Trend detection in satellite observations of formaldehyde tropospheric columns

[1] Being an intermediate product in the oxidation of a large number of non-methane volatile organic compounds (NMVOCs), formaldehyde (H2CO) is a useful indicator of biogenic, pyrogenic and anthropogenic hydrocarbon emissions. We present the first trend study performed on H2CO satellite columns, retrieved from the GOME and SCIAMACHY instruments between 1997 and 2009. A linear model with a seasonal component is used to fit the time series of monthly averaged columns. The error and statistical significance of the inferred trends are estimated. The study focuses on Asia but results are also provided for large cities worldwide. Statistically significant positive trends of formaldehyde columns are observed over northeastern China (4% yr−1) and India (1.6% yr−1), related to strong increases in anthropogenic NMVOC emissions, whereas negative trends of about −3% yr−1 are observed over Tokyo as well as over cities of the northeast U.S. urban corridor as a result of effective pollution regulation measures.

[1]  H. Akimoto,et al.  An Asian emission inventory of anthropogenic emission sources for the period 1980-2020 , 2007 .

[2]  E. Mahieu,et al.  Trend analysis of greenhouse gases over Europe measured by a network of ground-based remote FTIR instruments , 2008 .

[3]  Shaodong Xie,et al.  Tempo-spatial variation of emission inventories of speciated volatile organic compounds from on-road vehicles in China , 2009 .

[4]  Christine Wiedinmyer,et al.  Quantifying the Seasonal and Interannual Variability of North American Isoprene Emissions using Satellite Observations of Formaldehyde Column , 2005 .

[5]  Pieter Valks,et al.  H2CO columns retrieved from GOME-2: first scientific results and progress towards the development of an operational product , 2009 .

[6]  Trissevgeni Stavrakou,et al.  Global emissions of non-methane hydrocarbons deduced from SCIAMACHY formaldehyde columns through 2003-2006 , 2009 .

[7]  Dominik Brunner,et al.  An improved tropospheric NO 2 retrieval for satellite observations in the vicinity of mountainous terrain , 2009 .

[8]  K. Boersma,et al.  Trends, seasonal variability and dominant NOx source derived from a ten year record of NO2 measured from space , 2008 .

[9]  Shaodong Xie,et al.  Spatial and temporal variation of historical anthropogenic NMVOCs emission inventories in China , 2008 .

[10]  Sander Houweling,et al.  The impact of nonmethane hydrocarbon compounds on tropospheric photochemistry , 1998 .

[11]  J. Burrows,et al.  Systematic analysis of interannual and seasonal variations of model-simulated tropospheric NO 2 in Asia and comparison with GOME-satellite data , 2006 .

[12]  M. V. Roozendael,et al.  FRESCO+: an improved O 2 A-band cloud retrieval algorithm for tropospheric trace gas retrievals , 2008 .

[13]  Henk Eskes,et al.  Twelve years of global observations of formaldehyde in the troposphere using GOME and SCIAMACHY sensors , 2008 .

[14]  Erik Swietlicki,et al.  Organic aerosol and global climate modelling: a review , 2004 .

[15]  A. J. Miller,et al.  Factors affecting the detection of trends: Statistical considerations and applications to environmental data , 1998 .

[16]  J. Burrows,et al.  Increase in tropospheric nitrogen dioxide over China observed from space , 2005, Nature.

[17]  Henk Eskes,et al.  Detection of the trend and seasonal variation in tropospheric NO2 over China , 2006 .

[18]  R. Spurr LIDORT and VLIDORT: Linearized pseudo-spherical scalar and vector discrete ordinate radiative transfer models for use in remote sensing retrieval problems , 2008 .

[19]  Geert K. Moortgat,et al.  Temperature dependence of the absorption cross sections of formaldehyde between 223 and 323 K in the wavelength range 225–375 nm , 2000 .

[20]  Barbara Barletta,et al.  Space‐based formaldehyde measurements as constraints on volatile organic compound emissions in east and south Asia and implications for ozone , 2007 .

[21]  D. Streets,et al.  Satellite observations of recent power plant construction in Inner Mongolia, China , 2009 .

[22]  Thomas P. Kurosu,et al.  Mapping isoprene emissions over North America using formaldehyde column observations from space , 2003 .

[23]  I. D. Smedt,et al.  Evaluating the performance of pyrogenic and biogenic emission inventories against one decade of space-based formaldehyde columns , 2008 .

[24]  P. Palmer,et al.  Regulated large‐scale annual shutdown of Amazonian isoprene emissions? , 2009 .