Removal of heavy metal ions from pharma-effluents using graphene-oxide nanosorbents and study of their adsorption kinetics

Abstract Nanomaterials open up enormous opportunities in the areas of industrial waste water treatment and their application. Effective removal of toxic heavy metal ions like Pb(II), Ni(II) and Cr(VI) from pharmacy waste-effluent using graphene-oxide(GO) nanosorbents is reported here. Cr and Pb ions are completely removed by GO, however Ni ion trace was gradually decreased when GO concentration was increased. The concentration of GO at 70 mg removes all heavy metal ions effectively with the permissible pH of 8.00 and very low conductivity of 0.027 dS/m in 100 mL effluent, studied using atomic absorption spectroscopy. Also the adsorption isotherm models and adsorption kinetics are discussed.

[1]  Yilong Wang,et al.  Synergistic Removal of Pb(II), Cd(II) and Humic Acid by Fe3O4@Mesoporous Silica-Graphene Oxide Composites , 2013, PloS one.

[2]  K. Bani-Melhem,et al.  Heavy metal ions removal from metal plating wastewater using electrocoagulation: Kinetic study and process performance , 2015 .

[3]  H. Mousavi,et al.  Effect of nanostructure alumina on adsorption of heavy metals , 2010 .

[4]  S. Saha,et al.  Removal of toxic Cr(VI) by UV-active functionalized graphene oxide for water purification , 2013 .

[5]  S. Ramaprabhu,et al.  Functionalized graphene sheets for arsenic removal and desalination of sea water , 2011 .

[6]  Rodney S. Ruoff,et al.  Characterization of Thermally Reduced Graphene Oxide by Imaging Ellipsometry , 2008 .

[7]  R. Kumar,et al.  Synthesis and characterization of porous magnetic silica composite for the removal of heavy metals from aqueous solution , 2015 .

[8]  Young-Ju Kim,et al.  Optimization of color and COD removal from livestock wastewater by electrocoagulation process: Application of Box–Behnken design (BBD) , 2015 .

[9]  S. Stankovich,et al.  Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets , 2006 .

[10]  G. Eda,et al.  Chemically Derived Graphene Oxide: Towards Large‐Area Thin‐Film Electronics and Optoelectronics , 2010, Advanced materials.

[11]  Sang‐Jae Kim,et al.  Graphene-oxide (GO)-Fe3+ hybrid nanosheets with effective sonocatalytic degradation of Reactive Red 120 and study of their kinetics mechanism. , 2015, Ultrasonics sonochemistry.

[12]  J. Zhao,et al.  Nanomaterials as Sorbents to Remove Heavy Metal Ions in Wastewater Treatment , 2012 .

[13]  Soo-Jin Park,et al.  A review on solid adsorbents for carbon dioxide capture , 2015 .

[14]  S.-J. Cui,et al.  Adsorption removal of pefloxacin from water by halloysite nanotubes , 2015 .

[15]  M. Ghiaci,et al.  Schiff Base Ligands Immobilized on a Nanosized SiO2–Al2O3 Mixed Oxide as Adsorbents for Heavy Metals , 2011 .

[16]  S. M. Dehaghi,et al.  Removal of Lead Ions from Wastewater Using Functionalized Multiwalled Carbon Nanotubes with Tris(2-Aminoethyl)Amine , 2013 .

[17]  Wai-Hung Lo,et al.  Removal and recovery of heavy metals by bacteria isolated from activated sludge treating industrial effluents and municipal wastewater , 2000 .

[18]  Jian Bao,et al.  Thiol-functionalized magnetite/graphene oxide hybrid as a reusable adsorbent for Hg2+ removal , 2013, Nanoscale Research Letters.

[19]  Jiaxing Li,et al.  Few-layered graphene oxide nanosheets as superior sorbents for heavy metal ion pollution management. , 2011, Environmental science & technology.

[20]  Kun She Low,et al.  Biosorption of basic dyes by water hyacinth roots , 1995 .

[21]  Y. Ho,et al.  Regression analysis for the sorption isotherms of basic dyes on sugarcane dust. , 2005, Bioresource technology.

[22]  Xiangke Wang,et al.  Adsorption of Ni(II) from Aqueous Solution Using Oxidized Multiwall Carbon Nanotubes , 2006 .

[23]  Guangming Zeng,et al.  Simultaneous removal of Cd(II) and ionic dyes from aqueous solution using magnetic graphene oxide nanocomposite as an adsorbent , 2013 .

[24]  K. Krishnamoorthy,et al.  An investigation of the electrical transport properties of graphene-oxide thin films , 2012 .

[25]  I. Ali New generation adsorbents for water treatment. , 2012, Chemical reviews.

[26]  Mohamed Barakat,et al.  New trends in removing heavy metals from industrial wastewater , 2011 .

[27]  Jin Suk Chung,et al.  Fast and simple fabrication of a large transparent chemically-converted graphene film by spray-coating , 2010 .

[28]  Jian Jin,et al.  Polydopamine-mediated surface-functionalization of graphene oxide for heavy metal ions removal , 2015 .

[29]  Tonni Agustiono Kurniawan,et al.  Low-cost adsorbents for heavy metals uptake from contaminated water: a review. , 2003, Journal of hazardous materials.

[30]  P. Sharma,et al.  Removal of a Cationic Dye from Aqueous Solution Using Graphene Oxide Nanosheets: Investigation of Adsorption Parameters , 2013 .

[31]  Huang-Wei Chang,et al.  Structural and nanomechanical properties of BiFeO3 thin films deposited by radio frequency magnetron sputtering , 2013, Nanoscale Research Letters.

[32]  M. Machida,et al.  Lead(II) adsorption onto the graphene layer of carbonaceous materials in aqueous solution , 2006 .

[33]  Aiqin Wang,et al.  Synthesis of covalently crosslinked attapulgite/poly(acrylic acid-co-acrylamide) nanocomposite hydrogels and their evaluation as adsorbent for heavy metal ions , 2015 .

[34]  K. Tyszczuk‐Rotko,et al.  Ordered mesoporous carbons as effective sorbents for removal of heavy metal ions , 2015 .

[35]  K. Krishnamoorthy,et al.  An investigation on high-temperature electrical transport properties of graphene-oxide nano-thinfilms , 2013 .

[36]  Shiyan Chen,et al.  Adsorption of Cu(II) and Pb(II) onto diethylenetriamine-bacterial cellulose , 2009 .

[37]  Sakthivel Thangavel,et al.  Understanding the adsorption property of graphene-oxide with different degrees of oxidation levels , 2014 .