论文信息 - Suppression of cluster unsaturation by formation of extensive but long-range metal-metal bonding: crystal structures of [Ru3H(pyS)(CO)9] and [{Ru3H(pyS)(CO)7}3], where pyS is the pyridine-2-thiolato ligand

Suppression of cluster unsaturation by formation of extensive but long-range metal-metal bonding: crystal structures of [Ru3H(pyS)(CO)9] and [{Ru3H(pyS)(CO)7}3], where pyS is the pyridine-2-thiolato ligand

The cluster [Ru 3 (CO) 12 ] reacts with 1 mol equiv of pyridine-2-thiol (pySH) in refluxing cyclohexane to give the yellow cluster [Ru 3 (μ-H)(μ 3 -pyS)(CO) 9 ] (1). Crystals of 1 are monoclinic, of space group P2 1 /c.

K. Hardcastle | A. Deeming | M. Karim