Promising Bioalcohols for Low-Emission Vehicles

In recent decades, many kinds of research have been conducted on alternative fuels for compression ignition (CI) engines. Low/zero-carbon fuels, such as bioalcohols and hydrogen, are the most promising alternative fuels and are extensively studied because of their availability, ease of manufacturing, and environmental benefits. Using these promising fuels in CI engines is environmentally and economically beneficial. The most common alcohols are methanol, ethanol, isopropanol, propanol, butanol, n-butanol, tert-butanol, iso-butanol, and pentanol. The primary objective of this review paper is to examine the impact of bioalcohols and their blends with conventional diesel fuel in CI engines since these fuels possess characteristic properties that impact overall engine performance and exhaust emissions. This research also indicated that alcohols and blended fuels could be used as fuels in compression ignition engines. Chemical and physical properties of alcohols were examined, such as lubricity, viscosity, calorific value, and cetane number, and their combustion characteristics in compression ignition engines provide a comprehensive review of their potential biofuels as alternative fuels.

[1]  M. P. Dorado,et al.  Influence of 1-butanol and 1-pentanol addition to diesel fuel on exhaust and noise emissions under stationary and transient conditions , 2021 .

[2]  Nathália Duarte Souza Alvarenga Santos,et al.  Internal combustion engines and biofuels: Examining why this robust combination should not be ignored for future sustainable transportation , 2021 .

[3]  M. Lapuerta,et al.  Progress in the Use of Biobutanol Blends in Diesel Engines , 2021, Energies.

[4]  Xiaochen Wang,et al.  Oxidation behaviors and nanostructure of particulate matter produced from a diesel engine fueled with n-pentanol and 2-ethylhexyl nitrate additives , 2021 .

[5]  Y. Zhuang,et al.  Morphology analysis of soot particles from a modern diesel engine fueled with different types of oxygenated fuels , 2020 .

[6]  S. No Utilization of Pentanol as Biofuels in Compression Ignition Engines , 2020, Frontiers in Mechanical Engineering.

[7]  C. Lee,et al.  Effects of alcohol addition to traditional fuels on soot formation: A review , 2020 .

[8]  J. Jeevahan,et al.  Effect of the addition of 1-pentanol on engine performance and emission characteristics of diesel and biodiesel fuelled single cylinder diesel engine , 2020 .

[9]  Yang Wang,et al.  Combustion and emission characteristics of n-butanol-gasoline blends in SI direct injection gasoline engine , 2020 .

[10]  Ying Wang,et al.  An overview of physical and chemical features of diesel exhaust particles , 2019 .

[11]  R. S. Bharj,et al.  Study of physical-chemical properties for 2nd generation ethanol-blended diesel fuel in India , 2019, Sustainable Chemistry and Pharmacy.

[12]  Abhijeet Killol,et al.  Experimental studies of a diesel engine run on biodiesel n-butanol blends , 2019, Renewable Energy.

[13]  C. Hergueta,et al.  Impact of bio-alcohol fuels combustion on particulate matter morphology from efficient gasoline direct injection engines , 2018, Applied Energy.

[14]  A. Tsolakis,et al.  Interactions between aftertreatment systems architecture and combustion of oxygenated fuels for improved low temperature catalysts activity , 2018, Fuel.

[15]  M. Lapuerta,et al.  Cold flow and filterability properties of n-butanol and ethanol blends with diesel and biodiesel fuels , 2018, Fuel.

[16]  Omar I. Awad,et al.  Alcohol and ether as alternative fuels in spark ignition engine: A review , 2018 .

[17]  M VinodBabu,et al.  Butanol and pentanol: The promising biofuels for CI engines – A review , 2017 .

[18]  Gholamhassan Najafi,et al.  Alcohol based automotive fuels from first four alcohol family in compression and spark ignition engine: A review on engine performance and exhaust emissions , 2017 .

[19]  M. A. Fayad,et al.  Manipulating modern diesel engine particulate emission characteristics through butanol fuel blending and fuel injection strategies for efficient diesel oxidation catalysts , 2017 .

[20]  Xun Zhang,et al.  Switchgrass-Based Bioethanol Productivity and Potential Environmental Impact from Marginal Lands in China , 2017 .

[21]  Júlia Pladevall Viladecans,et al.  Value Chain Structures that Define European Cellulosic Ethanol Production , 2017 .

[22]  Saman Seneweera,et al.  Investigation of Ethanol Production Potential from Lignocellulosic Material without Enzymatic Hydrolysis Using the Ultrasound Technique , 2017 .

[23]  R. Harrison,et al.  Environmental Impacts of Road Vehicles: Past, Present and Future , 2017 .

[24]  J. J. Hernández,et al.  Autoignition of blends of n-butanol and ethanol with diesel or biodiesel fuels in a constant-volume combustion chamber , 2017 .

[25]  A. Marzocchella,et al.  Pre-treatment and enzymatic hydrolysis of lettuce residues as feedstock for bio-butanol production , 2017 .

[26]  Soo-Young No,et al.  Application of biobutanol in advanced CI engines – A review , 2016 .

[27]  A. Tsolakis,et al.  Enhancing the properties of Fischer-Tropsch fuel produced from syngas over Co/SiO2 catalyst: Lubricity and Calorific Value , 2016 .

[28]  Haiqiao Wei,et al.  Experimental investigation on the knocking combustion characteristics of n-butanol gasoline blends in a DISI engine , 2016 .

[29]  S. Saravanan,et al.  Use of higher alcohol biofuels in diesel engines: A review , 2016 .

[30]  V. Krishnamoorthy,et al.  A comparative evaluation and optimization of performance and emission characteristics of a DI diesel engine fueled with n-propanol/diesel, n-butanol/diesel and n-pentanol/diesel blends using response surface methodology , 2016 .

[31]  Mohammad J. Taherzadeh,et al.  Techno-Economic Analysis of Integrating First and Second-Generation Ethanol Production Using Filamentous Fungi: An Industrial Case Study , 2016 .

[32]  Meisam Ahmadi Ghadikolaei Effect of alcohol blend and fumigation on regulated and unregulated emissions of IC engines - a review , 2016 .

[33]  S. Saravanan,et al.  Effects of iso-butanol/diesel and n-pentanol/diesel blends on performance and emissions of a DI diesel engine under premixed LTC (low temperature combustion) mode , 2016 .

[34]  Haji Hassan Masjuki,et al.  Higher alcohol–biodiesel–diesel blends: An approach for improving the performance, emission, and combustion of a light-duty diesel engine , 2016 .

[35]  Obed M. Ali,et al.  Analysis of blended fuel properties and engine performance with palm biodiesel–diesel blended fuel , 2016 .

[36]  S. Saravanan,et al.  Effect of exhaust gas recirculation (EGR) on performance and emissions of a constant speed DI diesel engine fueled with pentanol/diesel blends , 2015 .

[37]  Li Li,et al.  Combustion and emission characteristics of diesel engine fueled with diesel/biodiesel/pentanol fuel blends , 2015 .

[38]  A. Tsolakis,et al.  Role of Alternative Fuels on Particulate Matter (PM) Characteristics and Influence of the Diesel Oxidation Catalyst. , 2015, Environmental science & technology.

[39]  A. Pisello,et al.  Sustainable Ethanol Production from Common Reed ( Phragmites australis ) through Simultaneuos Saccharification and Fermentation , 2015 .

[40]  Byungchul Choi,et al.  Individual hydrocarbons and particulate matter emission from a turbocharged CRDI diesel engine fueled with n-butanol/diesel blends , 2015 .

[41]  Haji Hassan Masjuki,et al.  Performance and emission assessment of diesel–biodiesel–ethanol/bioethanol blend as a fuel in diesel engines: A review , 2015 .

[42]  A. Tsolakis,et al.  Extending the environmental benefits of ethanol–diesel blends through DGE incorporation , 2015 .

[43]  N. Ladommatos,et al.  Molecular Structure of Photosynthetic Microbial Biofuels for Improved Engine Combustion and Emissions Characteristics , 2015, Front. Bioeng. Biotechnol..

[44]  N. Ladommatos,et al.  The influence of straight vegetable oil fatty acid composition on compression ignition combustion and emissions , 2015 .

[45]  Karthik Nithyanandan,et al.  Impacts of acetone on the spray combustion of Acetone–Butanol–Ethanol (ABE)-Diesel blends under low ambient temperature , 2015 .

[46]  Rajasekhar Balasubramanian,et al.  Effects of oxygenated fuel blends on carbonaceous particulate composition and particle size distributions from a stationary diesel engine , 2015 .

[47]  Chun-de Yao,et al.  Investigation of operating range in a methanol fumigated diesel engine , 2015 .

[48]  Yukihiro Tashiro,et al.  Recent advances to improve fermentative butanol production: genetic engineering and fermentation technology. , 2015, Journal of bioscience and bioengineering.

[49]  A. Marzocchella,et al.  Cellulosic butanol production from alkali-pretreated switchgrass (Panicum virgatum) and phragmites (Phragmites australis). , 2014, Bioresource technology.

[50]  S. M. Sarathy,et al.  Alcohol combustion chemistry , 2014 .

[51]  Brian Vad Mathiesen,et al.  A comparison between renewable transport fuels that can supplement or replace biofuels in a 100% renewable energy system , 2014 .

[52]  Mads Greaker,et al.  Promoting Second Generation Biofuels: Does the First Generation Pave the Road? , 2014 .

[53]  Liangjie Wei,et al.  Effect of n-pentanol addition on the combustion, performance and emission characteristics of a direct-injection diesel engine , 2014 .

[54]  Siti Kartom Kamarudin,et al.  An overview on the production of bio-methanol as potential renewable energy , 2014 .

[55]  Peng Geng,et al.  Reduction of PM emissions from a heavy-duty diesel engine with diesel/methanol dual fuel , 2014 .

[56]  I. M. Rizwanul Fattah,et al.  Production and comparison of fuel properties, engine performance, and emission characteristics of biodiesel from various non-edible vegetable oils: A review , 2014 .

[57]  Simsoo Park,et al.  Review on characterization of nano-particle emissions and PM morphology from internal combustion engines: Part 2 , 2014 .

[58]  Rajasekhar Balasubramanian,et al.  Influence of butanol–diesel blends on particulate emissions of a non-road diesel engine , 2014 .

[59]  Salim Newaz Kazi,et al.  A comprehensive literature review of bio-fuel performance in internal combustion engine and relevant costs involvement , 2014 .

[60]  Zhengqing Chen,et al.  Combustion and emissions characteristics of high n-butanol/diesel ratio blend in a heavy-duty diesel engine and EGR impact , 2014 .

[61]  E. Sukjit,et al.  Effect of ambient humidity and hygroscopy on the lubricity of diesel fuels , 2014 .

[62]  Mohd Nashrul Mohd Zubir,et al.  A comprehensive review of bio-diesel as alternative fuel for compression ignition engines , 2013 .

[63]  L. M. Das,et al.  Experimental studies on a DI diesel engine fueled with bioethanol-diesel emulsions , 2013 .

[64]  B. DeAngelo,et al.  Bounding the role of black carbon in the climate system: A scientific assessment , 2013 .

[65]  H. Sajjad,et al.  Fuel properties, engine performance and emission characteristic of common biodiesels as a renewable and sustainable source of fuel , 2013 .

[66]  Il Moon,et al.  Advances in diesel–alcohol blends and their effects on the performance and emissions of diesel engines , 2013 .

[67]  M. Jia,et al.  Numerical study on the combustion and emission characteristics of a methanol/diesel reactivity controlled compression ignition (RCCI) engine , 2013 .

[68]  M. P. Dorado,et al.  Performance tests of a diesel engine fueled with pentanol/diesel fuel blends , 2013 .

[69]  K. Dearn,et al.  Finding synergies in fuels properties for the design of renewable fuels--hydroxylated biodiesel effects on butanol-diesel blends. , 2013, Environmental science & technology.

[70]  Thore Berntsson,et al.  System aspects of biomass gasification with methanol synthesis – Process concepts and energy analysis , 2012 .

[71]  Yang Fang,et al.  Improving Production of Bioethanol from Duckweed (Landoltia punctata) by Pectinase Pretreatment , 2012 .

[72]  M. P. Dorado,et al.  A comparison of performance of higher alcohols/diesel fuel blends in a diesel engine , 2012 .

[73]  Reyes García-Contreras,et al.  The effect of the addition of individual methyl esters on the combustion and emissions of ethanol and butanol -diesel blends , 2012 .

[74]  Beatriz Fidalgo,et al.  CO2 reforming of coke oven gas over a Ni/γAl2O3 catalyst to produce syngas for methanol synthesis , 2012 .

[75]  Laura A. Pellegrini,et al.  Economic analysis of a combined energy–methanol production plant , 2011 .

[76]  Jens Buchgeister,et al.  A LCA (life cycle assessment) of the methanol production from sugarcane bagasse , 2011 .

[77]  Changming Gong,et al.  Regulated emissions from a direct-injection spark-ignition methanol engine , 2011 .

[78]  Chunde Yao,et al.  Effect of fumigation methanol and ethanol on the gaseous and particulate emissions of a direct-injection diesel engine , 2011 .

[79]  Riitta L. Keiski,et al.  Challenges in biobutanol production: How to improve the efficiency? , 2011 .

[80]  Yuanxin Wu,et al.  Experimental study on methanol recovery through flashing vaporation in continuous production of biodiesel via supercritical methanol , 2011 .

[81]  Jun Li,et al.  Effect of injection and ignition timings on performance and emissions from a spark-ignition engine fueled with methanol , 2010 .

[82]  Cenk Sayin,et al.  Engine performance and exhaust gas emissions of methanol and ethanol–diesel blends , 2010 .

[83]  Tiziano Faravelli,et al.  An experimental and kinetic modeling study of combustion of isomers of butanol , 2010 .

[84]  Reyes García-Contreras,et al.  Stability, Lubricity, Viscosity, and Cold-Flow Properties of Alcohol−Diesel Blends , 2010 .

[85]  Mustafa Canakci,et al.  The influence of operating parameters on the performance and emissions of a DI diesel engine using methanol-blended-diesel fuel , 2010 .

[86]  N. Houbak,et al.  Technoeconomic analysis of a methanol plant based on gasification of biomass and electrolysis of water , 2010 .

[87]  J. Agudelo,et al.  Lubricity of Ethanol-Biodiesel-Diesel Fuel Blends , 2010 .

[88]  T. Chan,et al.  Experimental investigation on regulated and unregulated emissions of a diesel/methanol compound combustion engine with and without diesel oxidation catalyst. , 2010, The Science of the total environment.

[89]  Sylvain Leduc,et al.  Location of a biomass based methanol production plant: A dynamic problem in northern Sweden , 2010 .

[90]  N. R. A. Filho,et al.  Production and characterization of the biofuels obtained by thermal cracking and thermal catalytic cracking of vegetable oils , 2009 .

[91]  J. Liao,et al.  Pentanol isomer synthesis in engineered microorganisms , 2009, Applied Microbiology and Biotechnology.

[92]  Zhen Huang,et al.  Regulated and unregulated emissions from a diesel engine fueled with biodiesel and biodiesel blended with methanol , 2009 .

[93]  Anthony Paul Roskilly,et al.  Experimental investigation on the performance and emissions of a diesel engine fuelled with ethanol–diesel blends , 2009 .

[94]  Mustafa Canakci,et al.  Effect of injection timing on the exhaust emissions of a diesel engine using diesel–methanol blends , 2009 .

[95]  M. Al-Hasan,et al.  The effect of iso‐butanol‐diesel blends on engine performance , 2008 .

[96]  Chun Tai,et al.  Simulation of High Efficiency Heavy Duty SI Engines Using Direct Injection of Alcohol for Knock Avoidance , 2008 .

[97]  L. Nielsen,et al.  Fermentative butanol production by clostridia , 2008, Biotechnology and bioengineering.

[98]  Qing Gao,et al.  Combustion of a Spark-Ignition Methanol Engine during Cold Start under Cycle-by-Cycle Control , 2008 .

[99]  Ranjeet S. Sokhi,et al.  Atmospheric polycyclic aromatic hydrocarbons: Source attribution, emission factors and regulation , 2008 .

[100]  S C Lee,et al.  Experimental investigation on the performance, gaseous and particulate emissions of a methanol fumigated diesel engine. , 2008, The Science of the total environment.

[101]  Ron Cascone,et al.  Biobutanol : A Replacement for Bioethanol? , 2008 .

[102]  P. Dürre Biobutanol: An attractive biofuel , 2007, Biotechnology journal.

[103]  Matthew J. Brusstar,et al.  High Efficiency with Future Alcohol Fuels in a Stoichiometric Medium Duty Spark Ignition Engine , 2007 .

[104]  Chonglin Song,et al.  Influence of ethanol-diesel blended fuels on diesel exhaust emissions and mutagenic and genotoxic activities of particulate extracts. , 2007, Journal of hazardous materials.

[105]  J. Chow,et al.  Evaluation of the thermal/optical reflectance method for discrimination between char- and soot-EC. , 2007, Chemosphere.

[106]  H. Wichmann Diesel Exhaust Particles , 2007, Inhalation toxicology.

[107]  R. Niven Ethanol in gasoline: environmental impacts and sustainability review article , 2005 .

[108]  Bing Liu,et al.  Combustion behaviors of a compression-ignition engine fueled with diesel/methanol blends under various fuel delivery advance angles. , 2004, Bioresource technology.

[109]  H. Zhen,et al.  Effect of cetane number improver on heat release rate and emissions of high speed diesel engine fueled with ethanol–diesel blend fuel , 2004 .

[110]  Hakima Abou-Rachid,et al.  DFT studies of the hydrogen abstraction from primary alcohols by O2 in relation with cetane number data , 2003 .

[111]  M. Chao,et al.  Effect of methanol-containing additive on the emission of carbonyl compounds from a heavy-duty diesel engine. , 2000, Journal of hazardous materials.

[112]  Jane V. Hall,et al.  Potential air quality benefits of methanol as a vehicle fuel , 1985 .