Influence of the External Electric Field on the Dielectric Properties of Ca2Sr(C2D5CO2)6

The results of the investigation of the dielectric dispersion and the influence of an external electric field on the static dielectric permittivity in DDSP crystals are presented. Dielectric dispersion takes place mainly in the frequency range from 107 to 108 Hz, where e′(T) shows a critical slowing-down of the polarization relaxation process. The static dielectric permittivity strongly depends on the external electric field, and a maximum of e′ occurs at E ≠ 0. e′ reaches its maximum at E = 0.8 kV/cm. The proposed phenomenological explanation gives a good agreement with experimental data over the whole range of external electric field, thus, the concept of the internal biasing field is supported by a simple evaluation of the phenomenological theory. Nevertheless, the origin of the biasing field in the high temperature phase is still an open question. Es wird der Einflus eines elektrischen Feldes auf die dielektrischen Eigenschaften von DDSP-Einkristallen untersucht. Bei T = 278 K erscheint die dielektrische Dispersion im Frequenzbereich von 107 bis 108 Hz, die mit Relaxationsprozessen der Polarisation verbunden ist. Die statische Dielektrizitatskonstante hangt sehr stark von der elektrischen Feldstarke ab und erreicht ein Maximum bei E ≠ 0. Der Realteil der komplexen Dielektrizitatskonstante erreichte sein Maximum bei E = 0,8 kV/cm. Es wird ein phanomenologisches Modell entwickelt, das die experimentellen Daten gut beschreibt. Es gibt Schwierigkeiten bei der Anwendung dieses Modells bei der Erklarung der inneren elektrischen Felder in dem untersuchten Material.

[1]  T. Yagi,et al.  Effect of deuteration on the dynamical dielectric properties of DSP , 1990 .

[2]  T. Yagi On the mechanism of I – II phase transition of DSP , 1990 .

[3]  T. Yagi,et al.  Raman scattering spectra of internal modes of ferroelectric deuterated dicalcium strontium propionate, ca2sr(c2d5co2)6 , 1989 .

[4]  T. Yagi,et al.  Crystal structure of deuterated dicalcium strontium propionate, Ca2Sr(C2D5CO2)6 in the paraelectric and ferroelectric phases , 1988 .

[5]  T. Yagi,et al.  Brillouin Scattering Study of Deuterated Dicalcium Strontium Propionate, Ca 2 Sr(C 2 D 5 CO 2 ) 6 , 1987 .

[6]  T. Yagi,et al.  Spontaneous Polarization of Deuterated Dicalcium Strontium Propionate, Ca2Sr(C2D5CO2)6 , 1987 .

[7]  A. Brilingas,et al.  Relaxational Dynamics of the Improper Ferroelectric K3BiCl6 · 2 KC1 · KH3F4 , 1986 .

[8]  T. Yagi On the Dielectric Anomaly of the Deuterated Dicalcium Strontium Propionate, Ca2Sr(C2D5CO2)6 , 1986 .

[9]  A. Glazer,et al.  The structure and optical activity of the paraelectric phase of dicalcium strontium propionate , 1981 .

[10]  Y. Ishibashi,et al.  Two-Sublattice Model of Ferroelectric Phase Transitions , 1976 .

[11]  E. Nakamura,et al.  Effect of Heat-Treatment of Dielectric Properties of Ca 2 Sr(C 2 H 5 CO 2 ) 6 , 1976 .

[12]  Y. Ishibashi,et al.  A Simple Model for Phase Transition in Ca2Sr(C2H5CO2)6 , 1974 .

[13]  M. Hosoya,et al.  Dielectric Critical Slowing-Down in Ferroelectric Ca2Sr(C2H5CO2)6 , 1967 .

[14]  J. P. Remeika,et al.  Ferroelectricity of Dicalcium Strontium Propionate , 1957 .