Limits of Design for Recycling and “Sustainability”: A Review

Metals and materials play a pivotal role in society as their properties impart unique functionality to engineered structures and consumer products. Metals are theoretically infinitely recyclable; however, the functionality and design of consumer product complicate recycling due to their ever more complex structures producing un-liberated low grade and complex recyclates. Metallurgical smelting ingenuity, good technology and intelligent use of thermodynamics and transfer processes gets metallurgists and recyclers a far way down the path of creating high recycling rates from a large range of primary concentrates and recyclates. However, the 2nd Law of Thermodynamics teaches us the practical limits of recycling in terms of entropy creation, which is determined by the complexity of the recyclates and hence to the economics of processing/technology and metal/energy recovery. The usual simple accounting type tools do not rise to the challenge. Therefore, a key issue for the creation of “sustainable systems” and hence the minimization of waste (or in other words achieve high recycling rates) is the creation of optimal industrial ecological systems with optimally linked Best Available Techniques (BAT). This must maximize the recovery of materials from ores and recyclates within the boundaries of consumer behaviour, product design/functionality, thermodynamics, legislation, technology and economics. Examples will show how recyclate quality/grade predicted by recycling models affects entropy creation, while also reviewing various published methodologies. This paper shows that simulation models are a prerequisite to designing “sustainable” systems as these can predict recyclate grade/quality/losses/toxicity of streams, the link to entropy and economics and the realization of company ideals and mission statements in this regard. In other words, to dematerialize society requires detail input by engineers, their predictive tools and economic based design approaches to engineer a sustainable future.

[1]  K. Fichter,et al.  World Business Council for Sustainable Development - WBCSD , 1998 .

[2]  D. Lorenz The application of sustainable development principles to the theory and practice of property valuation , 2009 .

[3]  Qin Lu,et al.  Model-based analysis of capacity and service fees for electronics recyclers , 2006 .

[4]  Helmut Rechberger,et al.  Practical handbook of material flow analysis , 2003 .

[5]  Casper Boks,et al.  Quotes for environmentally weighted recyclability (QWERTY): Concept of describing product recyclability in terms of environmental value , 2003 .

[6]  Markus A. Reuter,et al.  The time-varying factors influencing the recycling rate of products , 2004 .

[7]  K Briffaerts,et al.  Waste battery treatment options: comparing their environmental performance. , 2009, Waste management.

[8]  T. Leczo HIsmelt{reg_sign} technology: the future of ironmaking , 2009 .

[9]  J den Boer,et al.  LCA-IWM: a decision support tool for sustainability assessment of waste management systems. , 2007, Waste management.

[10]  Juan García-Serna,et al.  New trends for design towards sustainability in chemical engineering: Green engineering , 2007 .

[11]  J. Dewulf,et al.  Recycling rechargeable lithium ion batteries: Critical analysis of natural resource savings , 2010 .

[12]  I. Nikolic,et al.  Integration of Life Cycle Assessment Into Agent‐Based Modeling , 2009 .

[13]  R. B. Doorneweert,et al.  Global Reporting Initiative , 2010 .

[14]  Otto Rentz,et al.  Integrated technique assessment based on the pinch analysis approach for the design of production networks , 2006, Eur. J. Oper. Res..

[15]  E. Hertwich Life cycle approaches to sustainable consumption: a critical review. , 2005, Environmental science & technology.

[16]  Nikola Anastasijevic,et al.  Low CO2 emission technologies for iron and steelmaking as well as titania slag production , 2007 .

[17]  Kirsten Sinclair Rosselot,et al.  Implementing the Results of Material Flow Analysis , 2009 .

[18]  Petr Stehlík,et al.  Contribution to advances in waste-to-energy technologies. , 2009 .

[19]  Marie Münster,et al.  Comparing Waste-to-Energy technologies by applying energy system analysis. , 2010, Waste management.

[20]  R. Siddique,et al.  Use of recycled plastic in concrete: a review. , 2008, Waste management.

[21]  Edward Cohen-Rosenthal,et al.  A Walk on the Human Side of Industrial Ecology , 2000 .

[22]  David T. Allen,et al.  Green engineering : environmentally conscious design of chemical processes/ [by] David T. Allen and David R. Shonnard , 2001 .

[23]  Mario Schmidt,et al.  The Sankey Diagram in Energy and Material Flow Management , 2008 .

[24]  Eric Forssberg,et al.  Mechanical recycling of waste electric and electronic equipment: a review. , 2003, Journal of hazardous materials.

[25]  I. Nonaka,et al.  How Japanese Companies Create the Dynamics of Innovation , 1995 .

[26]  Yuichi Moriguchi,et al.  CO2 in the iron and steel industry: an analysis of Japanese emission reduction potentials , 2002 .

[27]  Markus A. Reuter,et al.  Dynamic performance metrics to assess sustainability and cost effectiveness of integrated urban water systems , 2010 .

[28]  Göran Finnveden,et al.  Environmental systems analysis tools – an overview , 2005 .

[29]  N. Fraunholcz,et al.  Separation of waste plastics by froth flotation––a review, part I , 2004 .

[30]  M. Braungart,et al.  Cradle-to-cradle design: creating healthy emissions - a strategy for eco-effective product and system design , 2007 .

[31]  Qi Liu,et al.  Sulfuric acid leaching of ocean manganese nodules using phenols as reducing agents , 2001 .

[32]  Markus A. Reuter,et al.  Material and Metal Ecology , 2008 .

[33]  Martin Porter,et al.  Packaging and Packaging Waste , 2002 .

[34]  Martin Ruhrberg,et al.  Assessing the recycling efficiency of copper from end-of-life products in Western Europe , 2006 .

[35]  Tao Wang,et al.  The energy benefit of stainless steel recycling , 2008 .

[36]  Mark Cross,et al.  Modeling and Simulation of Mineral Processing Systems , 2003 .

[37]  Roland Clift,et al.  Time-dependent material flow analysis of iron and steel in the UK: Part 1: Production and consumption trends 1970-2000 , 2007 .

[38]  Kun-Mo Lee,et al.  Comparison of four methods for integrating environmental and economic aspects in the end-of-life stage of a washing machine , 2006 .

[39]  Ata Akcil,et al.  A review of technologies for the recovery of metals from spent alkaline and zinc-carbon batteries , 2009 .

[40]  S. Bringezu,et al.  Platinum Group Metal Flows of Europe, Part II , 2009 .

[41]  Markus A. Reuter,et al.  Exergy as a tool for evaluation of the resource efficiency of recycling systems , 2007 .

[42]  Markus A. Reuter,et al.  The use of fuzzy rule models to link automotive design to recycling rate calculation , 2007 .

[43]  S. Kjelstrup,et al.  An Indicator to Evaluate the Thermodynamic Maturity of Industrial Process Units in Industrial Ecology , 2008 .

[44]  Elmar Beeh,et al.  Super Light Car—lightweight construction thanks to a multi-material design and function integration , 2009 .

[45]  Petr Stehlík,et al.  Waste to energy – An evaluation of the environmental impact , 2010 .

[46]  Adisa Azapagic,et al.  A mathematical model and decision-support framework for material recovery, recycling and cascaded use , 2002 .

[47]  Mark W. Maier,et al.  Architecting Principles for Systems‐of‐Systems , 1996 .

[48]  Markus A. Reuter,et al.  The metrics of material and metal ecology : Harmonizing the resource, technology and environmental cycles , 2005 .

[49]  Ernst Strüngmann Forum,et al.  Linkages of sustainability , 2009 .

[50]  J. Sundqvist,et al.  ORWARE - a simulation tool for waste management. , 2002 .

[51]  Perrine Chancerel,et al.  Recycling-oriented characterization of small waste electrical and electronic equipment. , 2009, Waste management.

[52]  Joseph Fiksel,et al.  Designing resilient, sustainable systems. , 2003, Environmental science & technology.

[53]  Mark E. Hanson,et al.  Global sustainability: Toward measurement , 1988 .

[54]  Jo Dewulf,et al.  Exergy-Based Efficiency Analysis of Pyrometallurgical Processes , 2010 .

[55]  Lifeng Zhang,et al.  Metallurgical recovery of metals from electronic waste: a review. , 2008, Journal of hazardous materials.

[56]  Robert U. Ayres,et al.  Eco-thermodynamics: economics and the second law , 1998 .

[57]  Manbir S. Sodhi,et al.  Models for recycling electronics end-of-life products , 2001, OR Spectr..

[58]  Markus A. Reuter,et al.  Dynamic modelling of E-waste recycling system performance based on product design , 2010 .

[59]  H. Wenzel,et al.  Paper waste - recycling, incineration or landfilling? A review of existing life cycle assessments. , 2007, Waste management.

[60]  P. Georgiadis,et al.  Sustainability in electrical and electronic equipment closed-loop supply chains: A System Dynamics approach , 2008 .

[61]  The development of a CFD model of a submerged arc furnace for phosphorus production , 2006 .

[62]  Paul T. Anastas,et al.  Frontiers in Green Chemistry: meeting the grand challenges for sustainability in R&D and manufacturing , 2008 .

[63]  Roland Clift,et al.  Time-dependent material flow analysis of iron and steel in the UK: Part 2. Scrap generation and recycling , 2007 .

[64]  Markus A. Reuter,et al.  Analysis of transport phenomena in a rotary-kiln hazardous waste incinerator , 2007 .

[65]  Adisa Azapagic,et al.  Life cycle assessment and multiobjective optimisation , 1999 .

[66]  H. Kooi,et al.  Exergy analysis with a flowsheeting simulator—I. Theory; calculating exergies of material streams , 1996 .

[67]  Diana Liverman,et al.  Global sustainability: Toward definition , 1987 .

[68]  J. Baeyens,et al.  Recycling and recovery routes of plastic solid waste (PSW): a review. , 2009, Waste management.

[69]  J. Kaivo-oja,et al.  Linking analyses and environmental Kuznets curves for aggregated material flows in the EU , 2007 .

[70]  T. Graedel Industrial Ecology , 1995 .

[71]  Chi Ming Tam,et al.  A review on the viable technology for construction waste recycling , 2006 .

[72]  Reynold Sequeira,et al.  Risk analysis and protection measures in a carbon nanofiber manufacturing enterprise: an exploratory investigation. , 2009, The Science of the total environment.

[73]  T. Norgate,et al.  Assessing the environmental impact of metal production processes , 2007 .

[74]  Adisa Azapagic,et al.  Options for broadening and deepening the LCA approaches , 2010 .

[75]  T. Spengler,et al.  Environmental integrated production and recycling management , 1997 .

[76]  Mario Schmidt,et al.  A production-theory-based framework for analysing recycling systems in the e-waste sector , 2005 .

[77]  Markus A. Reuter,et al.  Fundamental limits for the recycling of end-of-life vehicles , 2006 .

[78]  Janet K. Allen,et al.  Applying Ecological Input‐Output Flow Analysis to Material Flows in Industrial Systems: Part II: Flow Metrics , 2004 .

[79]  Fabrice Mathieux,et al.  ReSICLED: a new Recovery Conscious Design method for complex products based on a multicriteria assessment of the recoverability. , 2008 .

[80]  Urmila M. Diwekar,et al.  Green process design, industrial ecology, and sustainability: A systems analysis perspective , 2005 .

[81]  Tobias Müller,et al.  Development of a recycling process for nickel-metal hydride batteries , 2006 .

[82]  Werner Leopold Kepplinger Actual state of smelting-reduction processes in ironmaking , 2009 .

[83]  E. Williams,et al.  Exploring e-waste management systems in the United States , 2008 .

[84]  Stefan Salhofer,et al.  Modelling municipal solid waste generation: a review. , 2008, Waste management.

[85]  André Faaij,et al.  Optimising waste treatment systems - Part A: Methodology and technological data for optimising energy production and economic performance , 2006 .

[86]  Jun Yoshinaga,et al.  Environmental Fate of Gallium Arsenide Semiconductor Disposal , 2003 .

[87]  Markus A. Reuter,et al.  Management of the Web of Water and Web of Materials , 2010 .

[88]  Markus A. Reuter,et al.  Thermodynamic metrics for measuring the “sustainability” of design for recycling , 2008 .

[89]  Braden Allenby,et al.  Earth Systems Engineering: The Role of Industrial Ecology in an Engineered World , 1998 .

[90]  William McDonough,et al.  Cradle to Cradle: Remaking the Way We Make Things , 2002 .

[91]  Robert U. Ayres,et al.  Metals recycling: economic and environmental implications , 1997 .

[92]  Robert Ries,et al.  Characterizing, Propagating, and Analyzing Uncertainty in Life‐Cycle Assessment: A Survey of Quantitative Approaches , 2007 .

[93]  Helmut Rechberger,et al.  A new, entropy based method to support waste and resource management decisions. , 2002, Environmental science & technology.

[94]  Donald Huisingh,et al.  Applications of industrial ecology—an overview of the special issue , 2004 .

[95]  E. Voet,et al.  Dematerialization: Not Just a Matter of Weight , 2004 .

[96]  Anders Nordin,et al.  High temperature corrosion in a 65 MW waste to energy plant , 2007 .

[97]  Peter Bartelmus,et al.  Dematerialization and Capital Maintenance: Two Sides of the Sustainability Coin , 2003 .

[98]  S. Gössling,et al.  Entropy production as a measure for resource use: Method development and application to metallurgical processes , 2004 .

[99]  Yasushi Kondo,et al.  The Waste Input‐Output Approach to Materials Flow Analysis , 2007 .

[100]  P. Anastas,et al.  Green Chemistry , 2018, Environmental Science.

[101]  Markus A. Reuter,et al.  A Fundamental Metric for Metal Recycling Applied to Coated Magnesium , 2008 .

[102]  J. Schnoor,et al.  Sustainability science and engineering: the emergence of a new metadiscipline. , 2003, Environmental science & technology.

[103]  Xavier Gabarrell,et al.  Material flow analysis adapted to an industrial area , 2007 .

[104]  Kenneth J. Martchek,et al.  Material Flow Analysis in the Aluminum Industry , 2009 .

[105]  A M Genaidy,et al.  Evidence-based integrated environmental solutions for secondary lead smelters: pollution prevention and waste minimization technologies and practices. , 2009, The Science of the total environment.

[106]  Lieve Helsen,et al.  Total recycling of CCA treated wood waste by low-temperature pyrolysis , 1998 .

[107]  F. McDougall,et al.  International expert group on life cycle assessment for integrated waste management , 2005 .

[108]  Lennart Y. Ljungberg,et al.  Materials selection and design for development of sustainable products , 2007 .

[109]  Karlson Hargroves,et al.  Factor Five: Transforming the Global Economy through 80% Improvements in Resource Productivity , 2009 .

[110]  Nizar Haoues,et al.  State of the art of plastic sorting and recycling : Feedback to vehicle design , 2007 .

[111]  Matthias Ruth Dynamic Modeling of Industrial Ecosystems , 2009 .

[112]  J. M. Floyd,et al.  Converting an idea into a worldwide business commercializing smelting technology , 2005 .

[113]  Markus A. Reuter,et al.  The influence of particle size reduction and liberation on the recycling rate of end-of-life vehicles , 2004 .

[114]  J. Dewulf,et al.  Integrating industrial ecology principles into a set of environmental sustainability indicators for technology assessment. , 2005 .

[115]  Zhenming Xu,et al.  Recycling of non-metallic fractions from waste printed circuit boards: a review. , 2009, Journal of hazardous materials.

[116]  Markus A. Reuter,et al.  Top submerged lance direct zinc smelting , 2009 .

[117]  Lauren Basson,et al.  A critical systems approach to decision support for process engineering , 2007, Comput. Chem. Eng..

[118]  J. J. Breen,et al.  Design for the environment and Green Chemistry: The heart and soul of industrial ecology , 1997 .

[119]  Oladele Osibanjo,et al.  Overview of electronic waste (e-waste) management practices and legislations, and their poor applications in the developing countries , 2008 .

[120]  Zhihong Li,et al.  Comparison of CO2 emission between COREX and blast furnace iron-making system. , 2009, Journal of environmental sciences.

[121]  Eric Forssberg,et al.  A review of plastics waste recycling and the flotation of plastics , 1999 .

[122]  Denise Crocce Romano Espinosa,et al.  Recycling of batteries: a review of current processes and technologies , 2004 .

[123]  H. Thomas,et al.  A review of processes and technologies for the recycling of lithium-ion secondary batteries , 2008 .

[124]  Yuichi Moriguchi,et al.  Proposal of six indicators of material cycles for describing society's metabolism: from the viewpoint of material flow analysis , 2004 .

[125]  Jim Petrie,et al.  Process synthesis and optimisation tools for environmental design: methodology and structure , 2000 .