Combined Fire Retardant and Wood Preservative Treatments for Outdoor Wood Applications – A Review of the Literature

A collaborative Australian national project funded jointly by the Commonwealth Scientific and Industrial Research Organisation and the Forest & Wood Products Research and Development Corporation has been undertaken to develop a ‘proof of concept’ for a combined fire retardant/wood preservative treatment technology for P. radiata to satisfy the requirements of both the Australian Bushfire and Wood Preservation Standards. The focus of the work was on products that found use in exposed outdoor, above-ground applications. This paper reviews the literature currently available regarding the impregnation of wood with chemical systems that offer resistance to both fire and biodegradation and are also suitable for exterior applications. We have found that in general, researchers have chosen to utilise the dual functionality of boron compounds to achieve both fire retardancy and wood preservation. Often, such systems are applied in multi-step processes, which involve an impregnation step followed by a curing step. Because of the leaching problems associated with boron, a great deal of effort has gone into the development of systems which fix the boron into wood so that its preservation properties can be maintained throughout the useful life of the material.

[1]  S. Saka,et al.  Wood-inorganic composites prepared by sol-gel processing, 1: Wood-inorganic composites with porous structure , 1992 .

[2]  Haruhiko Yamaguchi,et al.  Silicic acid: boric acid complexes as wood preservatives , 2003, Wood Science and Technology.

[3]  Menachem Lewin Flame Retarding of Wood by Chemical Modification with Bromate-Bromide Solutions , 1997 .

[4]  Kunio Tsunoda,et al.  Preservative properties of vapor-boron-treated wood and wood-based composites , 2001, Journal of Wood Science.

[5]  Yuji Imamura,et al.  Decay and termite resistance of boron-treated and chemically modified wood by in situ co-polymerization of allyl glycidyl ether (AGE) with methyl methacrylate (MMA) , 2004 .

[6]  Roger M. Rowell,et al.  Thermal properties of wood reacted with a phosphorus pentoxide-amine system , 2004 .

[7]  S. Saka,et al.  Wood-inorganic composites prepared by the sol-gel process. V. Fire-resisting properties of the SiO2-P2O5-B2O3 wood-inorganic composites. , 1996 .

[8]  Ergun Baysal,et al.  Determination of Oxygen Index Levels and Thermal Analysis of Scots Pine (Pinus sylvestris L.) Impregnated with Melamine Formaldehyde-Boron Combinations , 2002 .

[9]  S. Saka,et al.  Wood-inorganic composites prepared by the sol-gel process. VI. Effects of a property-enhancer on fire-resistance in SiO2-P2O5 and SiO2-B2O3 wood-inorganic composites. , 1996 .

[10]  G. Zaikov,et al.  Recent Advances in Flame Retardancy of Polymeric Materials (Materials, Applications, Industry Developments, Markets) , 1994, Engineering Plastics.

[11]  H. Yamaguchi,et al.  Low molecular weight silicic acid – inorganic compound complex as wood preservative , 2002, Wood Science and Technology.

[12]  Mehmet Colak,et al.  Amount of leachant and water absorption levels of wood treated with borates and water repellents. , 2006, Bioresource technology.