Plasma Focused Ion Beam Tomography for Accurate Characterization of Black Silicon Validated by Full Wave Optical Simulation

Black silicon (BSi) is a branch of silicon material whose surface is specially processed to a micro/nanoscale structure, which can achieve ultra‐low reflectance or ultra‐high electrochemical reactivity. The diversity and complex surface structures of BSi make it challenging to commercialize BSi devices. Modeling and simulation are commonly used in the semiconductor industry to help in better understanding the material properties, predict the device performance, and provide guidelines for fabrication parameters’ optimization. The biggest challenge for BSi device modeling and simulation is obtaining accurate input surface morphological data. In this work, the 3D models of challenging BSi textures are compared as obtained by atomic force microscopy (AFM) and plasma focused ion beam (PFIB) tomography techniques. In previous work, the PFIB tomography workflow toward the application of surface topography is optimized. In this work, the 3D models obtained from both AFM and PFIB are comprehensively compared, by using the surface models as inputs for finite‐difference time‐domain‐based optical simulation. The results provide strong evidence that PFIB tomography is a better choice for characterizing highly roughened surface such as BSi and provides surface 3D models with better reliability and consistency.

[1]  D. Payne,et al.  Large volume tomography using plasma FIB-SEM: A comprehensive case study on black silicon. , 2021, Ultramicroscopy.

[2]  Xiaofeng Wang,et al.  A novel perspective on the design of thermochromic VO2 films: Combining ab initio calculations with FDTD simulations , 2020 .

[3]  R. S. Davidsen,et al.  3D characterisation using plasma FIB-SEM: A large-area tomography technique for complex surfaces like black silicon. , 2020, Ultramicroscopy.

[4]  K. McIntosh,et al.  Understanding the optics of industrial black silicon , 2018 .

[5]  P. Zhang,et al.  Review Application of Nanostructured Black Silicon , 2018, Nanoscale Research Letters.

[6]  Y. Liu,et al.  A theoretical study on the optical properties of black silicon , 2018 .

[7]  H. Savin,et al.  Surface passivation of black silicon phosphorus emitters with atomic layer deposited SiO2/Al2O3 stacks , 2017 .

[8]  Qingliang Liao,et al.  Enhanced photoelectrochemical efficiency and stability using a conformal TiO2 film on a black silicon photoanode , 2017, Nature Energy.

[9]  A. Tünnermann,et al.  The structural and optical properties of black silicon by inductively coupled plasma reactive ion etching , 2014 .

[10]  Yi-Je Juang,et al.  Black silicon SERS substrate: effect of surface morphology on SERS detection and application of single algal cell analysis. , 2014, Biosensors & bioelectronics.

[11]  Saulius Juodkazis,et al.  Bactericidal activity of black silicon , 2013, Nature Communications.

[12]  C. Frewin Atomic Force Microscopy Investigations into Biology - From Cell to Protein , 2012 .

[13]  I. Oh,et al.  Enhanced photoelectrochemical hydrogen production from silicon nanowire array photocathode. , 2012, Nano letters.

[14]  Chaobo Li,et al.  A novel method to produce black silicon for solar cells , 2011 .

[15]  Jihun Oh,et al.  Nanoporous black silicon photocathode for H2 production by photoelectrochemical water splitting , 2011 .

[16]  Surojit Chattopadhyay,et al.  Anti-reflecting and photonic nanostructures , 2010 .

[17]  Thomas Käsebier,et al.  Optical modeling of needle like silicon surfaces produced by an ICP-RIE process , 2010, Photonics Europe.

[18]  J. Jiang,et al.  Black silicon enhanced photodetectors: a path to IR CMOS , 2010, Defense + Commercial Sensing.

[19]  Paul Stradins,et al.  Efficient black silicon solar cell with a density-graded nanoporous surface: Optical properties, performance limitations, and design rules , 2009 .

[20]  Scott Ward,et al.  Nanostructured black silicon and the optical reflectance of graded-density surfaces , 2009 .

[21]  M. Bouaïcha,et al.  Laser-beam-induced current mapping evaluation of porous silicon-based passivation in polycrystalline silicon solar cells , 2009 .

[22]  Martin A. Green,et al.  Self-consistent optical parameters of intrinsic silicon at 300 K including temperature coefficients , 2008 .

[23]  Kok-Keong Lew,et al.  Silicon nanowire array photelectrochemical cells. , 2007, Journal of the American Chemical Society.

[24]  Gengfeng Zheng,et al.  Nanowire-Based Nanoelectronic Devices in the Life Sciences , 2007 .

[25]  Charles M. Lieber,et al.  Nanowire-based biosensors. , 2006, Analytical chemistry.

[26]  N. Jalili,et al.  A review of atomic force microscopy imaging systems: application to molecular metrology and biological sciences , 2004 .

[27]  J. Tascón,et al.  Adhesion artefacts in atomic force microscopy imaging , 2000, Journal of microscopy.

[28]  Udo D. Schwarz,et al.  Tip artefacts in scanning force microscopy , 1994 .

[29]  Dror Sarid,et al.  Review of scanning force microscopy , 1991 .

[30]  志村 史夫 Semiconductor silicon crystal technology , 1989 .

[31]  D. Lynch,et al.  Handbook of Optical Constants of Solids , 1985 .