Crystallization of silicon films of submicron thickness by blue-multi-laser-diode annealing

Blue-Multi-Laser-Diode Annealing (BLDA) was performed in the continuous wave (CW) mode on Si films as thick as 0.5 μm and 1 μm deposited by rf sputtering. As a result of controlling the laser power from 4.0 to 4.8 W, a whole Si layer of 0.5 μm in thickness was completely crystallized and consisted of a columnar structure of fine grains beneath a partially melted Si surface owing to the high temperature gradient along the depth in the Si layer. After additional hydrogenation in a furnace ambient, the ratio of the photo/dark current under AM1.5 illumination distinctly improved to 6 times higher than that of as-deposited condition. The BLDA is expected to be applied to thin-film solar cells and/or to thin film transistor (TFT) photo-sensor systems on panels as a new low-temperature poly-silicon (LTPS) fabrication technique.

[1]  A. L. Patterson The Scherrer Formula for X-Ray Particle Size Determination , 1939 .

[2]  L. Saravia,et al.  Calculation of the photoelectric effect in silicon , 1971 .

[3]  James R. Chelikowsky,et al.  ELECTRONIC STRUCTURE OF SILICON , 1974 .

[4]  J. Desoyer,et al.  Comparison between microscopical aspects of a-Si films crystallized by pulsed UV excimer laser and calculated temperature profiles , 1989 .

[5]  J. Stoquert,et al.  Pulsed excimer and Nd:YAG laser crystallization of a-Si:H: The specific role of hydrogen , 1990 .

[6]  Jean Brini,et al.  Effect of excimer laser annealing on the structural and electrical properties of polycrystalline silicon thin-film transistors , 1999 .

[7]  R. Tscharner,et al.  Photovoltaic technology: the case for thin-film solar cells , 1999, Science.

[8]  Robert A. Street,et al.  Flat panel imagers with pixel level amplifiers based on polycrystalline silicon thin-film transistor technology , 2002 .

[9]  R. Ishihara,et al.  Melting and crystallization behavior of low-pressure chemical-vapor-deposition amorphous Si films during excimer-laser annealing , 2004 .

[10]  Mool C. Gupta,et al.  Semiconductor laser crystallization of a-Si:H on conducting tin-oxide-coated glass for solar cell and display applications , 2005 .

[11]  Jun Zhou,et al.  Numerical and experimental analysis on green laser crystallization of amorphous silicon thin films , 2009 .

[12]  S. Xiong,et al.  The influence of Si precursor on poly-Si crystallized by YAG laser , 2010 .

[13]  Takashi Noguchi,et al.  Opto-Thermal Analysis of Blue Multi Laser Diode Annealing (BLDA) , 2010, IEICE Trans. Electron..

[14]  Motoyasu Terao,et al.  Advanced Micro-Polycrystalline Silicon Films Formed by Blue-Multi-Laser-Diode Annealing , 2010 .

[15]  Crystallization Behavior of Sputtered Amorphous Silicon Films by Blue-Multi-Laser-Diode Annealing , 2011 .