Determination of light extinction efficiency of diesel soot from smoke opacity measurements

An experimental method for the indirect determination of the light extinction efficiency of the exhaust gas emitted by diesel engines is proposed in this paper, based on the simultaneous measurement of spot opacity and continuous opacity, together with the double modelling of the associated soot concentration. The first model simulates the projection of a differently sized soot particle population enclosed in an exhaust gas sample on the filter of a spot opacimeter. The second one simulates the light extinction caused by the soot particles flowing in the exhaust gas stream in an online continuous opacimeter, on the basis of the Beer–Lambert law. This method is an alternative to other theoretical or semi-empirical complex methods which have proved to be inadequate in the case of soot agglomerates. The application of this method to a set of experimental smoke measurements from a commercial light-duty DI diesel engine typical of vehicle road transportation permitted us to draw conclusions about the effect of different engine conditions on the mean light extinction efficiency of the soot particles flowing in the raw exhaust gas stream.

[1]  G. M. Makhviladze,et al.  The effect of particle coagulation and fractal structure on the optical properties and detection of smoke , 2001 .

[2]  D. Roessler,et al.  Diesel particle mass concentration by optical techniques. , 1982, Applied optics.

[3]  A. Jones Scattering efficiency factors for agglomerates for small spheres , 1979 .

[4]  S. Merola,et al.  Analysis of exhausts emitted by i.c. engines and stationary burners, by means of u.v. extinction and fluorescence spectroscopy. , 2001, Chemosphere.

[5]  C. Tropea,et al.  Light Scattering from Small Particles , 2003 .

[6]  Henning Bockhorn,et al.  Progress in characterization of soot formation by optical methods , 2002 .

[7]  George G. Muntean,et al.  A Theoretical Model for the Correlation of Smoke Number to Dry Particulate Concentration in Diesel Exhaust , 1999 .

[8]  M. Choi,et al.  Measurement of dimensionless soot extinction constant using a gravimetric sampling technique , 1998 .

[9]  S. Friedlander,et al.  Smoke, dust, and haze , 2000 .

[10]  M. Quinten Enhanced optical response by soot agglomerates , 1997 .

[11]  T. Charalampopoulos,et al.  On the inverse scattering problem for characterization of agglomerated particulates: partial derivative formulation , 1995 .

[12]  Christopher R. Shaddix,et al.  The elusive history of m∼= 1.57 – 0.56i for the refractive index of soot , 1996 .

[13]  D. Mackowski,et al.  Calculation of total cross sections of multiple-sphere clusters , 1994 .

[14]  V. Babenko Influence of carbon aerosol aggregation on its optical properties in the asymptotic model of fractal cluster , 1997 .

[15]  C. Sorensen,et al.  Light scattering study of fractal cluster aggregation near the free molecular regime , 1997 .

[16]  Ian Colbeck,et al.  The morphology and optical properties of soot produced by different fuels , 1997 .

[17]  G. Fournier,et al.  Simple approximation to extinction efficiency valid over all size parameters. , 1990, Applied optics.

[18]  Choongsik Bae,et al.  Detailed Characterization of Morphology and Dimensions of Diesel Particulates via Thermophoretic Sampling , 2001 .

[19]  Jian-Qi Zhao,et al.  Bridging technique for calculating the extinction efficiency of arbitrary shaped particles. , 2003, Applied optics.

[20]  Michael R. Zachariah,et al.  Energy accumulation in nanoparticle collision and coalescence processes , 2002 .

[21]  C. Megaridis,et al.  Absorption and scattering of light by polydisperse aggregates. , 1991, Applied optics.

[22]  P. Mcmurry,et al.  Structural Properties of Diesel Exhaust Particles Measured by Transmission Electron Microscopy (TEM): Relationships to Particle Mass and Mobility , 2004 .

[23]  David M. Roessler,et al.  Carbon aerosol visibility vs particle size distribution. , 1978, Applied optics.

[24]  E. Mikhailov,et al.  Restructuring of soot particles: Experimental study , 1996 .

[25]  M. V. Berry,et al.  Optics of Fractal Clusters Such as Smoke , 1986 .

[26]  S. Friedlander Smoke, Dust, and Haze: Fundamentals of Aerosol Dynamics , 2000 .

[27]  N Ladommatos,et al.  Optical diagnostics for soot and temperature measurement in diesel engines , 1998 .

[28]  A. Coppalle,et al.  Inversion method and experiment to determine the soot refractive index: application to turbulent diffusion flames , 2002 .