Thin-film SnO2 sensor arrays controlled by variation of contact potential—a suitable tool for chemometric gas mixture analysis in the TLV range

Abstract The selectivity of SnO2 thin-film gas sensors can be modulated by changing the contact areas of the contact electrodes. The investigated SnO2 arrays have been structured with two mask steps only. Gas mixture analysis in the German threshold limit value (TLV) range has been performed with an integrated thin-film sensor array using principal component regression (PCR) analysis. As an example, NO2, CO, CH4 and H2O mixtures in air have been analyzed. In this case additional doping materials, catalysts, temperature gradients, etc., to enhance selectivity are not necessary.

[1]  Isabel Sayago,et al.  Use of complex impedance spectroscopy in chemical sensor characterization , 1991 .

[2]  Udo Weimar,et al.  A.c. measurements on tin oxide sensors to improve selectivities and sensitivities , 1995 .

[3]  K. Steiner,et al.  Mobility profiles in short and narrow GaAs MESFET channels , 1991 .

[4]  D. Kohl,et al.  Physical and Chemical Aspects of Oxidic Semiconductor Gas Sensors , 1988 .

[5]  S. Laux,et al.  Effective barrier heights of mixed phase contacts: Size effects , 1982 .

[6]  R. Ionescu,et al.  The mechanism of the interaction between CO and an SnO2 surface: the role of water vapour , 1993 .

[7]  K. Steiner,et al.  Minimum-size effects in asymmetric tilt-angle-implanted LDD-WN/sub x/-GaAs MESFET's , 1991 .

[8]  D. S. Vlachos,et al.  The effect of humidity on tin-oxide thick-film gas sensors in the presence of reducing and combustible gases , 1995 .

[9]  K. Steiner,et al.  Contact and sheet resistance of SnO2 thin films from transmission-line model measurements , 1995 .

[10]  Udo Weimar,et al.  Conductance, work function and catalytic activity of SnO2-based gas sensors , 1991 .

[11]  Wolfgang Göpel,et al.  SnO2 sensors: current status and future prospects☆ , 1995 .

[12]  J. P. Marton,et al.  Physical Properties of SnO2 Materials I . Preparation and Defect Structure , 1976 .

[13]  S. Laux,et al.  Size dependence of ’’effective’’ barrier heights of mixed‐phase contacts , 1982 .

[14]  P. Hauptmann Sensors: A Comprehensive Survey , 1996 .