Complexes of niobium and tantalum with chloride, sulfide and oxide ligands: synthesis and crystal st

[1]  D. Coucouvanis,et al.  Synthesis and Structural Characterization of the [Nb(O)(S2)2SH]2-, [Nb(S)3SH]2-, and {[Nb(S)3]2O}4- anions. New elementary Thio- and Oxothioniobates , 1995 .

[2]  M. Millar,et al.  Synthesis and structure of titanium tetrathiolate and tantalum pentathiolate complexes. Metal-sulfur bonding in early transition metal compounds☆ , 1995 .

[3]  H. Brunner,et al.  Comparative studies in the Cp2M(η2-S2) H series (Cp = t-BuC5H4,C5Me Et; M = Nb, Ta) on the reactivity of hydrie and disulfide ligands , 1995 .

[4]  F. Preuß,et al.  Oxo‐ und Thiotantal(V)‐Verbindungen: Synthese von TaOX3 und TaSX3 (X = OR, SR) , 1994 .

[5]  D. Coucouvanis,et al.  Chalcogenometalate Complexes of NbV and TaV. Synthesis and Structural Characterization of the Et4N+ Salts of the[(E)3M(StBu)]2- Complexes (E = S, M = Nb, Ta; E = Se, M = Nb) and of (Ph4P)2[(S)3M(OMe)] , 1994 .

[6]  V. Fedorov,et al.  Nb2S44+ Complexes with 1,1-Dithioacid Ligands , 1994 .

[7]  F. Cotton,et al.  Preparations, structures, electronic structures, and magnetic properties of face-sharing bioctahedral niobium(III) and tantalum(III) compounds , 1994 .

[8]  A. Nakamura,et al.  Linear vs. bent MOR bonds in d0 metal alkoxides: X-ray crystal structure of (C5Me5)Ta(StBu)3(OnBu) and EHMO analysis , 1994 .

[9]  C. G. Young,et al.  Synthesis and crystal structure of tris(diethyldithiocarbamato-S,S′)(disulfido-S,S′)niobium(V) , 1994 .

[10]  B. Nuber,et al.  Von Cp+2Nb(η2-S2)H zu CP+3Nb3S12: Reaktivitätsstudien an Niobocensulfiden , 1993 .

[11]  H. Brunner,et al.  Reactivity studies on tantalocene(sulfido)hydride Cp'2Ta(=S)H (Cp'=ButC5H4) : cycloaddition on and protonation of the Ta=S ligand , 1993 .

[12]  R. H. Holm,et al.  Group 5 tetrathiometalates : simplified syntheses and structures , 1992 .

[13]  D. A. Femec,et al.  Synthesis, structure, and characterization of bis(diethyldithiocarbamato)(diethylthiocarbamyl)sulfidoniobium(V) and its tantalum analog , 1992 .

[14]  D. Coucouvanis,et al.  Activation and cleavage of the carbon-sulfur bond in niobium tert-butanethiolato complexes. Syntheses and structural characterizations of the tetrahedral and trigonal bipyramidal [Ph4P][NbV(S)2(tert-BuS)2] and [Et4N][NbV(S)(tert-BuS)4] complexes , 1992 .

[15]  H. Brunner,et al.  Metallocene sulfide chemistry of niobium and tantalum: new insights into the formation of niobium-polysulfido complexes and synthesis, structure, and reactivity of Cp2'Ta(.eta.2-S2)H (Cp' = tert-BuC5H4) , 1992 .

[16]  O. Curnow,et al.  Synthesis and structure of tetrakis(benzenethiolato)(methylcyclopentadienyl)tantalum and an EHMO analysis of its distorted four-legged piano-stool structure , 1991 .

[17]  F. Cotton,et al.  Structures of [Nb2Cl6(C4H8S)(PEt3)2], [Nb2Cl6(C4H8S)(C4H8O)2] and [Ta2Cl6(C4H8S)(PMe3)2] , 1991 .

[18]  U. Müller,et al.  Thiohalogeno-Verbindungen von Niob und Tantal: NbSCl3, TaSCl3, [NbSCl5]2−, [TaSCl5]2−, [NbSBr4]− Die Kristallstrukturen von (PPh4)2[NbSCl5] · 2 CH2Cl2 und NEt4[NbCl6]† , 1991 .

[19]  F. Cotton,et al.  A new bis(.mu.-sulfido)ditantalum(IV) edge-sharing bioctahedral molecule and a reassessment of some earlier "bis(.mu.-chloro)" molecules , 1990 .

[20]  S. Woodward,et al.  Cyclopentadienylniobium and -molybdenum phosphorodithioate complexes. X-ray crystal structures of CpNbCl3[S2P(OPr-iso)2], CpNbCl(.mu.-Cl)2Nb[S2P(OPr-iso)2]Cp, and cis-Cp'Mo(CO)2[S2P(OPr-iso)2] , 1990 .

[21]  G. Sheldrick Phase annealing in SHELX-90: direct methods for larger structures , 1990 .

[22]  W. M. Davis,et al.  X-ray study of Ta(CHCMe sub 3 )(S-2,4,6-C sub 6 H sub 2 -i-Pr sub 3 ) sub 3 (SEt sub 2 ) suggests why it is inactive for metathesis of ordinary olefins , 1990 .

[23]  A. Salifoglou,et al.  First examples of six-coordinate niobium and tantalum homoleptic complexes with monodentate arenethiolate ligands. Synthesis and structural characterization of [Ph4P]2[Nb(SPh)6], Na(THF)3Nb(SPh-pMe)6. [(15-crown-5)Na][Ta(SPh)6], and Nb2(.mu.2-SPh)4(SPh)4(SPh)2Cl2(C2H5CN)2 , 1990 .

[24]  R. Henderson,et al.  The chemistry of niobium and tantalum dithiocarbamato-complexes. Part 4. The co-ordination isomers of NbCl3(S2CNEt2)2 and the X-ray crystal structure of [NbCl3(S2CNEt2)2] , 1990 .

[25]  D. Walton,et al.  The chemistry of niobium and tantalum dithiocarbamato-complexes. Part 1. Synthesis, structure, and protonation of dinitrogen-bridged complexes , 1990 .

[26]  V. Young,et al.  Synthesis and Structure of a Tetrameric Tantalum(III) Compound , 1989 .

[27]  F. Cotton,et al.  The reactivity of M2(μ-Cl)2(μ-SMe2)Cl4(SMe2)2: formation of Ta2(μ-SEt)2(μ-Cl)Cl4(SMe2)2 and NbCl3(S2CNEt2)2 , 1989 .

[28]  G. Christou,et al.  Preparation and reactions of niobium(V) sulphide complexes , 1989 .

[29]  A. Nakamura,et al.  Synthesis of sulfido(pentamethylcyclopentadienyl)tantalum complex (C5Me5)Ta(S)32- and the structure of a hexagonal-prismatic Ta2Li4S6 core , 1989 .

[30]  F. Cotton,et al.  Oxo-bridged Ta(+3) dimers, (TaCl2L2)2(μ-O)(μ-SR2), revisited. Structural differences between isoelectronic μ-O and μ-OH complexes , 1988 .

[31]  F. Cotton,et al.  Reactions of Nb2Cl6(SMe2)3 and Ta2Cl6(SMe2)3 with compounds containing NN single bonds , 1988 .

[32]  A. Müller,et al.  Polysulfide Complexes of Metals , 1988 .

[33]  G. Christou,et al.  The first example of a niobium–sulphide–thiolate cluster: metal–metal bonding and µ4-sulphide groups in tetranuclear [Nb4S2(SPH)12]4– , 1987 .

[34]  A. Nakamura,et al.  Cleavage of a carbon-sulfur bond in [Nb(SCH2CH2S)3]-leading to formation of a sulfide and tpdt ligand in [NbS(SCH2CH2S)(SCH2CH2SCH2CH2S)]- , 1986 .

[35]  Y. Do,et al.  Variability of niobiumsulfur bond lengths: The molecular structures of sulfido-tris(N,N-diethyldithiocarbamato)niobium(V) , 1985 .

[36]  M. Drew,et al.  High-co-ordination-number compounds of niobium and tantalum: reactions of niobium and tantalum halides and sulphide-halides with sodium diethyldithiocarbamate. The crystal structures of [Nb(S2CNEt2)4]Br, Nb(S2CNEt2)3S, and Ta(S2CNEt2)3(S2) , 1985 .

[37]  A. Müller,et al.  VERY SIMPLE PRODUCTION OF [FE4S4BR4]2-, A CUBAN CLUSTER WITH NON-COMPRESSED (FE4S4)2+ CORE , 1985 .

[38]  V. Shklover,et al.  Synthesis and molecular structure of the niobocene sulphide dimer , 1984 .

[39]  M. Drew,et al.  Some co-ordination compounds of TaCl3S and TaBr3S. X-Ray crystal structure of [TaCl3S(PhSCH2CH2SPh)] , 1984 .

[40]  J. Berg,et al.  SOLUBLE METAL SULFIDES - SYNTHESIS AND STRUCTURES OF [M6S17]4- (M = NB, TA) - ICOSAHEDRAL-FRAGMENT CAGES CONTAINING FOUR TYPES OF COORDINATED SULFIDE , 1983 .

[41]  M. Drew,et al.  The reactions of tetrahydrothiophene (tht) with tribromosulphidoniobium(V) and trichlorosulphidoniobium(V) and the crystal structures of three of the products Nb2Cl4S3·4tht, Nb2Br4S3·4tht, and NbBr3S·2tht , 1983 .

[42]  T. Rauchfuss,et al.  Structure of (MeC5H4)2V2S5 and its acetylene addition reaction , 1982 .

[43]  K. Prout,et al.  One example of disulphide as bridging ligand in μ‐disulphido‐bis[η‐(n‐butylcyclopentadienyl)dichloromolybdenum] , 1979 .

[44]  J. Gladysz,et al.  Introduction of sulphur into organic molecules via lithium triethylborohydride reduction of S8 , 1978 .

[45]  D. Pantaleo,et al.  The crystal and molecular structures of NbCl(OCH3)2(dedtc)2 and NbBr(OCH3)2(dedtc)2 , 1971 .

[46]  F. Fairbrother,et al.  53. The halides of niobium and tantalum. Part VII. Dimethyl ether, di-n-propyl ether, and di-n-propyl sulphide complexes of the pentachlorides; the relative strengths of dialkyl ether and dialkyl sulphide complexes , 1964 .

[47]  J. F. Nixon,et al.  29. The halides of niobium and tantalum. Part VI , 1962 .