Gold Nanoparticle‐Based Fluorometric and Colorimetric Sensing of Copper(II) Ions

merized to form a random-phase segregated morphology referred to as the floodlit region. Film thickness was controlled by the addition of 10 lm diameter glass rods to the pre-polymer syrup. The diffraction efficiency of the grating was determined through the ratio of the intensity of diffracted light to incident light using a He–Ne (632 nm) laser. SEM images were collected with a Hitachi 900S operating at 1 keV. The PM597 was excited with the doubled output (532 nm) of a Nd:YAG that had a repetition rate of 10 Hz and pulse duration of 5–8 ns. Photoluminescence (PL) was collected perpendicular to the cell with an Ocean Optics CCD/spectrometer that had a resolution of 1.9 nm.

[1]  Eunkeu Oh,et al.  Inhibition assay of biomolecules based on fluorescence resonance energy transfer (FRET) between quantum dots and gold nanoparticles. , 2005, Journal of the American Chemical Society.

[2]  E. Anslyn,et al.  Catalytic signal amplification using a Heck reaction. An example in the fluorescence sensing of CuII. , 2004, Journal of the American Chemical Society.

[3]  Jian Pei,et al.  Exploiting an Imidazole-Functionalized Polyfluorene Derivative as a Chemosensory Material , 2004 .

[4]  Igor Nabiev,et al.  Energy Transfer in Aqueous Solutions of Oppositely Charged CdSe/ZnS Core/Shell Quantum Dots and in Quantum Dot−Nanogold Assemblies , 2004 .

[5]  Igor L. Medintz,et al.  Fluorescence resonance energy transfer between quantum dot donors and dye-labeled protein acceptors. , 2003, Journal of the American Chemical Society.

[6]  Hui-Hui Zeng,et al.  Real-time determination of picomolar free Cu(II) in seawater using a fluorescence-based fiber optic biosensor. , 2003, Analytical chemistry.

[7]  Xiaogang Peng,et al.  Single-phase and gram-scale routes toward nearly monodisperse Au and other noble metal nanocrystals. , 2003, Journal of the American Chemical Society.

[8]  K. G. Thomas,et al.  Chromophore-functionalized gold nanoparticles. , 2003, Accounts of chemical research.

[9]  A. Heeger,et al.  Beyond superquenching: Hyper-efficient energy transfer from conjugated polymers to gold nanoparticles , 2003, Proceedings of the National Academy of Sciences of the United States of America.

[10]  Surat Hotchandani,et al.  Electrochemical modulation of fluorophore emission on a nanostructured gold film. , 2002, Angewandte Chemie.

[11]  S. Nie,et al.  Self-assembled nanoparticle probes for recognition and detection of biomolecules. , 2002, Journal of the American Chemical Society.

[12]  C. R. Mayer,et al.  3D Hybrid Nanonetworks from Gold‐Functionalized Nanoparticles , 2002 .

[13]  G. U. Kulkarni,et al.  Size-dependent chemistry: properties of nanocrystals. , 2002, Chemistry.

[14]  F. Mancin,et al.  Self-Assembling in Surfactant Aggregates: An Alternative Way to the Realization of Fluorescence Chemosensors for Cu(II) Ions , 2001 .

[15]  S. Yamada,et al.  Facile Fabrication of Photoelectrochemical Assemblies Consisting of Gold Nanoparticles and a Tris(2,2‘-bipyridine)ruthenium(II)−Viologen Linked Thiol , 2001 .

[16]  A. Libchaber,et al.  Single-mismatch detection using gold-quenched fluorescent oligonucleotides , 2001, Nature Biotechnology.

[17]  Joseph T. Hupp,et al.  Gold Nanoparticle-Based Sensing of “Spectroscopically Silent” Heavy Metal Ions , 2001 .

[18]  F. Mancin,et al.  Exploiting the Self-Assembly Strategy for the Design of Selective Cu(II) Ion Chemosensors. , 1999, Angewandte Chemie.

[19]  R. Murray,et al.  Gold nanoelectrodes of varied size: transition to molecule-like charging , 1998, Science.

[20]  R. Krämer Fluorescent Chemosensors for Cu2+ Ions: Fast, Selective, and Highly Sensitive. , 1998, Angewandte Chemie.

[21]  E. Braun,et al.  DNA-templated assembly and electrode attachment of a conducting silver wire , 1998, Nature.

[22]  B. Imperiali,et al.  Exploiting Polypeptide Motifs for the Design of Selective Cu(II) Ion Chemosensors , 1998 .

[23]  J. Storhoff,et al.  Selective colorimetric detection of polynucleotides based on the distance-dependent optical properties of gold nanoparticles. , 1997, Science.

[24]  H. Michel,et al.  Use of nanogold- and fluorescent-labeled antibody Fv fragments in immunocytochemistry. , 1996, The journal of histochemistry and cytochemistry : official journal of the Histochemistry Society.

[25]  U. Kreibig,et al.  Optical properties of aggregates of small metal particles , 1986 .

[26]  K. Müllen,et al.  Liquid crystalline coronene derivatives , 2001 .

[27]  I. Willner,et al.  Assembly of a Zn(II)-Porphyrin−Bipyridinium Dyad and Au-Nanoparticle Superstructures on Conductive Surfaces , 1999 .