The Degradation of Indigo Sodium Disulphonate by Chromium Isomorphic Replacement in Magnetite

This study was designed to investigate the degradation of indigo sodium disulphonate (ISD, a kind of indigoiddyes) in heterogeneous Fenton system (H2O2/Fe3-xCrxO4). The co-precipitation was employed to synthesize a series of Cr-doped magnetite. The result of XRD indicated that Chromium isomorphic replacement will not cause significant changes in the structure of the magnetite. The thermogravimetric (TG) and differential scanning calorimetry analysis was applied in the samples. The adsorption data showed that strong acidic condition and high concentration Cr-containing magnetite contributed to the enhancement of adsorbing capacity. The degradation experiment was carried out in consideration of 4 aspects, including pH, Fe3-xCrxO4, H2O2 concentration and catalyst dosage, stating that Cr-doped magnetite made for degrading indigo sodium disulphonate.

[1]  J. Fierro,et al.  Zero valent iron (ZVI) mediated Fenton degradation of industrial wastewater: Treatment performance and characterization of final composites , 2015 .

[2]  A. Figoli,et al.  Fenton-like catalytic activity of wet-spun chitosan hollow fibers loaded with Fe3O4 nanoparticles: Batch and continuous flow investigations , 2015 .

[3]  S. Hashemian,et al.  Hydrothermal synthesis of nano cavities of Al-MCF for adsorption of indigo carmine from aqueous solution , 2015 .

[4]  J. Casas,et al.  Comparison of Fenton and Fenton-like oxidation for the treatment of cosmetic wastewater. , 2014, Water science and technology : a journal of the International Association on Water Pollution Research.

[5]  Manhong Huang,et al.  A batch decolorization and kinetic study of Reactive Black 5 by a bacterial strain Enterobacter sp. GY-1 , 2011 .

[6]  H. El-Desoky,et al.  Electro-Fenton oxidation of Sunset Yellow FCF azo-dye in aqueous solutions , 2011 .

[7]  B. Moon,et al.  Fenton oxidation of Orange II by pre-reduction using nanoscale zero-valent iron , 2011 .

[8]  Xiaoliang Liang,et al.  The decolorization of Acid Orange II in non-homogeneous Fenton reaction catalyzed by natural vanadium-titanium magnetite. , 2010, Journal of hazardous materials.

[9]  M. Chaudhuri,et al.  Comparison of different advanced oxidation processes for treatment of antibiotic aqueous solution , 2010 .

[10]  Shijian Yang,et al.  Decolorization of methylene blue by heterogeneous Fenton reaction using Fe3−xTixO4 (0 ≤ x ≤ 0.78) at neutral pH values , 2009 .

[11]  D. Mantzavinos,et al.  Removal of residual pharmaceuticals from aqueous systems by advanced oxidation processes. , 2009, Environment international.

[12]  M. I. Maldonado,et al.  Pilot plant scale reactive dyes degradation by solar photo-Fenton and biological processes , 2008 .

[13]  Shaobin Wang.  A Comparative study of Fenton and Fenton-like reaction kinetics in decolourisation of wastewater , 2008 .

[14]  R. Lago,et al.  Cr-containing magnetites Fe3-xCrxO4: The role of Cr3+ and Fe2+ on the stability and reactivity towards H2O2 reactions , 2007 .

[15]  M. Oturan,et al.  Electrochemical Advanced Oxidation Processes (EAOPs) for Environmental Applications , 2007 .

[16]  R. Lago,et al.  Novel active heterogeneous Fenton system based on Fe3-xMxO4 (Fe, Co, Mn, Ni): the role of M2+ species on the reactivity towards H2O2 reactions. , 2006, Journal of hazardous materials.

[17]  R. Lago,et al.  Novel solvent free liquid-phase oxidation of β-pinene over heterogeneous catalysts based on Fe3−xMxO4 (M=Co and Mn) , 2004 .

[18]  F. Beltrán,et al.  Fenton Reagent Advanced Oxidation of Polynuclear Aromatic Hydrocarbons in Water , 1998 .

[19]  Stefan H. Bossmann,et al.  New Evidence against Hydroxyl Radicals as Reactive Intermediates in the Thermal and Photochemically Enhanced Fenton Reactions , 1998 .

[20]  André M. Braun,et al.  Industrial waste water treatment: large scale development of a light-enhanced Fenton reaction , 1997 .