A detailed physical model for ion implant induced damage in silicon

A unified physically based ion implantation damage model has been developed which successfully predicts both the impurity profiles and the damage profiles for a wide range of implant conditions for arsenic, phosphorus, BF/sub 2/, and boron implants into single-crystal silicon. In addition, the amorphous layer thicknesses predicted by this new damage model are also in excellent agreement with experimental measurements. This damage model is based on the physics of point defects in silicon, and explicitly simulates the defect production, diffusion, and their interactions which include interstitial-vacancy recombination, clustering of same type of defects, defect-impurity complex formation, emission of mobile defects from clusters, and surface effects for the first time. New computationally efficient algorithms have been developed to overcome the barrier of the excessive computational requirements. In addition, the new model has been incorporated in the UT-MARLOWE ion implantation simulator, and has been developed primarily for use in engineering workstations. This damage model is the most physical model in the literature to date within the framework of the binary collision approximation (BCA), and provides the required, accurate as-implanted impurity profiles and damage profiles for transient enhanced diffusion (TED) simulation.

[1]  J. Poate,et al.  Atomistic calculations of ion implantation in Si: Point defect and transient enhanced diffusion phenomena , 1996 .

[2]  H. L. Heinisch,et al.  Defect production in simulated cascades: Cascade quenching and short-term annealing , 1983 .

[3]  G. D. Watkins,et al.  DEFECTS IN IRRADIATED SILICON: ELECTRON PARAMAGNETIC RESONANCE OF THE DIVACANCY , 1965 .

[4]  A. Tasch,et al.  Monte Carlo simulation of boron implantation into single-crystal silicon , 1992 .

[5]  Lin H. Yang,et al.  Ab initio pseudopotential calculations of point defects and boron impurity in silicon , 1995 .

[6]  M. Jaraíz,et al.  Diffusion and interactions of point defects in silicon: molecular dynamics simulations , 1995 .

[7]  R. Tauber,et al.  Formation of amorphous layers by ion implantation , 1985 .

[8]  B. Obradovic,et al.  Monte Carlo simulation of ion implantation damage process in silicon , 1996, International Electron Devices Meeting. Technical Digest.

[9]  G. Vineyard Frequency factors and isotope effects in solid state rate processes , 1957 .

[10]  M. Jaraíz,et al.  Computer simulation of point-defect distributions generated by ion implantation , 1993 .

[11]  F. L. Vook,et al.  Relation of neutron to ion damage annealing in Si and Ge , 1969 .

[12]  M. Posselt,et al.  Crystal-trim and its application to investigations on channeling effects during ion implantation , 1994 .

[13]  J. Ziegler,et al.  stopping and range of ions in solids , 1985 .

[14]  T. Feudel,et al.  Modeling of Damage Accumulation during Ion Implantation into Single‐Crystalline Silicon , 1997 .

[15]  Brown,et al.  Calculation of thermodynamic and transport properties of intrinsic point defects in silicon. , 1993, Physical review. B, Condensed matter.

[16]  D. K. Brice,et al.  ION IMPLANTATION DEPTH DISTRIBUTIONS: ENERGY DEPOSITION INTO ATOMIC PROCESSES AND ION LOCATIONS , 1970 .

[17]  Brian J. Mulvaney,et al.  PEPPER-a process simulator for VLSI , 1989, IEEE Trans. Comput. Aided Des. Integr. Circuits Syst..

[18]  James F. Gibbons,et al.  Displacement criterion for amorphization of silicon during ion implantation , 1981 .

[19]  Dynamic simulation of damage accumulation during implantation of BF2+ molecular ions into crystalline silicon , 1995 .

[20]  Lee,et al.  Fully relaxed point defects in crystalline silicon. , 1993, Physical review. B, Condensed matter.

[21]  Cowern,et al.  Reactions of point defects and dopant atoms in silicon. , 1992, Physical review letters.

[22]  M. Robinson,et al.  Slowing‐down time of energetic ions in solids , 1975 .

[23]  P. A. Stolk,et al.  Implantation and transient B diffusion in Si: The source of the interstitials , 1994 .

[24]  P. Holloway,et al.  Optical investigations of ion implant damage in silicon , 1988 .

[25]  S. J. Morris,et al.  Monte Carlo simulation of arsenic ion implantation in (100) single-crystal silicon , 1996 .

[26]  Mark T. Robinson,et al.  Computer simulation of atomic-displacement cascades in solids in the binary-collision approximation , 1974 .

[27]  J. Ziegler THE STOPPING AND RANGE OF IONS IN SOLIDS , 1988 .

[28]  T. D. Rubia,et al.  Ion-beam processing of silicon at keV energies: A molecular-dynamics study. , 1996, Physical review. B, Condensed matter.

[29]  F. Morehead,et al.  Formation of Amorphous Silicon by Ion Bombardment as a Function of Ion, Temperature, and Dose , 1972 .