Treatment and recovery of contaminated railway ballast

Experimental tests of metal extraction from stones sampled from articially contaminated railway ballasts are presented and discussed. Metal extraction was performed by washing with aqueous solutions of disodium ethylenedi- aminetetraacetate (EDTA), at selected concentrations. The eectiveness of the remediation process was evaluated using leaching tests. The results indicate that the washing technology represents a successful and aordable solution for the imple- mentation of an on-site treatment aimed at a reuse process. Adopting a 0.05 M EDTA solution, extraction yields in the range between 40% and 70% were achieved, depending on contact time and pH of the washing solution.

[1]  E. Arnold,et al.  Standard methods for the examination of water and wastewater. 16th ed. , 1985 .

[2]  A. Billi,et al.  Linking rock fabric to fibrous mineralisation: a basic tool for the asbestos hazard , 2011 .

[3]  Catherine N. Mulligan,et al.  Remediation technologies for metal-contaminated soils and groundwater: an evaluation , 2001 .

[4]  M. Radziemska,et al.  HEAVY METAL CONCENTRATIONS IN SOIL AND MOSS (Pleurozium schreberi) NEAR RAILROAD LINES IN OLSZTYN (POLAND) , 2013 .

[5]  F. Tateo,et al.  Sheet silicates as effective carriers of heavy metals in the ophiolitic mine area of Vigonzano (northern Italy) , 2001, Mineralogical Magazine.

[6]  D. Lestan,et al.  Recycling of EDTA solution after soil washing of Pb, Zn, Cd and As contaminated soil. , 2012, Chemosphere.

[7]  A. Bermond,et al.  Major and trace metal extraction from soil by EDTA: Equilibrium and kinetic studies , 2006 .

[8]  C. Oviedo,et al.  EDTA: the chelating agent under environmental scrutiny , 2003 .

[9]  Y. Ai,et al.  Heavy metal contamination in soil alongside mountain railway in Sichuan, China , 2009, Environmental monitoring and assessment.

[10]  L. Di Palma,et al.  Electrokinetic remediation of gasoil contaminated soil enhanced by rhamnolipid , 2010 .

[11]  L. Palma Influence of indigenous and added iron on copper extraction from soil. , 2009 .

[12]  L. Di Palma,et al.  Recovery of EDTA and metal precipitation from soil flushing solutions. , 2003, Journal of hazardous materials.

[13]  D. A. Barry,et al.  Efficiency and potential environmental impacts of different cleaning agents used on contaminated railway ballast , 2002 .

[14]  L. Di Palma,et al.  Use of different chelating agents for heavy metal extraction from contaminated harbour sediment , 2011 .

[15]  A. E. Greenberg,et al.  Standard Methods for the Examination of Water and Wastewater seventh edition , 2013 .

[16]  S. McGrath,et al.  Leaching of heavy metals from contaminated soils using EDTA. , 2001, Environmental pollution.

[17]  L. Di Palma,et al.  Heavy metals mobilization from harbour sediments using EDTA and citric acid as chelating agents. , 2007, Journal of hazardous materials.

[18]  C. Martínez,et al.  Solubility of lead, zinc and copper added to mineral soils. , 2000, Environmental pollution.

[19]  L. Di Palma,et al.  Influence of Soil Organic Matter on Copper Extraction from Contaminated Soil , 2007 .

[20]  L. Palma,et al.  Experimental Assessment of Chromium Mobilization from Polluted Soil by Washing , 2012 .

[21]  M. Malawska,et al.  Railway transportation as a serious source of organic and inorganic pollution , 2010, Water, air, and soil pollution.