Review of recent development in Co-based catalysts supported on carbon materials for Fischer–Tropsch synthesis

Abstract Diminishing petroleum reserves, sharp fluctuations of crude oil prices, increasingly stringent environmental regulations and the global demand for a decreased dependence on petroleum for the production of fuels and chemicals, are the main driving force for the recent renewed interest in Fischer–Tropsch (FT) synthesis in academia and industry. Cobalt catalyst is the preferred catalyst for the production of long-chain paraffins because of its high activity, low water–gas shift activity and comparatively low price. Carbon materials including traditional activated carbons, carbon nanotubes and nanofibres, carbon spheres and mesoporous carbons have been used as the support for cobalt catalyst in the past 10 years for its inert property. The microstructures (e.g., carbon porosity, cobalt particle size, cobalt location and cobalt dispersion) of these carbon supported cobalt catalyst determine the CO conversion and product selectivity. In this paper, we focus on the most recent developments around carbon support structure effect, cobalt intrinsic properties and promoter effect on carbon supported cobalt catalyst for FT synthesis. The nitrogen doping effect, confinement effect and cobalt particle size effect on carbon nanotubes supported Co catalysts are further presented in this review.

[1]  Jinlin Li,et al.  Fischer–Tropsch synthesis: the effect of Al2O3 porosity on the performance of Co/Al2O3 catalyst , 2005 .

[2]  D. Goodman,et al.  Particle size effects in Fischer–Tropsch synthesis by cobalt , 2012 .

[3]  J. Barrault,et al.  Hydrogenation of carbon monoxide on carbon-supported cobalt rare earth catalysts , 1986 .

[4]  Xiulian Pan,et al.  Tailored cutting of carbon nanotubes and controlled dispersion of metal nanoparticles inside their channels , 2008 .

[5]  S. Biniak,et al.  The effect of the gradual thermal decomposition of surface oxygen species on the chemical and catalytic properties of oxidized activated carbon , 2002 .

[6]  Yongqing Zhang,et al.  Fischer–Tropsch synthesis: supercritical conversion using a Co/Al2O3 catalyst in a fixed bed reactor☆ , 2003 .

[7]  Yuhan Sun,et al.  Chemical treatment of γ-Al2O3 and its influence on the properties of Co-based catalysts for Fischer–Tropsch synthesis , 2003 .

[8]  D. Durand,et al.  Impact of aqueous impregnation on the long-range ordering and mesoporous structure of cobalt containing MCM-41 and SBA-15 materials , 2005 .

[9]  Chuang Xing,et al.  Controllable encapsulation of cobalt clusters inside carbon nanotubes as effective catalysts for Fischer–Tropsch synthesis , 2013 .

[10]  Gerald P. Huffman,et al.  Incorporation of catalytic dehydrogenation into Fischer–Tropsch synthesis of liquid fuels from coal to minimize carbon dioxide emissions , 2011 .

[11]  K. D. de Jong,et al.  Carbon Nanofibers: Catalytic Synthesis and Applications , 2000 .

[12]  Anders Holmen,et al.  Fischer–Tropsch synthesis: Cobalt particle size and support effects on intrinsic activity and product distribution , 2008 .

[13]  Ajay K. Dalai,et al.  Fischer–Tropsch synthesis over cobalt catalyst supported on carbon nanotubes in a slurry reactor , 2008 .

[14]  Nicolas Abatzoglou,et al.  Co, Ru and K loadings effects on the activity and selectivity of carbon nanotubes supported cobalt catalyst in Fischer–Tropsch synthesis , 2009 .

[15]  Tao Wang,et al.  Influence of lanthanum on the performance of Zr-Co/activated carbon catalysts in Fischer-Tropsch synthesis , 2008 .

[16]  Mietek Jaroniec,et al.  Synthesis of New, Nanoporous Carbon with Hexagonally Ordered Mesostructure , 2000 .

[17]  P. Serp,et al.  An efficient strategy to drive nanoparticles into carbon nanotubes and the remarkable effect of confinement on their catalytic performance. , 2009, Angewandte Chemie.

[18]  Jinlin Li,et al.  Fischer–Tropsch synthesis: The role of pore size for Co/SBA-15 catalysts , 2008 .

[19]  T. Fuller,et al.  Carbon as Catalyst and Support for Electrochemical Energy Conversion , 2014 .

[20]  E. Steen,et al.  Silica supported cobalt Fischer-Tropsch catalysts: effect of pore diameter of support , 2002 .

[21]  A. Dalai,et al.  Fischer–Tropsch synthesis over carbon nanotubes supported cobalt catalysts in a fixed bed reactor: Influence of acid treatment , 2009 .

[22]  A. Tavasoli,et al.  Enhancement of activity, selectivity and stability of CNTs-supported cobalt catalyst in Fischer–Tropsch via CNTs functionalization , 2014 .

[23]  Ahmad Tavasoli,et al.  Cobalt supported on carbon nanotubes — A promising novel Fischer–Tropsch synthesis catalyst , 2008 .

[24]  Yuhan Sun,et al.  Silylated Co/SBA-15 catalysts for Fischer―Tropsch synthesis , 2011 .

[25]  C. Pham‐Huu,et al.  Selective deposition of metal nanoparticles inside or outside multiwalled carbon nanotubes. , 2009, ACS nano.

[26]  S. Järås,et al.  On the selectivity of cobalt-based Fischer-Tropsch catalysts : Evidence for a common precursor for methane and long-chain hydrocarbons , 2010 .

[27]  D. Billing,et al.  Autoreduction and Catalytic Performance of a Cobalt Fischer–Tropsch Synthesis Catalyst Supported on Nitrogen‐Doped Carbon Spheres , 2010 .

[28]  Nicolas Abatzoglou,et al.  Effects of Confinement in Carbon Nanotubes on the Activity, Selectivity, and Lifetime of Fischer—Tropsch Co/Carbon Nanotube Catalysts , 2010 .

[29]  Jinlin Li,et al.  Effect of Silylation of SBA-15 on Its Supported Cobalt Catalysts for Fischer-Tropsch Synthesis , 2009 .

[30]  R. C. Bansal,et al.  Influence of hydrogen chemisorption on the subsequent chemisorption of oxygen on activated graphon , 1974 .

[31]  W. Chu,et al.  The nature of cobalt species in carbon nanotubes and their catalytic performance in Fischer–Tropsch reaction , 2009 .

[32]  Wei Chen,et al.  Effect of confinement in carbon nanotubes on the activity of Fischer-Tropsch iron catalyst. , 2008, Journal of the American Chemical Society.

[33]  A. Khodakov,et al.  Pore-Size Control of Cobalt Dispersion and Reducibility in Mesoporous Silicas , 2001 .

[34]  Neil J. Coville,et al.  Correlating the preparation and performance of cobalt catalysts supported on carbon nanotubes and carbon spheres in the Fischer–Tropsch synthesis , 2011 .

[35]  Zhenhua Li,et al.  Highly dispersed cobalt on N-doped carbon nanotubes with improved Fischer–Tropsch synthesis activity , 2014 .

[36]  D. Murzin,et al.  Effect of catalyst synthesis parameters on the metal particle size , 2013 .

[37]  Sang Woo Kim,et al.  Fischer–Tropsch Synthesis over cobalt based catalyst supported on different mesoporous silica , 2012 .

[38]  J. Goodwin,et al.  CO Hydrogenation on Ru-Promoted Co/MCM-41 Catalysts , 2002 .

[39]  M. Aguilar,et al.  Catalytic behavior of Co/(Nanoβ-Zeolite) bifunctional catalysts for Fischer–Tropsch reactions , 2011 .

[40]  H. Boehm.,et al.  Some aspects of the surface chemistry of carbon blacks and other carbons , 1994 .

[41]  M. K. Gnanamani,et al.  Fischer–Tropsch synthesis: Support and cobalt cluster size effects on kinetics over Co/Al2O3 and Co/SiO2 catalysts , 2011 .

[42]  Y. Mortazavi,et al.  Fischer–Tropsch synthesis over cobalt dispersed on carbon nanotubes-based supports and activated carbon , 2009 .

[43]  N. Coville,et al.  Promotion of Co/carbon sphere Fischer–Tropsch catalysts by residual K and Mn from carbon oxidation by KMnO4 , 2012 .

[44]  W. Xie,et al.  Effect of catalyst confinement and pore size on Fischer-Tropsch synthesis over cobalt supported on carbon nanotubes , 2012, Science China Chemistry.

[45]  G. Bezemer,et al.  Direct evidence of water-assisted sintering of cobalt on carbon nanofiber catalysts during simulated Fischer-Tropsch conditions revealed with in situ mossbauer spectroscopy. , 2010, Journal of the American Chemical Society.

[46]  J. Wittayakun,et al.  Effect of support morphology and Pd promoter on Co/SBA-15 for Fischer–Tropsch Synthesis , 2014 .

[47]  J. G. Goodwin,et al.  Effect of Pretreatment on the Activity of a Ru-Promoted Co/Al2O3Fischer–Tropsch Catalyst☆ , 1997 .

[48]  Isabel Díaz,et al.  Fischer–Tropsch synthesis of hydrocarbons over mesoporous Co/SBA-15 catalysts: the influence of metal loading, cobalt precursor, and promoters , 2003 .

[49]  J. Goodwin,et al.  Synthesis and characteristics of MCM-41 supported CoRu catalysts , 2002 .

[50]  Agustín Martínez,et al.  Cobalt supported on morphologically tailored SBA-15 mesostructures: The impact of pore length on metal dispersion and catalytic activity in the Fischer–Tropsch synthesis , 2009 .

[51]  K. P. Jong,et al.  Investigation of promoter effects of manganese oxide on carbon nanofiber-supported cobalt catalysts for Fischer–Tropsch synthesis , 2006 .

[52]  Weiyong Ying,et al.  The comprehensive kinetics of Fischer–Tropsch synthesis over a Co/AC catalyst on the basis of CO insertion mechanism , 2013 .

[53]  Jinlin Li,et al.  Ruthenium promotion of Co/SBA-15 catalysts with high cobalt loading for Fischer–Tropsch synthesis , 2009 .

[54]  Andrew Dicks,et al.  The role of carbon in fuel cells , 2006 .

[55]  Alexis T. Bell,et al.  Effects of Mn promotion on the activity and selectivity of Co/SiO2 for Fischer–Tropsch Synthesis , 2012 .

[56]  Ajay K. Dalai,et al.  Iron catalysts supported on carbon nanotubes for Fischer–Tropsch synthesis: Effect of catalytic site position , 2009 .

[57]  L. Pfefferle,et al.  Effect of surface oxygen containing groups on the catalytic activity of multi-walled carbon nanotube supported Pt catalyst , 2010 .

[58]  V. Gómez-Serrano,et al.  Oxidation of activated carbon by dry and wet methods: Surface chemistry and textural modifications , 2010 .

[59]  N. Coville,et al.  Fischer–Tropsch synthesis over model iron catalysts supported on carbon spheres: The effect of iron precursor, support pretreatment, catalyst preparation method and promoters , 2010 .

[60]  Yi Zhang,et al.  Multi-functional alumina–silica bimodal pore catalyst and its application for Fischer-Tropsch synthesis , 2005 .

[61]  Zhenhua Li,et al.  Comparison of induction behavior of Co/CNT and Co/SiO2 catalysts for the Fischer-Tropsch synthesis , 2012 .

[62]  A. Dalai,et al.  Alkali-Promoted Trimetallic Co−Rh−Mo Sulfide Catalysts for Higher Alcohols Synthesis from Synthesis Gas: Comparison of MWCNT and Activated Carbon Supports , 2010 .

[63]  Zhenhua Li,et al.  Effect of carbon support on Fischer–Tropsch synthesis activity and product distribution over Co-based catalysts , 2013 .

[64]  K. P. Jong,et al.  Cobalt supported on carbon nanofibers- a promising novel Fischer-Tropsch catalyst , 2004 .

[65]  Jinlin Li,et al.  Effect of catalyst pore size on the catalytic performance of silica supported cobalt Fischer–Tropsch catalysts , 2006 .

[66]  R. Revel,et al.  Differences in the characteristics and catalytic properties of cobalt-based Fischer–Tropsch catalysts supported on zirconia and alumina , 2004 .

[67]  Xianming Li,et al.  Effect of La2O3 doping on syntheses of C1–C18 mixed linear α-alcohols from syngas over the Co/AC catalysts , 2009 .

[68]  Enrique Iglesia,et al.  Design, synthesis, and use of cobalt-based Fischer-Tropsch synthesis catalysts , 1997 .

[69]  Wei Chu,et al.  Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels. , 2007, Chemical reviews.

[70]  R. Bechara,et al.  Catalytic properties of Co/Al2O3 system for hydrocarbon synthesis , 2001 .

[71]  Li Yan,et al.  The formation of Co2C species in activated carbon supported cobalt-based catalysts and its impact on Fischer–Tropsch reaction , 2005 .

[72]  D. Zhao,et al.  A facile aqueous route to synthesize highly ordered mesoporous polymers and carbon frameworks with Ia3d bicontinuous cubic structure. , 2005, Journal of the American Chemical Society.

[73]  Krijn P. de Jong,et al.  Design of supported cobalt catalysts with maximum activity for the Fischer-Tropsch synthesis , 2010 .

[74]  J. Wolan,et al.  Synthesis of Tailored Eggshell Cobalt Catalysts for Fischer–Tropsch Synthesis Using Wet Chemistry Techniques , 2012 .

[75]  Qingling Chen,et al.  Effect of vacuum impregnation on the performance of Co/SiO2 Fischer-Tropsch catalyst , 2011 .

[76]  Freek Kapteijn,et al.  Cobalt particle size effects in the Fischer-Tropsch reaction studied with carbon nanofiber supported catalysts. , 2006, Journal of the American Chemical Society.

[77]  Ye Wang,et al.  Synthesis of SBA-15 with different pore sizes and the utilization as supports of high loading of cobalt catalysts , 2001 .

[78]  Qinghong Zhang,et al.  Development of Novel Catalysts for Fischer–Tropsch Synthesis: Tuning the Product Selectivity , 2010 .

[79]  J. Figueiredo,et al.  Modification of the surface chemistry of activated carbons , 1999 .

[80]  Nick Burke,et al.  Porous carbon-supported catalysts for energy and environmental applications: A short review , 2011 .

[81]  L. Gengembre,et al.  Effect of cobalt precursor and pretreatment conditions on the structure and catalytic performance of cobalt silica-supported Fischer–Tropsch catalysts , 2005 .

[82]  E. Steen,et al.  Structure sensitivity of the Fischer-Tropsch activity and selectivity on alumina supported cobalt catalysts , 2013 .

[83]  Yuhan Sun,et al.  Fischer–Tropsch Synthesis over Ordered Mesoporous Carbon Supported Cobalt Catalysts: The Role of Amount of Carbon Precursor in Catalytic Performance , 2012, Catalysis Letters.

[84]  Wenping Ma,et al.  Fischer−Tropsch Synthesis over Activated-Carbon-Supported Cobalt Catalysts: Effect of Co Loading and Promoters on Catalyst Performance , 2004 .

[85]  Fischer-Tropsch synthesis over Co/SiMCM-41 and Co/SiO2 materials: The role of support at different cobalt loadings , 2005 .

[86]  S. Järås,et al.  Effect of Ti and Al addition via direct synthesis to SBA-15 as support for cobalt based Fischer-Tropsch catalysts , 2012 .

[87]  F. Fernandes,et al.  Ruthenium promotion of Co/SBA-15 catalysts for Fischer-Tropsch synthesis in slurry-phase reactors , 2012 .

[88]  J. Bitter,et al.  On the origin of the cobalt particle size effects in Fischer-Tropsch catalysis. , 2009, Journal of the American Chemical Society.

[89]  Zhenhua Li,et al.  Effect of Carbon Porosity and Cobalt Particle Size on the Catalytic Performance of Carbon Supported Cobalt Fischer–Tropsch Catalysts , 2014 .

[90]  D. Glasser,et al.  Fischer–Tropsch synthesis over iron catalysts supported on carbon nanotubes , 2005 .

[91]  A. Holmen,et al.  Fischer–Tropsch synthesis over γ-alumina-supported cobalt catalysts: Effect of support variables , 2007 .

[92]  Liping Guo,et al.  Ordered mesoporous carbon for electrochemical sensing: a review. , 2012, Analytica chimica acta.