Phosphorus Removal and Iron Recovery from High-Phosphorus Hematite Using Direct Reduction Followed by Melting Separation

ABSTRACT To efficiently utilize high-phosphorus oolitic hematite resources, a method using direct reduction followed by melting separation was proposed. In this study, direct reduction behavior of the ore–char briquette and the melting separation behavior of the reduced briquette were investigated. Direct reduction test results show that under investigated conditions, the briquette reached a metallization rate of 80%–88% and a residual carbon value of 0.11–4.85 wt%,and apatite layers were fragmented into tiny particles, some of which were embedded in metallic iron phase. Melting separation test results show that residual carbon can significantly influence the iron recovery rate. For metallic briquettes with the abovementioned qualities, the iron recovery rate ranged from 75% to 98%. To control the phosphorus content in molten iron to be nearly 0.4 wt%, an iron recovery rate of 80% was shown to be adequate.

[1]  S. Kawatra,et al.  Cold Bonding of Iron Ore Concentrate Pellets , 2015 .

[2]  M. Zhang,et al.  Feasible bioprocessing technologies for low-grade iron ores , 2015 .

[3]  Yong-sheng Sun,et al.  Size Distribution Behavior of Metallic Iron Particles in Coal-Based Reduction Products of an Oolitic Iron Ore , 2015 .

[4]  Huiqing Tang,et al.  Phosphorus Removal of Oolitic High Phosphorus Iron Ore Using Biomass Char , 2015 .

[5]  T. Fabritius,et al.  Thermally assisted liberation of high phosphorus oolitic iron ore: A comparison between microwave and conventional furnaces , 2015 .

[6]  T. Fabritius,et al.  Effect of microwave pre-treatment on the magnetic properties of iron ore and its implications on magnetic separation , 2014 .

[7]  Huiqing Tang,et al.  Slag/metal Separation Process of Gas-Reduced Oolitic High-Phosphorus Iron ore Fines , 2014 .

[8]  Huiqing Tang,et al.  Effect of Microwave Treatment Upon Processing Oolitic High Phosphorus Iron Ore for Phosphorus Removal , 2014, Metallurgical and Materials Transactions B.

[9]  S. Kawatra,et al.  Review of organic binders for iron ore concentrate agglomeration , 2014 .

[10]  S. Liu,et al.  Beneficiation of a low-grade, hematite-magnetite ore in China , 2014 .

[11]  J. Kou,et al.  Study on Phosphorus Removal of High-Phosphorus Oolitic Hematite by Coal-Based Direct Reduction and Magnetic Separation , 2014 .

[12]  Huiqing Tang,et al.  Dephosphorization Treatment of High Phosphorus Oolitic Iron Ore by Hydrometallurgical Process and Leaching Kinetics , 2013 .

[13]  Zhen He,et al.  Upgrading and dephosphorization of Western Australian iron ore using reduction roasting by adding sodium carbonate , 2013, International Journal of Minerals, Metallurgy, and Materials.

[14]  D. Bastin,et al.  Amenability for processing of oolitic iron ore concentrate for phosphorus removal , 2013 .

[15]  Yong-sheng Sun,et al.  Recovery of iron from high phosphorus oolitic iron ore using coal-based reduction followed by magnetic separation , 2013, International Journal of Minerals, Metallurgy, and Materials.

[16]  J. Diao,et al.  Coupled reaction kinetics of duplex steelmaking process for high phosphorus hot metal , 2013 .

[17]  J. Kou,et al.  The Function of Ca(OH)2 and Na2CO3 as Additive on the Reduction of High-Phosphorus Oolitic Hematite-coal Mixed Pellets , 2013 .

[18]  Shaoxian Song,et al.  Morphological and mineralogical characterizations of oolitic iron ore in the Exi region, China , 2013, International Journal of Minerals, Metallurgy, and Materials.

[19]  G. Valadão,et al.  Floatability studies of wavellite and preliminary results on phosphorus removal from a Brazilian iron ore by froth flotation , 2012 .

[20]  J. Kou,et al.  Mechanism of phosphorus removal in beneficiation of high phosphorous oolitic hematite by direct reduction roasting with dephosphorization agent , 2012 .

[21]  Wenbin Zhang,et al.  Beneficiation of High Phosphorus Limonite Ore by Sodium-carbonate-added Carbothermic Reduction , 2012 .

[22]  B. Xie,et al.  Dephosphorization of Iron Ore Bearing High Phosphorous by Carbothermic Reduction Assisted with Microwave and Magnetic Separation , 2012 .

[23]  G. Sparrow,et al.  Phosphorus Removal from Goethitic Iron Ore with a Low Temperature Heat Treatment and a Caustic Leach , 2012 .

[24]  Xue‐min Yang,et al.  A Thermodynamic Model of Phosphate Capacity for CaO-SiO2-MgO-FeO-Fe2O3-MnO-Al2O3-P2O5 Slags Equilibrated with Molten Steel during a Top–Bottom Combined Blown Converter Steelmaking Process Based on the Ion and Molecule Coexistence Theory , 2011 .

[25]  Wu Jie,et al.  Development of Technologies for High Phosphorus Oolitic Hematite Utilization , 2011 .

[26]  Yongliang Zhang,et al.  A Thermodynamic Model of Phosphorus Distribution Ratio between CaO-SiO2-MgO-FeO-Fe2O3-MnO-Al2O3-P2O5 Slags and Molten Steel during a Top–Bottom Combined Blown Converter Steelmaking Process Based on the Ion and Molecule Coexistence Theory , 2011 .

[27]  E. Matinde,et al.  Dephosphorization Treatment of High Phosphorus Iron Ore by Pre-reduction, Air Jet Milling and Screening Methods , 2011 .

[28]  Wang Yu-gang Experimental Study on Gas-based Reduction of Ultra-fine Oolitic High-phosphorus Hematite Powder , 2011 .

[29]  G. E. Metius,et al.  Recycling ferrous and nonferrous waste streams with FASTMET , 2003 .

[30]  R. J. Fruehan,et al.  Emerging technologies for iron and steelmaking , 2001 .

[31]  V. N. Misra,et al.  Dephosphorisation of western australian iron ore by hydrometallurgical process , 1999 .