Application of vacuum membrane distillation for small scale drinking water production

Abstract This study evaluated the applicability of a modified design vacuum enhanced-multi effect membrane distillation (V-MEMD) for drinking water production with feed solution containing NaCl and CaSO 4 . The applicability was studied in terms of flux, scale formation and ease of cleaning. A slight flux decline (18–20%) was observed with loosely deposited crystals in the membrane module during the 920 min of the operation. Larger formation of crystal (volume weighted mean size, D[4,3]) was observed in the final feed brine (D[4,3] brine feed  = 455.96 μm) compared to that inside the module (D[4,3] brine module  = 62.68 μm). The loose crystal deposition was attributed to the absence of hydraulic pressure, low feed temperature, high turbulence (Re = 5665.6) and short membrane retention time (21.6 s). The crystal formation in the membrane module, D[4,3] brine module increased with reduced permeate side vacuum and lower feed velocity. Periodic DI water flushing was found to be efficient to remove the scaling. The feed component mass balance showed that most of the components were able to be removed with 2 L DI water flushing. A 70% recovery ratio was projected for a scaled-up unit, highlighting the suitability of the V-MEMD as a small scale system for drinking water production.

[1]  Runyu Ma,et al.  Analysis of a solar-powered membrane distillation system , 2005 .

[2]  R. Panchagnula,et al.  Solid-State Characterization of Nevirapine , 2008, Indian journal of pharmaceutical sciences.

[3]  F. Banat,et al.  Autonomous Membrane Distillation Pilot Plant Unit Driven Solar Energy: Experiences and Lessons Learned , 2010 .

[4]  Marek Gryta,et al.  Fouling in direct contact membrane distillation process , 2008 .

[5]  N. Hilal,et al.  Membrane distillation: A comprehensive review , 2012 .

[6]  M. Gryta,et al.  Water demineralisation by NF/MD integrated processes , 2005 .

[7]  M. Gryta Scaling diminution by heterogeneous crystallization in a filtration element integrated with membrane distillation module , 2009 .

[8]  Liming Song,et al.  Pilot plant studies of novel membranes and devices for direct contact membrane distillation-based desalination , 2008 .

[9]  Bryce S. Richards,et al.  Photovoltaic-powered desalination system for remote Australian communities , 2003 .

[10]  Mohamed Khayet,et al.  A framework for better understanding membrane distillation separation process , 2006 .

[11]  S. Vigneswaran,et al.  Experiments and modeling of a vacuum membrane distillation for high saline water , 2014 .

[12]  S. T. Hsu,et al.  Seawater desalination by direct contact membrane distillation , 2002 .

[13]  R. Bailie,et al.  Housing and health in Indigenous communities: key issues for housing and health improvement in remote Aboriginal and Torres Strait Islander communities. , 2006, The Australian journal of rural health.

[14]  Tzahi Y. Cath,et al.  A scaling mitigation approach during direct contact membrane distillation , 2011 .

[15]  M. Gryta Alkaline scaling in the membrane distillation process , 2008 .

[16]  G. H. Nancollas,et al.  Calcium sulfate dihydrate crystal growth in aqueous solution at elevated temperatures , 1973 .

[17]  Enrico Drioli,et al.  Membrane distillation operated at high seawater concentration factors: Role of the membrane on CaCO3 scaling in presence of humic acid , 2010 .

[18]  R. Sheikholeslami,et al.  Coprecipitation of CaCO3 and CaSO4 , 2000 .

[19]  Changwei Zhao,et al.  Fluoride removal from brackish groundwater by direct contact membrane distillation. , 2010, Journal of environmental sciences.

[20]  James P. M. Syvitski,et al.  Principles, methods, and application of particle size analysis: Frontmatter , 1991 .

[21]  Corinne Cabassud,et al.  Vacuum membrane distillation of seawater reverse osmosis brines. , 2010, Water research.

[22]  Ho Jung Hwang,et al.  Production of drinking water from saline water by direct contact membrane distillation (DCMD) , 2011 .

[23]  Julián Blanco,et al.  Experimental evaluation of two pilot-scale membrane distillation modules used for solar desalination , 2012 .

[24]  Enrico Drioli,et al.  Theoretical and Experimental Study on Membrane Distillation in the Concentration of Orange Juice , 1994 .

[25]  Antoni W. Morawski,et al.  Membrane processes used for potable water quality improvement , 2002 .

[26]  Anthony G. Fane,et al.  Mass transfer mechanisms and transport resistances in direct contact membrane distillation process , 2006 .

[27]  J. Gubicza,et al.  Crystallite size distribution and dislocation structure determined by diffraction profile analysis: principles and practical application to cubic and hexagonal crystals , 2001 .

[28]  M. Weijnen,et al.  Crystal growth of calcium sulphate dihydrate at low supersaturation , 1982 .

[29]  Bryce S. Richards,et al.  Performance of a small solar-powered hybrid membrane system for remote communities under varying feedwater salinities , 2004 .

[30]  R. V. Hille,et al.  Aspects of gypsum precipitation in scaling waters , 2004 .

[31]  K. Sirkar,et al.  Potential for scaling by sparingly soluble salts in crossflow DCMD , 2008 .

[32]  A. Merdhah,et al.  Laboratory Study and Prediction of Calcium Sulphate at High-Salinity Formation Water , 2008 .

[33]  A. Erdogdu,et al.  The effect of Stirring Rate on Dissolution of Colemanite and Particle Size of Gypsum Crystals during the Boric Acid Production in a Batch Reactor , 2004 .

[34]  Sebastian Büttner,et al.  Experimental study of the memsys vacuum-multi-effect-membrane-distillation (V-MEMD) module , 2013 .

[35]  June-Seok Choi,et al.  Scale formation in reverse osmosis desalination: model development , 2009 .

[36]  Peter Eriksson,et al.  NF membrane characteristics and evaluation for sea water processing applications , 2005 .

[37]  A Pérez-González,et al.  State of the art and review on the treatment technologies of water reverse osmosis concentrates. , 2012, Water research.

[38]  S. Vigneswaran,et al.  Influence of feed/permeate velocity on scaling development in a direct contact membrane distillation , 2014 .

[39]  Benny D. Freeman,et al.  Reverse osmosis desalination: water sources, technology, and today's challenges. , 2009, Water research.