Analysis and imitation of organic Sanhetu concrete discovered in an ancient Chinese tomb of Qing Dynasty

Abstract The Organic Sanhetu Concrete (OSC) has a prominent position in the Chinese ancient construction, and especially the natural organic materials (sticky rice and egg white) have made some historical buildings legends. Compared with Portland cement, the OSC has exhibit excellent durability, impermeability and mechanical characteristics. The absorption of CO2 makes them as an environmental friendly building material during Qing Dynasty. However, it was almost lost after the emergence of Portland cement as a building material. Though, OSC have existed for thousands of years, we can't get accurate formula and process even after 200 years. Further, even the compressive strength of the imitation is not satisfactory. This paper is primarily focused on the archaeology discoveries in 2007, for that the samples were collected from the sealing earth of a Qing dynasty burial mound in Huaining, Anhui, China and analyzed to investigate its physical, chemical and mechanical characteristics. Based on the results, an imitation of OSC with organic additives was designed, combining with the formula in literature. The results of these experiments have shown that the compressive strength of the lime-based materials met that of concrete with strength grade of C20 (21 MPa) after weathering and cutting. In addition, the imitation is above 50 MPa, which was comparable to that of concrete that have strength grade of C50. Thus, it was concluded from this investigation that the substitution of the artificial organic additives to natural materials can open doors for novel research prospective in designing of building materials.

[1]  S. Thirumalini,et al.  Experimental investigation on physical and mechanical properties of lime mortar: Effect of organic addition , 2017 .

[3]  R. Veiga,et al.  Characterization of Ancient Pozzolanic Mortars from Roman Times to the 19th Century: Compatibility Issues of New Mortars with Substrates and Ancient Mortars , 2010 .

[4]  Xiaolin Liang,et al.  A case study and mechanism investigation of typical mortars used on ancient architecture in China , 2008 .

[5]  I. Gerlach,et al.  Qadhat—a comparative study of ancient and new lime mortar from the Marib province/Yemen , 2009 .

[6]  Antonia Moropoulou,et al.  Characterization of ancient, byzantine and later historic mortars by thermal and X-ray diffraction techniques☆ , 1995 .

[7]  P. Gleize,et al.  Characterization of historical mortars from Santa Catarina (Brazil) , 2009 .

[8]  Marius Vendrell,et al.  Traditional organic additives improve lime mortars: New old materials for restoration and building natural stone fabrics , 2011 .

[9]  J. Phair Green chemistry for sustainable cement production and use , 2006 .

[10]  Caterina Gattuso,et al.  Characterisation of archaeological mortars from Pompeii (Campania, Italy) and identification of construction phases by compositional data analysis , 2010 .

[11]  Antonio La Marca,et al.  Characterisation of archaeological mortars and plasters from kyme (Turkey) , 2011 .

[12]  P. Monteiro,et al.  Material characteristics of ancient Chinese lime binder and experimental reproductions with organic admixtures , 2015 .

[13]  Bingjian Zhang,et al.  Study of sticky rice-lime mortar technology for the restoration of historical masonry construction. , 2010, Accounts of chemical research.

[14]  R. Csencsits,et al.  Use of Organo- and Alkoxysilanes in the Synthesis of Grafted and Pristine Clays , 2001 .

[15]  V. Farmer,et al.  The Characterization of Soil Minerals by Infrared Spectroscopy , 1975 .

[16]  M. Regert,et al.  Alteration of Asian lacquer: in-depth insight using a physico-chemical multiscale approach. , 2013, The Analyst.

[17]  Paulo Roberto Gomes Brandão,et al.  Adsorption of starch, amylose, amylopectin and glucose monomer and their effect on the flotation of hematite and quartz. , 2003 .

[18]  Shaoxian Song,et al.  Influence of sticky rice and anionic polyacrylamide on the crystallization of calcium carbonate in Chinese organic sanhetu , 2015 .

[19]  Yi-lun Song Tian Gong Kai Wu , 2008 .

[20]  Eleni Aggelakopoulou,et al.  Strength development and lime reaction in mortars for repairing historic masonries , 2005 .

[21]  K. Rashid,et al.  Influence of organic agents to compressive strength of cement mortar , 2018, Construction and Building Materials.

[22]  J. Lanas,et al.  MECHANICAL PROPERTIES OF NATURAL HYDRAULIC LIME-BASED MORTARS , 2004 .

[23]  F. A. Miller,et al.  Infrared Spectra and Characteristic Frequencies of Inorganic Ions , 1952 .

[24]  Bingjian Zhang,et al.  Traditional mortar represented by sticky rice lime mortar—One of the great inventions in ancient China , 2009 .