Tribological and hydrothermal behaviour of silicon carbide under water lubrication

In this study the tribological and hydrothermal behaviour of silicon carbide was examined. No significant reaction layer was found after tribochemical experiments conducted on sintered silicon carbide (SSiC) and after hydrothermal treatment using a hydrothermal diamond anvil cell (HDAC). Mechanical contact of sliding parts induced superficial amorphisation and chemical analysis showed a slight increase in oxygen content within the topmost part of the surface. Static experiments using single-crystal silicon carbide (SCSiC) and a hydrothermal diamond anvil cell revealed an active oxidation mechanism and silica as the result of solution and precipitation.

[1]  Donald W. Feldman,et al.  Raman Scattering by Silicon and Germanium , 1967 .

[2]  K. Nickel,et al.  Phase transformations in materials studied by micro-Raman spectroscopy of indentations , 1997 .

[3]  I. Chou,et al.  A new diamond anvil cell for hydrothermal studies to 2.5 GPa and from −190 to 1200 °C , 1993 .

[4]  T. Quinn Computational methods applied to oxidational wear , 1996 .

[5]  K. Pöhlmann,et al.  Micro- and macro-tribological properties of SiC ceramics in sliding contact , 2001 .

[6]  Kôji Katô,et al.  Formation of tribochemical layer of ceramics sliding in water and its role for low friction , 2000 .

[7]  I. Chou,et al.  Techniques for determining pressure in the hydrothermal diamond- anvil cell: behavior and identification of ice polymorphs (I, III, V, VI) , 1995 .

[8]  R. Hemley,et al.  Raman spectroscopic study of microcrystalline silica , 1994 .

[9]  T. Quinn Oxidational wear modelling: Part II. The general theory of oxidational wear , 1994 .

[10]  Bell,et al.  Raman spectroscopy of SiO2 glass at high pressure. , 1986, Physical review letters.

[11]  E. Lara‐Curzio,et al.  Corrosion of CVD Silicon Carbide in 500°C Supercritical Water , 2007 .

[12]  Hiroshi Harima,et al.  Raman Investigation of SiC Polytypes , 1997 .

[13]  T. Quinn Oxidational wear modelling: I , 1992 .

[14]  William B. White,et al.  Characterization of diamond films by Raman spectroscopy , 1989 .

[15]  I. Chou,et al.  Hydrothermal studies in a new diamond anvil cell up to 10 GPa and from −190°C to 1200°C , 1993 .

[16]  J. Etchepare,et al.  Vibrational normal modes of SiO2. II. Cristobalite and tridymite , 1978 .