Correlation Between UV/Condensation and Xe Artificial Weathering Tests on Ethylene–Propylene–Diene Monomer Rubber

Artificial weathering tests on ethylene–propylene–diene monomer (EPDM) rubber were conducted in a fluorescent UV/condensation weathering equipment (E-UV environment) and a xenon lamp light exposure and weathering equipment (E-Xe environment) for different time periods. The correlation between E-UV and E-Xe environment was investigated by using crosslink density as criteria. Thermal gravimetric analysis (TGA) was used to evaluate the thermal stability of EPDM. The fracture morphology was monitored by scanning electron microscope (SEM). The results showed that the correlation between E-UV and E-Xe environments can be expressed as: $$ t_{\text{Xe}} = - 7.4818 + 1.1837t_{{{\text{Xe}}{-}{\text{UV}}}} , $$ where the correlation coefficient R is 0.9856. The thermal stability of EPDM did not deteriorate dramatically on exposure to the two artificial weathering environments. An oxidation layer was formed after 90 days of exposure.

[1]  Xiaogang Li,et al.  Surface degradation of ethylene–propylene–diene monomer (EPDM) containing 5-ethylidene-2-norbornene (ENB) as diene in artificial weathering environment , 2008 .

[2]  Agnès Rivaton,et al.  Radiochemical ageing of ethylene–propylene–diene elastomers. 4. Evaluation of some anti-oxidants , 2006 .

[3]  T. Zaharescu,et al.  Radiochemical oxidation of ethylene–propylene elastomers in the presence of some phenolic antioxidants , 1999 .

[4]  A. Meghea,et al.  Degradation of ethylene-propylene elastomers in the presence of ozone , 1995 .

[5]  Jong-Shin Huang,et al.  Effects of thermal aging on fatigue of carbon black–reinforced EPDM rubber , 2007 .

[6]  N. Wada,et al.  Reference materials for weathering tests on rubber products , 2006 .

[7]  S. Hvilsted,et al.  Surface characterisation of ethylene-propylene-diene rubber upon exposure to aqueous acidic solution , 2006 .

[8]  Kristoffer Almdal,et al.  A novel method for monitoring chemical degradation of crosslinked rubber by stress relaxation under tension , 2006 .

[9]  P. Kingshott,et al.  Chemical degradation of crosslinked ethylene-propylene-diene rubber in an acidic environment. Part I. Effect on accelerated sulphur crosslinks , 2006 .

[10]  Jin Gao,et al.  Aging of ethylene–propylene–diene monomer (EPDM) in artificial weathering environment , 2007 .

[11]  K. Gillen,et al.  Monitoring the degradation of a thermally aged EPDM terpolymer by 1H NMR relaxation measurements of solvent swelled samples , 2002 .