Activation and Dehydrogenative Silylation of the C-H Bonds of Phosphine-coordinated Ruthenium in Lu/Ru Heteromultimetallic Hydride Complexes

The reaction of half-sandwich lutetium dialkyl complex Cp∗Lu(CH2SiMe3)2(THF) (Cp∗= C5Me5) with ruthenium–trihydrido–phosphine complexes Cp∗Ru(PR3)H3 (R3 = Ph3, Ph2Me, PhMe2, and Me3) at 50 °C affor...

[1]  T. Shima,et al.  Synthesis and Reactions of Polynuclear Polyhydrido Rare Earth Metal Complexes Containing “(C5Me4SiMe3)LnH2” Units: A New Frontier in Rare Earth Metal Hydride Chemistry , 2007 .

[2]  Z. Hou,et al.  Cationic rare-earth polyhydrido complexes: synthesis, structure, and catalytic activity for the cis-1,4-selective polymerization of 1,3-cyclohexadiene. , 2006, Angewandte Chemie.

[3]  T. Shima,et al.  Hydrogenation of carbon monoxide by tetranuclear rare earth metal polyhydrido complexes. Selective formation of ethylene and isolation of well-defined polyoxo rare earth metal clusters. , 2006, Journal of the American Chemical Society.

[4]  Z. Hou,et al.  Alternating Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by Organo Rare Earth Metal Complexes , 2005 .

[5]  Z. Hou,et al.  Alternating ethylene-norbornene copolymerization catalyzed by cationic half-sandwich scandium complexes. , 2005, Angewandte Chemie.

[6]  A. Sadow,et al.  Synthesis and characterization of scandium silyl complexes of the type Cp*2ScSiHRR'. sigma-Bond metathesis reactions and catalytic dehydrogenative silation of hydrocarbons. , 2005, Journal of the American Chemical Society.

[7]  Z. Hou,et al.  Scandium half-metallocene-catalyzed syndiospecific styrene polymerization and styrene-ethylene copolymerization: unprecedented incorporation of syndiotactic styrene-styrene sequences in styrene-ethylene copolymers. , 2004, Journal of the American Chemical Society.

[8]  N. Chatani,et al.  Ru3(CO)12-catalyzed silylation of benzylic C-H bonds in arylpyridines and arylpyrazoles with hydrosilanes via C-H bond cleavage. , 2004, Journal of the American Chemical Society.

[9]  D. Hashizume,et al.  Hydrogenation of carbon dioxide and aryl isocyanates by a tetranuclear tetrahydrido yttrium complex. Isolation, structures, and CO2 insertion reactions of methylene diolate and mu3-oxo yttrium complexes. , 2004, Journal of the American Chemical Society.

[10]  B. Scott,et al.  Synthesis and Characterization of (Mono)-pentamethylcyclopentadienyl Lutetium Complexes: Formation of Bipyridyl-Stabilized Alkyls, Anilides, and Terminal Acetylides , 2004 .

[11]  Z. Hou,et al.  Tetranuclear rare earth metal polyhydrido complexes composed of "(C5Me4SiMe3)LnH2" Units. Unique reactivities toward unsaturated C-C, C-N, and C-O bonds. , 2004, Journal of the American Chemical Society.

[12]  Z. Hou,et al.  Isolation and structural characterization of a polyhydrido lanthanide cluster complex consisting of (C5Me4SiMe3)LuH2 units , 2003 .

[13]  Mark D. Smith,et al.  CH and PC bond activations of PMe2Ph ligands by an octahedral Ru6 cluster , 2002 .

[14]  T. Tilley,et al.  Organolutetium Complexes in σ-Bond Metathesis Reactions Involving Silicon. Catalysts for the Hydrogenolysis of Si−C Bonds , 2001 .

[15]  S. Arndt,et al.  Dimeric Hydrido Complexes of Rare-Earth Metals Containing a Linked Amido−Cyclopentadienyl Ligand: Synthesis, Characterization, and Monomer−Dimer Equilibrium , 2000 .

[16]  M. Ephritikhine.  Synthesis, Structure, and Reactions of Hydride, Borohydride, and Aluminohydride Compounds of the f-Elements. , 1997, Chemical reviews.

[17]  I. Beletskaya,et al.  Reactivity of lanthanide and yttrium hydrides and hydrocarbyls toward organosilicon hydrides and related compounds , 1997 .

[18]  T. Tilley,et al.  Lanthanide–tungsten heterobimetallic complexes viaσ-bond metathesis , 1994 .

[19]  I. Beletskaya,et al.  Bimetallic lanthanide complexes with lanthanide-transition metal bonds. Molecular structure of (C4H8O)(C5H5)2LuRu(CO)2(C5H5). The use of 139La NMR spectroscopy , 1993 .

[20]  Malcolm L. H. Green,et al.  New lanthanide–hydrogen–transition metal compounds: [{(PMe3)3WH5}2Yb·L3] and [{(η-C5H5)2NbH2}2Yb·L3] where L3=(MeOCH2CH2)2O , 1993 .

[21]  J. Ziller,et al.  Synthesis, structure, and reactivity of heterometallic polyhydride complexes of rhenium with yttrium and lutetium , 1992 .

[22]  D. Tocher,et al.  The synthesis and characterisation of a dirhodium(II) compound with bridging orthometallated dimethylphenylphosphine ligands , 1991 .

[23]  J. Ziller,et al.  Reversible opening and closing of hetero trimetallic units in (C5H5)2Y(THF)Re2H7(PMe2Ph)4 and (C5H5)2LuRe2H7(PMe2Ph)4 , 1990 .

[24]  D. Tocher,et al.  New ortho-metallated dirhodium(II) compounds , 1989 .

[25]  Y. Moro-oka,et al.  Hydride and borohydride derivatives of (pentamethylcyclopentadienyl)(tertiary phosphine)ruthenium , 1987 .

[26]  W. Evans,et al.  Organolanthanide and organoyttrium hydride chemistry. 6. Direct synthesis and /sup 1/H NMR spectral analysis of the trimetallic yttrium and yttrium-zirconium tetrahydride complexes, (((C/sub 5/H/sub 5/)/sub 2/YH)/sub 3/H)(Li(THF)/sub 4/) and ((CCH/sub 3/C/sub 5/H/sub 4/)/sub 2/YH)/sub 2/((CH/sub 3/C , 1984 .