Lightweight Raman spectroscope using time-correlated photon-counting detection

Significance Raman spectroscopy is an important tool in understanding chemical components of various materials. However, the excessive weight and energy consumption of a conventional CCD-based spectrometer forbids its applications in space-based instruments, including unmanned aircraft vehicles (UAVs) and Mars/Moon rovers. In this article, we present a lightweight and energy-efficient hyperspectral Raman measurement system. This technique allows UAVs and space vehicles to carry Raman spectrometers without consuming excessive energy. Raman spectroscopy is an important tool in understanding chemical components of various materials. However, the excessive weight and energy consumption of a conventional CCD-based Raman spectrometer forbids its applications under extreme conditions, including unmanned aircraft vehicles (UAVs) and Mars/Moon rovers. In this article, we present a highly sensitive, shot-noise–limited, and ruggedized Raman signal acquisition using a time-correlated photon-counting system. Compared with conventional Raman spectrometers, over 95% weight, 65% energy consumption, and 70% cost could be removed through this design. This technique allows space- and UAV-based Raman spectrometers to robustly perform hyperspectral Raman acquisitions without excessive energy consumption.

[1]  Reza Salem,et al.  Silicon-chip-based ultrafast optical oscilloscope , 2008, Nature.

[2]  Christer Holmlund,et al.  Novel hyperspectral imager for lightweight UAVs , 2010, Defense + Commercial Sensing.

[3]  M. I. Mead,et al.  A lightweight near-infrared spectrometer for the detection of trace atmospheric species. , 2010, The Review of scientific instruments.

[4]  Emil Wolf,et al.  Principles of Optics: Contents , 1999 .

[5]  Vladislav V. Yakovlev,et al.  Microscopic coherent Raman imaging using low-cost continuous wave lasers , 2013 .

[6]  B. Jalali,et al.  Amplified wavelength–time transformation for real-time spectroscopy , 2008 .

[7]  A. Burkart,et al.  A Novel UAV-Based Ultra-Light Weight Spectrometer for Field Spectroscopy , 2014, IEEE Sensors Journal.

[8]  Norman E. Marcon,et al.  Fluorescence and Raman spectroscopy. , 2003 .

[9]  Reza Salem,et al.  Ultrahigh-Speed Optical Processing Using Space-Time Duality , 2011 .

[10]  高培良 An acousto-optic tunable filter , 2009 .

[11]  Riichiro Saito,et al.  Raman spectroscopy of graphene and carbon nanotubes , 2011 .

[12]  Marlan O Scully,et al.  Single-shot stand-off chemical identification of powders using random Raman lasing , 2014, Proceedings of the National Academy of Sciences.

[13]  Dihan Hasan,et al.  Near‐Field Enhanced Plasmonic‐Magnetic Bifunctional Nanotubes for Single Cell Bioanalysis , 2013 .

[14]  Bahram Jalali,et al.  Coherent time-stretch transformation for real-time capture of wideband signals. , 2013, Optics express.

[15]  Patrick J. Treado,et al.  A Miniaturized, No-Moving-Parts Raman Spectrometer , 1993 .

[16]  Gengfeng Zheng,et al.  Fabrication of silicon nanowire devices for ultrasensitive, label-free, real-time detection of biological and chemical species , 2006, Nature Protocols.

[17]  I. C. Chang,et al.  Noncollinear acousto‐optic filter with large angular aperture , 1974 .

[18]  Brandon Redding,et al.  All-fiber spectrometer based on speckle pattern reconstruction. , 2013, Optics express.

[19]  Clemens F Kaminski,et al.  High bandwidth absorption spectroscopy with a dispersed supercontinuum source. , 2007, Optics express.

[20]  F. Coppinger,et al.  Time-stretched analogue-to-digital conversion , 1998 .

[21]  K. S. Krishnan,et al.  The Optical Analogue of the Compton Effect , 1928, Nature.

[22]  S. G. Harroun,et al.  Portable electrochemical surface-enhanced Raman spectroscopy system for routine spectroelectrochemical analysis. , 2012, Analytical chemistry.

[23]  Tuan Vo-Dinh,et al.  Development of a compact, handheld Raman instrument with no moving parts for use in field analysis , 2000 .

[24]  B. Jalali,et al.  Stereopsis-inspired time-stretched amplified real-time spectrometer (STARS) , 2012, IEEE Photonics Conference 2012.

[25]  Eric O Potma,et al.  Biomolecular imaging with coherent nonlinear vibrational microscopy. , 2013, Annual review of physical chemistry.

[26]  Gordon M. Barrow,et al.  Introduction to molecular spectroscopy. , 1962 .

[27]  N. Marcon,et al.  Fluorescence and Raman spectroscopy. , 2003, Gastrointestinal endoscopy clinics of North America.

[28]  N Gupta,et al.  A compact collinear AOTF Raman spectrometer. , 1997, Talanta.

[29]  Vladislav V. Yakovlev,et al.  Broadband nonlinear optical conversion of a high-energy diode-pumped picosecond laser , 2004 .

[30]  Charles H. Camp,et al.  High-Speed Coherent Raman Fingerprint Imaging of Biological Tissues , 2014, Nature Photonics.