Losses in luminescent solar concentrators unveiled , 2016 .

[9]  M. Mizukami,et al.  Flexible AM OLED panel driven by bottom-contact OTFTs , 2006, IEEE Electron Device Letters.

[10]  I. Papakonstantinou,et al.  Homeotropic alignment and Förster resonance energy transfer: The way to a brighter luminescent solar concentrator , 2014 .

[11]  Hyewon Kang,et al.  An improved method of preparing composite poly(dimethylsiloxane) moulds , 2006 .

[12]  A. Mata,et al.  Characterization of Polydimethylsiloxane (PDMS) Properties for Biomedical Micro/Nanosystems , 2005, Biomedical microdevices.

[13]  Heinrich Kurz,et al.  Improved mold fabrication for the definition of high quality nanopatterns by Soft UV-Nanoimprint lithography using diluted PDMS material , 2007 .

[14]  Jao-Hwa Kuang,et al.  Plastic Optical Fiber Displacement Sensor Based on Dual Cycling Bending , 2010, Sensors.

[15]  Hidetoshi Miura,et al.  Application of highly ordered TiO2 nanotube arrays in flexible dye-sensitized solar cells. , 2008, ACS nano.

[16]  David C. Miller,et al.  Analysis of transmitted optical spectrum enabling accelerated testing of CPV designs , 2009, Optics + Photonics for Sustainable Energy.

[17]  Dan Wang,et al.  Fiber-shaped flexible solar cells , 2010 .

[18]  Jin-seong Park,et al.  Thin film encapsulation for flexible AM-OLED: a review , 2011 .

[19]  N. Voelcker,et al.  Recent developments in PDMS surface modification for microfluidic devices , 2010, Electrophoresis.

[20]  Ole Hagemann,et al.  A complete process for production of flexible large area polymer solar cells entirely using screen printing—First public demonstration , 2009 .

[21]  Ping Ning,et al.  Simultaneous adsorptive removal of methylene blue and copper ions from aqueous solution by ferrocene‐modified cation exchange resin , 2014 .

[22]  Mark S. Brown,et al.  Efficiency and loss mechanisms of plasmonic Luminescent Solar Concentrators. , 2013, Optics express.

[23]  J. Rogers,et al.  Flexible concentrator photovoltaics based on microscale silicon solar cells embedded in luminescent waveguides. , 2011, Nature communications.

[24]  Jürgen H. Werner,et al.  Flexible solar cells for clothing , 2006 .

[25]  Richard H. Friend,et al.  An improved experimental determination of external photoluminescence quantum efficiency , 1997 .

[26]  G. Whitesides,et al.  Soft Actuators and Robots that Are Resistant to Mechanical Damage , 2014 .

[27]  F. Krebs,et al.  A roll-to-roll process to flexible polymer solar cells: model studies, manufacture and operational stability studies , 2009 .

[28]  Sergio Brovelli,et al.  Large-area luminescent solar concentrators based on ‘Stokes-shift-engineered’ nanocrystals in a mass-polymerized PMMA matrix , 2014, Nature Photonics.

[29]  A. Sugimoto,et al.  Flexible OLED displays using plastic substrates , 2004, IEEE Journal of Selected Topics in Quantum Electronics.

[30]  Thomas N. Jackson,et al.  All-organic active matrix flexible display , 2006 .

[31]  W. Huck,et al.  A self-assembly approach to chemical micropatterning of poly(dimethylsiloxane). , 2007, Angewandte Chemie.

[32]  Mohini Sain,et al.  Development of transparent bacterial cellulose nanocomposite film as substrate for flexible organic light emitting diode (OLED) display , 2012 .

[33]  F. Kessler,et al.  Technological aspects of flexible CIGS solar cells and modules , 2004 .