Thermally induced wrinkling in thin-film stacks on patterned substrates

Thermally induced film wrinkling is a fabrication and reliability challenge for thin-film stacks consisting of a compliant film capped by a stiffer film. The current understanding of film wrinkling is largely restricted to thin-film stacks on blanket substrates. An understanding of wrinkling in thin-film stacks on patterned substrates is of greater practical relevance to the microelectronic industry. Toward this goal, a numerical technique based on a spectral method is employed to simulate wrinkling in a stiff-film/ compliant-film system on a rigid patterned substrate. A coupling term in the Fourier space is introduced to capture the interaction between wrinkling amplitudes above patterned regions and surrounding regions. This coupling in wrinkling amplitudes suppresses wrinkling above patterned regions. Wrinkling amplitudes for a thin-film stack on a patterned substrate are shown to be dependent on the size of the patterns and their relative spacing.

[1]  Wei Hong,et al.  Evolution of wrinkles in hard films on soft substrates. , 2004, Physical review. E, Statistical, nonlinear, and soft matter physics.

[2]  George M. Whitesides,et al.  Spontaneous formation of ordered structures in thin films of metals supported on an elastomeric polymer , 1998, Nature.

[3]  Scott Halle,et al.  Highly etch-selective spin-on bottom antireflective coating for use in 193-nm lithography and beyond , 2003, SPIE Advanced Lithography.

[4]  J. Gill,et al.  Comprehensive reliability evaluation of a 90 nm CMOS technology with Cu/PECVD low-k BEOL , 2004, 2004 IEEE International Reliability Physics Symposium. Proceedings.

[5]  J. Hutchinson,et al.  Herringbone Buckling Patterns of Compressed Thin Films on Compliant Substrates , 2004 .

[6]  T. A. Zang,et al.  Spectral Methods: Fundamentals in Single Domains , 2010 .

[7]  L. Mahadevan,et al.  Geometry and physics of wrinkling. , 2003, Physical review letters.

[8]  Z. Suo,et al.  Nonlinear analyses of wrinkles in a film bonded to a compliant substrate , 2005 .

[9]  T. Kármán The engineer grapples with nonlinear problems , 1940 .

[10]  David G. Cahill,et al.  Stress-induced wrinkling of sputtered SiO2 films on polymethylmethacrylate , 2006 .

[11]  George M. Whitesides,et al.  Ordering of Spontaneously Formed Buckles on Planar Surfaces , 2000 .

[12]  Jan Genzer,et al.  Soft matter with hard skin: From skin wrinkles to templating and material characterization. , 2006, Soft matter.

[13]  Karen Petrillo,et al.  Silicon containing polymer in applications for 193 nm high NA lithography processes , 2006, SPIE Advanced Lithography.

[14]  Ilsoon Lee,et al.  Wrinkle-free nanomechanical film: control and prevention of polymer film buckling. , 2007, Nano letters.

[15]  S. Timoshenko,et al.  Theory of elasticity , 1975 .

[16]  Hyewon Kang,et al.  Polymer elasticity-driven wrinkling and coarsening in high temperature buckling of metal-capped polymer thin films. , 2004, Physical review letters.

[17]  H. G. Allen Analysis and design of structural sandwich panels , 1969 .

[18]  Masashi Watanabe Wrinkles formed on a thin gold film deposited onto stretched elastic substrates , 2005 .

[19]  Sang Hoon Lee,et al.  Wrinkled hard skins on polymers created by focused ion beam , 2007, Proceedings of the National Academy of Sciences.

[20]  M D Thouless,et al.  Surface instability of an elastic half space with material properties varying with depth. , 2008, Journal of the mechanics and physics of solids.

[21]  J. Rogers,et al.  Finite deformation mechanics in buckled thin films on compliant supports , 2007, Proceedings of the National Academy of Sciences.

[22]  Daniel C. Edelstein,et al.  A high performance 0.13 /spl mu/m copper BEOL technology with low-k dielectric , 2000, Proceedings of the IEEE 2000 International Interconnect Technology Conference (Cat. No.00EX407).

[23]  Karen Maex,et al.  Compressive stress relaxation through buckling of a low-k polymer-thin cap layer system , 2003 .

[24]  Rui Huang,et al.  Dynamics of wrinkle growth and coarsening in stressed thin films. , 2006, Physical review. E, Statistical, nonlinear, and soft matter physics.

[25]  Bryan D. Vogt,et al.  Elastic Moduli of Ultrathin Amorphous Polymer Films , 2006 .

[26]  Yonggang Huang,et al.  Stretchable and Foldable Silicon Integrated Circuits , 2008, Science.

[27]  Willi Volksen,et al.  A buckling-based metrology for measuring the elastic moduli of polymeric thin films , 2004, Nature materials.

[28]  Miss A.O. Penney (b) , 1974, The New Yale Book of Quotations.

[29]  Todd Emrick,et al.  Capillary Wrinkling of Floating Thin Polymer Films , 2007, Science.