New testing method for the evaluation of topographical gradients of varying strength

Passive gradient motion found in nature is becoming a point of interest for heat exchange and green energy technologies. Surfaces with a topographical gradient could potentially enhance heat exchanger performance, promote dropwise vs filmwise condensation, or delay icing on wind turbines by assisting in the removal of condensed or impacted droplets. Coating-free topographical surface tension gradients can be fabricated via various methods and need to be examined in terms of their capability for spontaneous droplet motion. In this work, a simple experimental method, coupled with numerical modeling and force analysis, for examining variable-pitch micro/nanoengineered hierarchical superhydrophobic gradients is shown. The method was validated against numerical calculations, allowing the strength of the gradients to be compared. In most cases, model predictions for droplet travel distance and velocity were within 20% of the measured data. This method could also be useful for gradient design improvements in the absence of spontaneous motion on a horizontal surface.

[1]  R. Blaikie,et al.  Force balance model for spontaneous droplet motion on bio-inspired topographical surface tension gradients , 2023, Physics of Fluids.

[2]  R. Blaikie,et al.  Development of a Coating-Less Aluminum Superhydrophobic Gradient for Spontaneous Water Droplet Motion Using One-Step Laser-Ablation. , 2022, Langmuir : the ACS journal of surfaces and colloids.

[3]  N. Pesika,et al.  Determination of the Sliding Angle of Water Drops on Surfaces from Friction Force Measurements , 2022, Langmuir : the ACS journal of surfaces and colloids.

[4]  R. Blaikie,et al.  Study of Micro- and Nanopatterned Aluminum Surfaces Using Different Microfabrication Processes for Water Management. , 2022, Langmuir : the ACS journal of surfaces and colloids.

[5]  R. Blaikie,et al.  Survey of Micro/Nanofabricated Chemical, Topographical, and Compound Passive Wetting Gradient Surfaces. , 2021, Langmuir : the ACS journal of surfaces and colloids.

[6]  Hai-dou Wang,et al.  Exploring Contact Angle Hysteresis Behavior of Droplets on the Surface Microstructure. , 2021, Langmuir : the ACS journal of surfaces and colloids.

[7]  Robin H. A. Ras,et al.  Water droplet friction and rolling dynamics on superhydrophobic surfaces , 2020, Communications Materials.

[8]  Seunghwa Ryu,et al.  How and When the Cassie-Baxter Droplet Starts to Slide on Textured Surfaces. , 2020, Langmuir : the ACS journal of surfaces and colloids.

[9]  H. Ding,et al.  Directed motion of an impinging water droplet—seesaw effect , 2020 .

[10]  Zhi-hai Jia,et al.  Wetting and adhesion energy of droplets on wettability gradient surfaces , 2020, Journal of Materials Science.

[11]  M. Chaplin Structure and Properties of Water in its Various States , 2019 .

[12]  Hao-Yang Mi,et al.  Gradient wetting state for droplet transportation and efficient fog harvest on nanopillared cicada wing surface , 2018, Materials Letters.

[13]  Jaakko V. I. Timonen,et al.  Origins of Extreme Liquid Repellency on Structured, Flat, and Lubricated Hydrophobic Surfaces. , 2018, Physical review letters.

[14]  Doris Vollmer,et al.  How drops start sliding over solid surfaces , 2017, Nature Physics.

[15]  Zuankai Wang,et al.  Long-range spontaneous droplet self-propulsion on wettability gradient surfaces , 2017, Scientific Reports.

[16]  J. A. White,et al.  Numerical study of the most stable contact angle of drops on tilted surfaces. , 2015, Langmuir : the ACS journal of surfaces and colloids.

[17]  M. Tiwari,et al.  Supercooled water drops impacting superhydrophobic textures. , 2014, Langmuir : the ACS journal of surfaces and colloids.

[18]  Luca Biferale,et al.  Stick-slip sliding of water drops on chemically heterogeneous surfaces. , 2013, Physical review letters.

[19]  L. Makkonen A thermodynamic model of sliding friction , 2012 .

[20]  Anthony M. Jacobi,et al.  Drainage of frost melt water from vertical brass surfaces with parallel microgrooves , 2012 .

[21]  F. He,et al.  Driving liquid droplets on microstructured gradient surface by mechanical vibration , 2011 .

[22]  A. Sommers Methodology for calculating the volume of condensate droplets on topographically modified, microgrooved surfaces. , 2011, Langmuir : the ACS journal of surfaces and colloids.

[23]  S. Mohamed-Nabil,et al.  Droplet dynamics over a super hydrophobic surface , 2010, 2010 3rd International Conference on Thermal Issues in Emerging Technologies Theory and Applications.

[24]  J. S. Sharp,et al.  Microtextured surfaces with gradient wetting properties. , 2010, Langmuir.

[25]  Jin Zhai,et al.  Directional water collection on wetted spider silk , 2010, Nature.

[26]  Fabrice Pardo,et al.  Drops onto gradients of texture , 2009 .

[27]  Bharat Bhushan,et al.  Micro-, nano- and hierarchical structures for superhydrophobicity, self-cleaning and low adhesion , 2009, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[28]  A. Jacobi,et al.  Wetting phenomena on micro-grooved aluminum surfaces and modeling of the critical droplet size. , 2008, Journal of colloid and interface science.

[29]  Da-Jeng Yao,et al.  Conversion of surface energy and manipulation of a single droplet across micropatterned surfaces. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[30]  K. Böhringer,et al.  Directing droplets using microstructured surfaces. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[31]  Lichao Gao,et al.  Contact angle hysteresis explained. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[32]  Abraham Marmur,et al.  Drops down the hill: theoretical study of limiting contact angles and the hysteresis range on a tilted plate. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[33]  M. Chaudhury,et al.  Ratcheting motion of liquid drops on gradient surfaces. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[34]  M. Chaudhury,et al.  Rectified Motion of Liquid Drops on Gradient Surfaces Induced by Vibration , 2002 .

[35]  F. Brochard,et al.  Motions of droplets on solid surfaces induced by chemical or thermal gradients , 1989 .

[36]  J. D’Arrigo Screening of membrane surface charges by divalent cations: an atomic representation. , 1978, The American journal of physiology.

[37]  H. P. Greenspan,et al.  On the motion of a small viscous droplet that wets a surface , 1978, Journal of Fluid Mechanics.

[38]  A. Le Bot,et al.  Dissipation of Vibration in Rough Contact , 2011 .

[39]  A. Cassie,et al.  Wettability of porous surfaces , 1944 .